Pengaruh Rasio Berat Asidfikasi Dan Persen Berat Adsorben Terhadap Kemurnian Gliserol Dengan Metode Asidikasi Dan Adsorpsi

Meningkatnya produksi biodisel sebagai bahan bakar mengakibatkan meningkatnya jumlah crude gliserol sebagai hasil samping. Untuk itu diperlukan beberapa perlakuan untuk memanfatkan gliserol tersebut dengan cara memurnikannya. Penelitian ini bertujuan untuk mengetahui rasio berat asam fosfat yang terbaik pada proses asidifikasi dan persen berat adsorben limbah cangkang telur ayam pada proses adsorpsi untuk menghasilkan kemurnian gliserol dengan kadar yang tertinggi. Percobaan diawali dengan pretreatment gliserol dengan asam fosfat dengan variabel uji rasio b e r a t (b/b) asam yang ditambahkan (1:0,2; 1:0,4; 1:0,6; 1:0,8 dan 1:1), dilanjutkan dengan adsorpsi menggunakan limbah cangkang telur ayam yang sudah diaktivasi secara termal dengan variabel uji persen berat adsorben (%b/b) 3%, 6%, 9%, 12% dan 15% dengan kondisi reaksi kecepatan pengadukan 250 rpm dan waktu adsorpsi 120 menit. Hasil kemurnian terbaik didapatkan pada rasio berat (b/b) asidifikasi 1:0,6, persen berat adsorben (%b/b) 15% dengan kadar gliserol sebesar 67,22%, densitas 1,171 g/cm3, kadar air 2,796%, kadar abu13,852% dan kadar MONG 16,130%. Hasil analisa gliserol yang sudah dimurnikan belum memenuhi standard gliserol komersial berdasarkan British Standard 2621:1979 dimana kadar gliserol harus 80%, densitas 1,2671 g/cm3, kadar air 10%, kadar abu 10% dan kadar MONG 2,5%

EKSTRAK DAUN SIRIH HIJAU DAN MERAH SEBAGAI ANTIOKSIDAN PADA MINYAK KELAPA

Extraction is the separation of a substance from the mixture, with the distribution of a solute between two solvents which can not be mixed to fetch solute from one solvent to another solvent. The purpose of this study was to determine the antioxidant activity found in betel leaf extract for coconut oil numbers peroxide analysis, antioxidant resistance, with Lovibond color test and to found variations in betel leaf types that produce the optimum operating conditions of antioxidants. In this study, green and red betel leaves extracted by using ethanol solvent, the extract is added to coconut oil and then tested peroxide number and color levels. The results obtained in this study were able to lower the number of betel leaves peroxide by 55.13% with the best optimum condition; volume of 150 ml of solvent, extraction time of 75 minutes, and stirring speed of 300 rpm for the raw material powder of red betel leaf

KARAKTERISTIK EDIBLE FILM DARI EKSTRAK KACANG KEDELAI DENGAN PENAMBAHAN TEPUNG TAPIOKA DAN GLISEROL SEBAGAI BAHAN PENGEMAS MAKANAN

ne way to solve the environment issue in the usage of nonbiodegradable plastic is by using biodegradable packaging. Edible film is a thin layer which is overlay the food. In this research, edible film made from mixture of soybean extract with starch and glycerol. The process of making edible films is began with producing soybean protein extract producing soy milk. Soy milk added by tapioca flour and glyserol variations : 2; 4; 6; 8 and 10 (ml/100 ml soy milk). Then, the mixture stirred by using magnetic stirer, formed and dried in the oven at the temperature of 40 °C ± 2 days. After that, the characteristics test of edible film done by checking the thickness, the tensile strength and elongation at break. The results of research shows that the addition of glycerol influence the edible film’s thickness, tensile strength and elongation at break. The thickness obtained from the increasing of the addition glycerol. They are 0,208 mm; 0,228 mm; 0,248 mm; 0,274 mm and 0,294 mm. The tensile strength will decrease if the thickness of the edible film increase. They are 0,105 MPa; 0,134 MPa; 0,088 MPa; 0,072 MPa and 0,048 MPa. The elongation at break which is obtained will increase by increasing of edible film’s thickness. They are 1,839%; 3,270%; 3,842%; 5,779%, and 6,158%. The characteristic’s test shows that the best thickness of edible film is 0,228 mm

PEMANFAATAN EKSTRAK DAUN SAMBUNG NYAWA (Gynura Procumbens [Lour].Merr) SEBAGAI ANTIOKSIDAN PADA MINYAK KELAPA MENGGUNAKAN PELARUT METANOL

Sambung Nyawa leaves (Gynura Procumbens [Lour].Merr) have been used as a traditional medicine. Sambung Nyawa leaves contain flavonoid compounds, its functional as a natural antioxidant. The aim of this study was to analyze the effect of Sambung Nyawa leaves extract addition as an antioxidant and ability to preserve the quality of coconut oil. Firstly, flavonoids were extracted from Sambung Nyawa leaves with combination of raw material to solvent ratio (w/v) and extraction temperature. The extracts which gave the highest total flavonoids contents were mixed into the coconut oil  for 3 days, 6 days, 9 days, 12 days, and 15 days. Total  flavonoids contents of  Sambung Nyawa leaves extracts were analyzed by UV-Vis spectrophotometry. The analyses for coconut oil were the value of acid, iod, and peroxide number. The results showed that the highest total flavonoids contents of  1,32 %  be obtained with raw material to solvent ratio of 1:10 (w/v) and extraction temperature of 55 oC. The lowest acid number of 0.45%, the highest iod number of 7.90 gr I2/100 gr, and the lowest peroxide number of 4.40 mg O2/100 gr be obtained with stored time of 3 days for coconut oil which mixed with the Sambung Nyawa leaves extracts

PENGARUH KONSENTRASI KATALIS DAN WAKTU REAKSI PADA PEMBUATAN EPOKSI MINYAK GORENG BEKAS

Epoxy is produced from an epoxidation of vegetable oil or natural oil with au nsaturated bond. Epoxy can be applied as a stabilizer, plasticizers in polyvinyl chloride (PVC) and can be used as an antioxidant in natural rubber processing, as a surfactant, anti-corrosive additive agent in lubricants and pesticide raw materials. The purpose of this research was to evaluate epoxy production from waste cooking oil. In this research, waste cooking oil was reacted with hexane as solvent, sulfuric acid as catalyst, glacial acetic acid and hydrogen peroxide. The catalyst concentration was varied from 1.5%, 2.1%, 2.5%, 3.1% and 3.5% and the epoxidation time was varied from 60, 120, 180, 240 and 300 min. The results showed that highest epoxy yield was achieved at reaction time of 300 min and 1.5% catalyst. At that condition, the iod number was 0,96 g I2/100 g WCO, oxirane oxygen content was 1.872 and oxirane oxygen conversion was 62.259%

PENGARUH PELARUT KLOROFORM DALAM PEMURNIAN GLISEROL DENGAN PROSES ASIDIFIKASI ASAM KLORIDA

Glycerol as a byproduct of biodiesel production was approximately formed 10% of the biodiesel weight. Impurities which contained in the glycerol such as catalyst, soap, methanol, water, salt, and matter organic non glycerol (MONG) have a significant effect on the glycerol concentration. So, it is necessary to treat the impurities. The purpose of this study is to know the effect of chloroform to glycerol purification process with acidification method using hydrochloric acid as pretreatment process. This research was begun with acid addition to the glycerol to neutralize the base content and to split the soap content into free fatty acid and salt, that are more easily separated from glycerol. Then the process was continued with extraction by the solvent chloroform using the variable of test volume ratio (v/v) (1:1, 1:1.5, 1:2)  and the extraction time (20, 40, and 60 minutes). The results showed that the more volume of solvent used, gave less extraction time to produce high purity of glycerol. The highest purity produced in this study amounted to 90,9082% is obtained at the ratio of the volume solvent (v/v) 1:1 with extraction time 60 minutes

PENGARUH MASSA KATALIS DAN WAKTU REAKSI PADA PEMBUATAN BIODIESEL DARI LIMBAH MINYAK JELANTAH DENGAN MENGGUNAKAN KATALIS HETEROGEN K2O DARI LIMBAH KULIT KAKAO

Waste cooking oil is a waste oil that comes from many types of cooking oils such as corn oil, vegetable oil, ect. The purpose of this research is to waste cooking oil as a raw material to form biodiesel with K2O as the solid catalyst from cocoa pod ash (CPA) which is calcined on temperature 650 oC within 4 hours. This oil contains a high level of Free Fatty Acid (FFA) that is 3.13%. Therefore, pretreatment should be done by using activated carbon (1% w/w) to reduce levels of FFA. The research will be observed the effect of reaction time and the mass of catalyst. The characteristics of biodiesel is analyzed according to the levels of methyl ester in biodiesel, density, and viscosity based on the Indonesian National Standard (SNI). The best conditions of biodiesel are obtained with the amount of catalyst is 6% (w/w) that is calcined at 650 °C, reaction time 180 minutes, ratio mol of alcohol : oil is 12: 1, and 65 oC reaction of temperature, resulting the purity and yield of biodiesel is 99,8% and 92,68%. The results of this research indicates that the use of waste cooking as a raw material is suitable in the manufacture of biodiesel

PEMANFAATAN LIMBAH CANGKANG TELUR AYAM SEBAGAI ADSORBEN PADA PEMURNIAN GLISEROL DENGAN METODE ASIDIFIKASI DAN ADSORPSI

Glycerol as a byproduct of biodiesel production was approximately formed 10-20% of the biodiesel weight. Impurities which contained in the glycerol such as inorganic salts, catalysts, water and matter organic non glycerol (MONG) which contained free fatty acids, fatty acids as residual of methyl ester, glycerides, and alcohols (generally methanol or ethanol) had a significant effect on glycerol concentration. We needed some treatment, especially to eliminate the impuritis. This study aims to purify glycerol by acidfication using phosphate and adsorption with chicken egg shell waste. This research was begun with the pretreatment of glycerol using phosphoric acid with the variable of test weight ratio (w/w) acid added 1: 0.2; 1: 0.4; 1: 0.6; 1: 0.8 and 1: 1 , continued with adsorption using thermally activated chicken egg shell waste with the variable weight percent adsorbent (%w/w) 3%, 6%, 9%, 12% and 15% with reaction conditions, stirring speed 250 rpm and adsorption time 120 minutes. The purest result was obtained at weight ratio (w/w) acidification of 1: 0.6, weight percent adsorbent (% w/w) 15% with glycerol content of 67.22%, density 1.171 g / cm3, moisture content 2.796%, ash content 13.852% and MONG content 16.130%