95 research outputs found
organic crystals: superconducting versus antiferromagnetic instabilities in an anisotropic triangular lattice Hubbard model
A Hubbard model at half-filling on an anisotropic triangular lattice has been
proposed as the minimal model to describe conducting layers of
organic materials. The model interpolates between the
square lattice and decoupled chains. The materials
present many similarities with cuprates, such as the presence of unconventional
metallic properties and the close proximity of superconducting and
antiferromagnetic phases. As in the cuprates, spin fluctuations are expected to
play a crucial role in the onset of superconductivity. We perform a
weak-coupling renormalization-group analysis to show that a superconducting
instability occurs. Frustration in the antiferromagnetic couplings, which
arises from the underlying geometrical arrangement of the lattice, breaks the
perfect nesting of the square lattice at half-filling. The spin-wave
instability is suppressed and a superconducting instability predominates. For
the isotropic triangular lattice, there are again signs of long-range magnetic
order, in agreement with studies at strong-coupling.Comment: 4 pages, 5 eps figs, to appear in Can. J. Phys. (proceedings of the
Highly Frustrated Magnetism (HFM-2000) conference, Waterloo, Canada, June
2000
Phonon anomalies due to strong electronic correlations in layered organic metals
We show how the coupling between the phonons and electrons in a strongly
correlated metal can result in phonon frequencies which have a non-monotonic
temperature dependence. Dynamical mean-field theory is used to study the
Hubbard-Holstein model that describes the \kappa-(BEDT-TTF)_2 X family of
superconducting molecular crystals. The crossover with increasing temperature
from a Fermi liquid to a bad metal produces phonon anomalies that are
consistent with recent Raman scattering and acoustic experiments.Comment: 6 pages, 3 eps figure
Transport criticality of the first-order Mott transition in a quasi-two-dimensional organic conductor, -(BEDT-TTF)Cu[N(CN)]Cl
An organic Mott insulator, -(BEDT-TTF)Cu[N(CN)]Cl, was
investigated by resistance measurements under continuously controllable He gas
pressure. The first-order Mott transition was demonstrated by observation of
clear jump in the resistance variation against pressure. Its critical endpoint
at 38 K is featured by vanishing of the resistive jump and critical divergence
in pressure derivative of resistance, , which are consistent with the prediction of the dynamical mean field
theory and have phenomenological correspondence with the liquid-gas transition.
The present results provide the experimental basis for physics of the Mott
transition criticality.Comment: 4 pages, 5 figure
Metal-insulator transition and charge ordering in the extended Hubbard model at one-quarter filling
We study with exact diagonalization the zero temperature properties of the
quarter-filled extended Hubbard model on a square lattice. We find that
increasing the ratio of the intersite Coulomb repulsion, , to the band width
drives the system from a metal to a charge ordered insulator. The evolution of
the optical conductivity spectrum with increasing is compared to the
observed optical conductivity of several layered molecular crystals with the
theta and beta'' crystal structures.Comment: 5 pages, 3 figure
Magnetic-field-induced superconductivity in layered organic molecular crystals with localized magnetic moments
The synthetic organic compound lambda-(BETS)2FeCl4 undergoes successive
transitions from an antiferromagnetic insulator to a metal and then to a
superconductor as a magnetic field is increased. We use a Hubbard-Kondo model
to clarify the role of the Fe(3+) magnetic ions in these phase transitions. In
the high-field regime, the magnetic field acting on the electron spins is
compensated by the exchange field He due to the magnetic ions. This suggests
that the field-induced superconducting state is the same as the zero-field
superconducting state which occurs under pressure or when the Fe(3+) ions are
replaced by non-magnetic Ga(3+) ions. We show how He can be extracted from the
observed splitting of the Shubnikov-de Haas frequencies. Furthermore, we use
this method of extracting He to predict the field range for field-induced
superconductivity in other materials.Comment: 5 page
Antiferromagnetic Heisenberg model on anisotropic triangular lattice in the presence of magnetic field
We use Schwinger boson mean field theory to study the antiferromagnetic
spin-1/2 Heisenberg model on an anisotropic triangular lattice in the presence
of a uniform external magnetic field. We calculate the field dependence of the
spin incommensurability in the ordered spin spiral phase, and compare the
results to the recent experiments in CsCuCl by Coldea et al. (Phys.
Rev. Lett. 86, 1335 (2001)).Comment: 4 pages with 4 figures include
Cyclotron effective masses in layered metals
Many layered metals such as quasi-two-dimensional organic molecular crystals
show properties consistent with a Fermi liquid description at low temperatures.
The effective masses extracted from the temperature dependence of the magnetic
oscillations observed in these materials are in the range, m^*_c/m_e \sim 1-7,
suggesting that these systems are strongly correlated. However, the ratio
m^*_c/m_e contains both the renormalization due to the electron-electron
interaction and the periodic potential of the lattice. We show that for any
quasi-two-dimensional band structure, the cyclotron mass is proportional to the
density of states at the Fermi energy. Due to Luttinger's theorem, this result
is also valid in the presence of interactions. We then evaluate m_c for several
model band structures for the \beta, \kappa, and \theta families of
(BEDT-TTF)_2X, where BEDT-TTF is bis-(ethylenedithia-tetrathiafulvalene) and X
is an anion. We find that for \kappa-(BEDT-TTF)_2X, the cyclotron mass of the
\beta-orbit, m^{*\beta}_c, is close to 2 m^{*\alpha}_c, where m^{*\alpha}_c is
the effective mass of the \alpha- orbit. This result is fairly insensitive to
the band structure details. For a wide range of materials we compare values of
the cyclotron mass deduced from band structure calculations to values deduced
from measurements of magnetic oscillations and the specific heat coefficient.Comment: 12 pages, 3 eps figure
Symmetrized mean-field description of magnetic instabilities in k-(BEDT-TTF)_2Cu[N(CN)]_2 Y salts
We present a novel and convenient mean-field method, and apply it to study
the metallic/antiferromagnetic interface of k-(BEDT-TTF)_2Cu[N(CN)]_2 Y organic
superconductors (BEDT_TTF is bis-ethylen-dithio-tetrathiafulvalene, Y=Cl, Br).
The method, which fully exploits the crystal symmetry, allows one to obtain the
mean-field solution of the 2D Hubbard model for very large lattices, up to
6x10^5 sites, yielding a reliable description of the phase boundary in a wide
region of the parameter space. The metal/antiferromagnet transtion appears to
be second order, except for a narrow region of the parameter space, where the
transition is very sharp and possibly first order. The cohexistence of metallic
and antiferromagnetic properties is only observed for the transient state in
the case of smooth second order transitions. The relevance of the present
resaults to the complex experimental behavior of centrosymmetric k-phase
BEDT-TTF salts is discussed.Comment: 9 pages in PS format, 7 figures (included in PS), 1 tabl
Phase diagram for a class of spin-half Heisenberg models interpolating between the square-lattice, the triangular-lattice and the linear chain limits
We study the spin-half Heisenberg models on an anisotropic two-dimensional
lattice which interpolates between the square-lattice at one end, a set of
decoupled spin-chains on the other end, and the triangular-lattice Heisenberg
model in between. By series expansions around two different dimer ground states
and around various commensurate and incommensurate magnetically ordered states,
we establish the phase diagram for this model of a frustrated antiferromagnet.
We find a particularly rich phase diagram due to the interplay of magnetic
frustration, quantum fluctuations and varying dimensionality. There is a large
region of the usual 2-sublattice Ne\'el phase, a 3-sublattice phase for the
triangular-lattice model, a region of incommensurate magnetic order around the
triangular-lattice model, and regions in parameter space where there is no
magnetic order. We find that the incommensurate ordering wavevector is in
general altered from its classical value by quantum fluctuations. The regime of
weakly coupled chains is particularly interesting and appears to be nearly
critical.Comment: RevTeX, 15 figure
Charge ordering and antiferromagnetic exchange in layered molecular crystals of the theta type
We consider the electronic properties of layered molecular crystals of the
type theta-DA, where A is an anion and D is a donor molecule such as
BEDT-TTF [where BEDT-TTF is bis-(ethylenedithia-tetrathiafulvalene)] which is
arranged in the theta type pattern within the layers. We argue that the
simplest strongly correlated electron model that can describe the rich phase
diagram of these materials is the extended Hubbard model on the square lattice
at a quarter filling. In the limit where the Coulomb repulsion on a single site
is large, the nearest-neighbour Coulomb repulsion, V, plays a crucial role.
When V is much larger than the intermolecular hopping integral t the ground
state is an insulator with charge ordering. In this phase antiferromagnetism
arises due to a novel fourth-order superexchange process around a plaquette on
the square lattice. We argue that the charge ordered phase is destroyed below a
critical non-zero value V, of the order of t. Slave boson theory is used to
explicitly demonstrate this for the SU(N) generalisation of the model, in the
large N limit. We also discuss the relevance of the model to the all-organic
family beta''-(BEDT-TTF)SFYSO where Y = CHCF, CH, CHF.Comment: 15 pages, 6 eps figure
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