Impacts of Urbanization and Its Parameters on Thermal and Dynamic Fields in Hangzhou: A Sensitivity Study Using the Weather Research and Forecasting Urban Model

The impact of urbanization and the sensitivity of urban canopy parameters (UCPs) on a typical summer rainfall event in Hangzhou, China, is investigated using three groups of ensemble experiments. In this case, urbanization leads to higher temperatures, lower mixing ratios, lower wind speeds before precipitation, and more precipitation in and around the urban area. Both the thermal and dynamical effects of urbanization contribute to an increase in temperature and precipitation, with thermal effects contributing 71.2% and 63.8% to the temperature and precipitation increase, respectively, while the thermal and dynamical impacts cause the opposite changes to the mixing ratio and wind speed. Compared to the other three meteorological elements, the model has the largest uncertainty in the simulation of precipitation, which includes the sensitivity of the different parameterization schemes to the simulation of precipitation in urban areas, and the uncertainty brought by the urban effect on precipitation is not confined within the city but extends to the surrounding areas as well. Temperature and mixing ratio are more sensitive to thermal-related UCPs, while the wind speed is mainly affected by the structural parameters. These variations, however, are sometimes contradictory to precipitation changes, which further adds to the complexity of precipitation simulation

A CHA zeolite supported Ga-oxo cluster for partial oxidation of CH4 at room temperature

A catalytic system for activation of CH4 under mild conditions is in high demand. In this study, Ga-oxo clusters in CHA zeolites were prepared by reductive solid-state ion-exchange followed by O-2 treatment. Formation of the Ga-oxo clusters was demonstrated using X-ray absorption fine structure (XAFS) measurements. Plausible models of the cluster were developed by using an ab initio thermodynamic analysis. Importantly, the CHA zeolite-supported Ga-oxo clusters promote partial oxidation of CH4 to yield adsorbed formaldehyde and formic acid. The results of density functional theory (DFT) calculations, designed to gain information about the mechanism of the process, show that the Z(2)[Ga-2(O)(OH)(2)] is likely the most active cluster for C-H bond activation of CH4. Observations made in this experimental and theoretical effort demonstrate that main-group metal-oxo clusters have the potential of serving as active species for transformations of CH4

A Comparison of Different Station Data on Revealing the Characteristics of Extreme Hourly Precipitation Over Complex Terrain: The Case of Zhejiang, China

Abstract Both long‐term but small number of national stations and short‐term but large number of regional stations have been frequently used to study the extreme hourly precipitation (EXHP) in China. However, few studies focus on the differences of the two for revealing the features of EXHP. In this study, the characteristics of EXHP in Zhejiang Province are investigated using three rainfall data sets at three threshold criteria. The comparison between different data sets shows that increasing the station density can better reflect the climatic spatial distribution of EXHP thresholds if long‐term data is absent. The majority of EXHP can be classified into four weather types: the southwesterly wind type (30.7%–48.5%), the trough type (12.2%–23.6%), the tropical cyclone (TC) type (11.4%–17.5%) and the easterly wind type (4.9%–17.9%). The selection of stations is more sensitive to the proportions of the four weather types than the statistical years and threshold criteria. The monthly and diurnal variations of EXHP, as well as their differences revealed by the three data sets, are varied by weather type. Only using national stations cannot distinguish the spatial differences between the TC type and the easterly wind type, and there is an underestimation for southwesterly wind type and trough type in the mountainous area of southwest Zhejiang. The statistical year and station height are the main reasons for the differences in the duration of EXHP events calculated by different data sets, with the TC type having the largest effect and the southwesterly wind type the smallest

Cytochrome P450s Are Essential for Insecticide Tolerance in the Endoparasitoid Wasp Meteorus pulchricornis (Hymenoptera: Braconidae)

With the widespread application of insecticides, parasitoid wasps may also be under risk when exposed to insecticides directly at their free-living stages. The endoparasitoid wasp Meteorus pulchricornis is the predominant natural enemy of many lepidopteran pests, such as Spodoptera litura and Helicoverpa armigera. The cytochrome P450 monooxygenases constitute a ubiquitous and complex superfamily of hydrophobic, haem-containing enzymes. P450s are involved in the detoxification of many xenobiotics. However, their exact roles in the tolerance mechanism in parasitoids toward insecticides has received less attention. Here, 28 P450 genes in M. pulchricornis were identified from a previously constructed transcriptome dataset. These P450 genes belonged to CYP2, -3, and -4, and mitochondrial clans. Subsequently, eight candidate MpulCYPs were selected from four CYP clans to validate their expression patterns under phoxim, cypermethrin, and chlorfenapyr exposure by qRT-PCR. The results showed that all three insecticides had significant effects on the expression of MpulCYPs. To further study the function of P450s, CYP369B3 was silenced, and its expression levels of CYP369B3 were significantly decreased. Survival analysis indicated that after dsRNA injection, the mortality rate of wasps was significantly increased when M. pulchricornis females were exposed to insecticides compared to control groups. Our findings provide a theoretical base for elucidating the mechanism of insecticide tolerance and promote functional research on P450 genes in parasitoid wasps