1 research outputs found
Light-Driven Self-Cascade Peroxidase-like Nanozymes without Exogenous H<sub>2</sub>O<sub>2</sub>
The peroxidase (POD)-like nanozyme
typically requires the addition
of exogenous H2O2. To address the limitation,
previous work mainly adopted a cascade strategy for H2O2 production. Herein, we propose a new light-driven self-cascade
strategy to construct POD-like nanozymes without exogenous H2O2. The model nanozyme resorcinol–formaldehyde
resin-Fe3+ (RF-Fe3+) is synthesized with the
hydroxyl-rich photocatalytic material RF as the carrier to in situ
chelate metal oxides, which can simultaneously achieve the functions
of in situ H2O2 generation under irradiation
and substrate oxidation via POD-like behavior. Notably, RF-Fe3+ exhibits high affinity to H2O2, attributed
to the excellent adsorption ability and hydroxyl-rich feature of RF.
Furthermore, the dual photoelectrode-assisted photofuel cell was further
constructed with a high-power density of 120 ± 5 μW cm–2 based on the RF-Fe3+ photocathode. This
work not only demonstrates the new self-cascade strategy of in situ
generation of catalysis substrates but also provides an opportunity
to extend the catalytical field