7 research outputs found
NORMAL COORDINATE TREATMENT OF THE COBALTICYANIDE ION,
Author Institution: Los Alamos Scientific Laboratory, University of CaliforniaInfrared and Raman data for , in the solid phase and in aqueous solution have been used in a normal coordinate treatment of the cobalticyanide ion. Data for the completely substituted and isotopic molecules were included. The isotopic shifts are shown to favor the assignment of the deformation mode to a band of higher frequency than that of the stretching mode. The general quadratic force field and the compliance constants will be discussed