The Adsorption of CHS-1 Resin for Cr (VI) of Low Concentration from Electroplating Wastewater

AbstractThe adsorption property of CHS-1 resin for Cr (VI) was investigated by chemical analysis. Experiment results show that CHS-1 resin has the best adsorption ability for Cr (VI) at pH=2-3. The exchange adsorption rate of the resin for Cr (VI) at low concentration is controlled by liquid film diffusion and chemical reaction. The behavior obeys the Freundlich isotherm and Langmuir equation. Its saturated sorption capacity is 347.22mg/g at 298K. The thermodynamic adsorption parameters, enthalpy change ΔH and free energy change ΔG298 of the adsorption are 1.39kJ/mol and -5.3kJ/mol. Cr (VI) adsorbed on CHS-1 resin can be eluted by 5% NaOH -5% NaCl quantitatively without apparent decrease in sorption capacity

Validation of the multiple velocity multiple size group (CFX10.0 N x M MUSIG) model for polydispersed multiphase flows

To simulate dispersed two-phase flows CFD tools for predicting the local particle number density and the size distribution are required. These quantities do not only have a significant effect on rates of mixing, heterogeneous chemical reaction rates or interfacial heat and mass transfers, but also a direct relevance to the hydrodynamics of the total system, such as the flow pattern and flow regime. The Multiple Size Group (MUSIG) model available in the commercial codes CFX-4 and CFX-5 was developed for this purpose. Mathematically, this model is based on the population balance method and the two-fluid modeling approach. The dispersed phase is divided into N size classes. In order to reduce the computational cost, all size groups are assumed to share the same velocity field. This model allows to use a sufficient number of particle size groups required for the coalescence and breakup calculation. Nevertheless, the assumption also restricts its applicability to homogeneous dispersed flows. We refer to the CFX MUSIG model mentioned above as the homogeneous model, which fails to predict the correct phase distribution when heterogeneous particle motion becomes important. In many flows the non-drag forces play an essential role with respect to the bubble motion. Especially, the lift force acting on large deformed bubbles, which is dominated by the asymmetrical wake, has a direction opposite to the shear induced lift force on a small bubble. This bubble separation cannot be predicted by the homogeneous MUSIG model. In order to overcome this shortcoming we developed an efficient inhomogeneous MUSIG model in cooperation with ANSYS CFX. A novel multiple velocity multiple size group model, which incorporates the population balance equation into the multi-fluid modeling framework, was proposed. The validation of this new model is discussed in this report