225 research outputs found

    Structure of halo and quasi-halo helium–helium–alkali trimers

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    We report a diffusion Monte Carlo study of A4He2 and A4He3He trimers’ structural properties, were A is one of the alkali atoms 6,7Li, 23Na, 39K, 85Rb or 133Cs. Some of them are in a pure halo state, characterized by large spatial extent and universality, while some are close to the halo limit. The theoretical analysis of these trimers enables insight on how structural properties of weakly bound systems change when approaching the halo edge. For that purpose, two-variable distributions of inter-particle separations and angles were calculated. Extreme spatial extensions of some trimers with 3He confirm their halo nature. Although all the considered systems are floppy, trimers with all bound dimer subsystems are less spread and have significantly lower percentage of quasi-linear configurations than those which have at least one unbound dimer subsystem.Postprint (author's final draft

    Ground-state properties of weakly bound helium-alkali trimers

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    Weakly bound triatomic molecules consisting of two helium atoms and one alkali metal atom are studied by means of the diffusion Monte Carlo method. We determined the stability of 4He2A, 4He3HeA, and 3He2A, where A is one of the alkali atoms Li, Na, K, Rb, or Cs. Some of the trimers with 3He are predicted to be self-bound for the first time, but this is observed to be dependent on the He–A interaction potential model. In addition to the ground-state energy of the trimers, we determined their density, radial, and angular distributions. Many of them are spatially very extended, which qualifies them as quantum halo statesPostprint (author's final draft

    Performance and Economic Comparison of Solar Cooling Configurations

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    In this paper a performance and economic comparison of solar cooling configurations using a new integrated approach combining the hourly thermal-optical performance assessment of the solar systems with the economic aspects has been conducted. Evacuated tube solar collectors with single effect LiBr absorption chiller and compact solar linear concentrating Fresnel collectors with single effect or medium temperature double effect LiBr absorption chiller have been taken into account. Considering that all the produced cold thermal energy could be delivered to a final user, the latter solar cooling configuration shows the possibility to have the Levelized Cost Of Cooling (LCOC) comparable with standard electric compression cooling. However, technology improvements and economy of scale are necessary in order to reduce solar field cost in the range 150-250 €/m2

    Elusive structure of helium trimers

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    Over the years many He–He interaction potentials have been developed, some very sophisticated, including various corrections beyond the Born–Oppenheimer approximation. Most of them were used to predict properties of helium dimers and trimers, examples of exotic quantum states, whose experimental study proved to be very challenging. Recently, detailed structural properties of helium trimers were measured for the first time, allowing a comparison with theoretical predictions and possibly enabling the evaluation of different interaction potentials. The comparisons already made included adjusting the maxima of both theoretical and experimental correlation functions to one, so the overall agreement between theory and experiment appeared satisfactory. However, no attempt was made to evaluate the quality of the interaction potentials used in the calculations. In this work, we calculate the experimentally measured correlation functions using both new and old potentials, compare them with experimental data and rank the potentials. We use diffusion Monte Carlo simulations at T = 0, which give within statistical noise exact results of the ground state properties. All models predict both trimers 4He3 and 4He23{}_{2}{}^{3}He to be in a quantum halo state.Postprint (author's final draft

    Van der Waals five-body size-energy universality

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    A universal relationship between scaled size and scaled energy is explored in five-body self-bound quantum systems. The ground-state binding energy and structure properties are obtained by means of the diffusion Monte Carlo method. We use pure estimators to eliminate any residual bias in the estimation of the cluster size. Strengthening the inter-particle interaction, we extend the exploration from the halo region to classical systems. Universal scaled size-scaled energy line, which does not depend on the short-range potential details and binding strength, is found for homogeneous pentamers with interaction potentials decaying at long range predominantly as r-6. For mixed pentamers, we discuss under which conditions the universal line can approximately describe the size- energy ratio. Our data is compatible with generalized Tjon lines, which assume a linear dependence between the binding energy of the pentamers and the one of tetramers, when both are divided by the trimer energies.Postprint (published version

    Universality of size-energy ratio in four-body systems

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    Universal relationship of scaled size and scaled energy, which was previously established for two- and three-body systems in their ground state, is examined for four-body systems, using Quantum Monte Carlo simulations. We study in detail the halo region, in which systems are extremely weakly bound. Strengthening the interparticle interaction we extend the exploration all the way to classical systems. Universal size-energy law is found for homogeneous tetramers in the case of interaction potentials decaying predominantly as r-6. In the case of mixed tetramers, we also show under which conditions the universal line can approximately describe the size-energy ratio. The universal law can be used to extract ground-state energy from experimentally measurable structural characteristics, as well as for evaluation of theoretical interaction models.Postprint (published version

    Levelized Cost of Heat for Linear Fresnel Concentrated Solar Systems

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    In this paper, a deep investigation upon levelized cost of heat (LCOH) produced by small-scale solar linear concentrating Fresnel collectors (CSLFC) is proposed. Solar industrial process heat applications have temperature requirements from about 60 °C to 260 °C. CSLFCs can effectively integrate conventional fossil fuel thermal systems. The study is addressed to assess technology cost projection needed to achieve competitive LCOH. So, on the basis of a framework specifically developed for these economic assessments, the best investment scenarios, in terms of industrial application, geographical location and technical design solutions, where to effectively apply the technology of CSLFC, are highlighted. The analysis has been focused on specific cost of several existing CSLFCs associated with declared performances at different operating temperatures. Two main classes of CSLFC with different total efficiency (optical and thermal) corresponding to various design solutions and specific cost were selected. The expected performances in the whole application temperature range have been evaluated through Glayx Tech proprietary simulation code, including optical and thermal unsteady analysis. A huge database coming from full CSLFC simulation varying latitude, yearly DNI, operating fluid, outlet temperature, thermal storage options, has been collected. CLSFC design and performance requirements are the key-choice to achieve competitive LCOH: the use of high efficiency – high cost components is not always rewarding in terms of final LCOH and must be attentively decided basing on site, irradiation, heat quality and LCOH target. In this perspective, CLSFCs are the most promising for industrial small scale heat applications since they show the greatest potential to reduce manufacturing costs

    “It’s like my kid came back overnight”: Experiences of trans and non-binary young people and their families seeking, finding and engaging with clinical care in England

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    Background: Trans and non-binary children and young people in England, UK struggle to gain access to affirming clinical care, despite the international research evidence pointing towards this best practice approach. Concurrently, they are subject to constant discussion in UK national media and politics, where many negative assumptions are made about their needs, experiences and clinical provision. Their journey to seek appropriate care has not yet been documented. Aims: We trace the experiences of trans and non-binary children and youth and their families in their decision to seek, searches for and experiences with affirmative and non-affirmative clinical input for help with their gender. Method: 27 dyadic, semi-structured interviews were undertaken with trans and non-binary children and young people and their parents from 13 families. Results: The process of seeking support via National Health Service clinical routes in England, UK is beset with lengthy waiting lists, issues with geographical inaccessibility, a lack of relevant clinical knowledge, and a failure to recognise the value of family expertise. Family doctors provide contraceptive hormones in lieu of proper access to puberty blocking or gender affirming hormones, and most families resort to private care they can ill afford. Discussion: Training in gender identity and gender dysphoria is recommended for both family doctors, and children’s mental health services. Gender identity development services could be decentralised, with local hubs offering more accessible support
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