3,325 research outputs found
Long-range electron transfer in structurally engineered pentaammineruthenium (histidine-62) cytochrome c
In many biological processes, long-range electron transfer (ET) plays a key role. When the three-dimensional structures of proteins are accurately known, use of modified proteins and protein-protein complexes provides an experimental approach to study ET rates between two metal centers. For Ru(His)- modified proteins, the introduction of histidine residues at any desired surface location by site-directed mutagenesis opens the way for systematic investigations of ET pathways
Spectroscopic and redox properties of amine-unctionalized K_2[Os-^(II)(bpy)(CN)_4] complexes
We report the first examples of amine-functionalized K_2[Os^(II)(bpy)(CN)_4] (bpy = 2,2'-bipyridine) complexes. The tetracyanoosmate complexes were prepared by UV irradiation (λ = 254 nm) of K_4[Os^(II)(CN)_6] and primary amine-functionalized bpy ligands in acidic aqueous media. The aqueous solution pH dependences of the spectroscopic and redox properties of 4,4'- and 5,5'-substituted complexes have been investigated. The pendant amine functional groups and coordinated cyanide ligands are basic sites that can be sequentially protonated, thereby allowing systematic tuning of electrochemical and optical spectroscopic properties
Embedded Star Formation in the Eagle Nebula with Spitzer/GLIMPSE
We present new Spitzer photometry of the Eagle Nebula (M16, containing the
optical cluster NGC 6611) combined with near-infrared photometry from 2MASS. We
use dust radiative transfer models, mid-infrared and near-infrared color-color
analysis, and mid-infrared spectral indices to analyze point source spectral
energy distributions, select candidate young stellar objects (YSOs), and
constrain their mass and evolutionary state. Comparison of the different
protostellar selection methods shows that mid-infrared methods are consistent,
but as has been known for some time, near-infrared-only analysis misses some
young objects. We reveal more than 400 protostellar candidates, including one
massive young stellar object (YSO) that has not been previously highlighted.
The YSO distribution supports a picture of distributed low-level star
formation, with no strong evidence of triggered star formation in the
``pillars''. We confirm the youth of NGC 6611 by a large fraction of
infrared-excess sources, and reveal a younger cluster of YSOs in the nearby
molecular cloud. Analysis of the YSO clustering properties shows a possible
imprint of the molecular cloud's Jeans length. Multiwavelength mid-IR imaging
thus allows us to analyze the protostellar population, to measure the dust
temperature and column density, and to relate these in a consistent picture of
star formation in M16.Comment: 16p preprint - ApJ accepte
Searches for Long Lived Neutral Particles
An intriguing possibility for TeV scale physics is the existence of neutral
long lived particles (LOLIPs) that subsequently decay into SM states. Such
particles are many cases indistinguishable from missing transverse energy (MET)
at colliders. We propose new methods to search for these particles using
neutrino telescopes. We study their detection prospects, assuming production
either at the LHC or through dark matter (DM) annihilations in the Sun and the
Earth. We find that the sensitivity for LOLIPs produced at the LHC is limited
by luminosity and detection energy thresholds. On the other hand, in the case
of DM annihilation into LOLIPs, the sensitivity of neutrino telescopes is
promising and may extend beyond the reach of upcoming direct detection
experiments. In the context of low scale hidden sectors weakly coupled to the
SM, such indirect searches allow to probe couplings as small as 10^-15.Comment: 22 pages, 6 figure
Absolute diffuse calibration of IRAC through mid-infrared and radio study of HII regions
We investigate the diffuse absolute calibration of the InfraRed Array Camera
on the Spitzer Space Telescope at 8.0microns using a sample of 43 HII regions
with a wide range of morphologies near GLON=312deg. For each region we
carefully measure sky-subtracted,point-source- subtracted, areally-integrated
IRAC 8.0-micron fluxes and compare these with Midcourse Space eXperiment (MSX)
8.3-micron images at two different spatial resolutions, and with radio
continuum maps. We determine an accurate median ratio of IRAC
8.0-micron/MSX\8.3-micron fluxes, of 1.55+/-0.15. From robust spectral energy
distributions of these regions we conclude that the present 8.0-micron diffuse
calibration of the SST is 36% too high compared with the MSX validated
calibration, perhaps due to scattered light inside the camera. This is an
independent confirmation of the result derived for the diffuse calibration of
IRAC by the Spitzer Science Center (SSC).
From regression analyses we find that 843-MHz radio fluxes of HII regions and
mid-infrared (MIR) fluxes are linearly related for MSX at 8.3-microns and
Spitzer at 8.0 microns, confirming the earlier MSX result by Cohen & Green. The
median ratio of MIR/843-MHz diffuse continuum fluxes is 600 times smaller in
nonthermal than thermal regions, making it a sharp discriminant. The ratios are
largely independent of morphology up to a size of ~24 arcsec. We provide
homogeneous radio and MIR morphologies for all sources. MIR morphology is not
uniquely related to radio structure. Compact regions may have MIR filaments
and/or diffuse haloes, perhaps infrared counter- parts to weakly ionized radio
haloes found around compact HII regions. We offer two IRAC colour-colour plots
as quantitative diagnostics of diffuse HII regions.Comment: 29 pages, LaTeX (aastex), incl. 31 PostScript (ps,eps) figures and 5
tables. Accepted by MNRAS (main journal). Replaced an unused file and added
this URL for people wishing to download a version with high-resolution
images: http://www.astro.wisc.edu/sirtf/martin.hii.accepted.pd
RECAST: Extending the Impact of Existing Analyses
Searches for new physics by experimental collaborations represent a
significant investment in time and resources. Often these searches are
sensitive to a broader class of models than they were originally designed to
test. We aim to extend the impact of existing searches through a technique we
call 'recasting'. After considering several examples, which illustrate the
issues and subtleties involved, we present RECAST, a framework designed to
facilitate the usage of this technique.Comment: 13 pages, 4 figure
The FUSE survey of OVI absorption in and near the Galaxy
We present FUSE observations of OVI absorption in a sample of 100
extragalactic targets and 2 distant halo stars. We describe the details of the
calibration, alignment in velocity, continuum fitting, and manner in which
contaminants were removed (Galactic H2, absorption intrinsic to the background
target and intergalactic Ly-beta lines). We searched for OVI absorption in the
velocity range -1200 to 1200 km/s. With a few exceptions, we only find OVI
between -400 and 400 km/s; the exceptions may be intergalactic OVI. We discuss
the separation of the observed OVI absorption into components associated with
the Galactic halo and components at high-velocity, which are probably located
in the neighborhood of the Galaxy. We describe the measurements of equivalent
width and column density, and we analyze the different contributions to the
errors. We conclude that low-velocity Galactic OVI absorption occurs along all
sightlines - the few non-detections only occur in noisy spectra. We further
show that high-velocity OVI is very common, having equivalent width >65 mAA in
50% of the sightlines and >30 mAA in 70% of the high-quality sightlines. The
high-velocity OVI absorption has velocities relative to the LSR of
+/-(100--330) km/s; there is no correlation between velocity and absorption
strength. We present 50 km/s wide OVI channel maps. These show evidence for the
imprint of Galactic rotation. They also highlight two known HI high-velocity
clouds (complex~C and the Magellanic Stream). The channel maps further show
that OVI at velocities <-200 km/s occurs along all sightlines in the region
l=20-150, b200 km/s occurs along all sightlines
in the region l=180-300, b>20 (abbreviated).Comment: 85 pages, 127 figures, 13 color figures, 3 tables, AASTeX preprint
format. All figures are in PNG format due to space concerns. Bound copies of
manuscript and two accompanying articles are available upon request.
submitted to ApJ
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