937 research outputs found
Iron Displacements and Magnetoelastic Coupling in the Spin-Ladder Compound BaFe2Se3
We report long-range ordered antiferromagnetism concomitant with local iron
displacements in the spin-ladder compound BaFeSe. Short-range magnetic
correlations, present at room temperature, develop into long-range
antiferromagnetic order below T = 256 K, with no superconductivity down to
1.8 K. Built of ferromagnetic Fe plaquettes, the magnetic ground state
correlates with local displacements of the Fe atoms. These iron displacements
imply significant magnetoelastic coupling in FeX-based materials, an
ingredient hypothesized to be important in the emergence of superconductivity.
This result also suggests that knowledge of these local displacements is
essential for properly understanding the electronic structure of these systems.
As with the copper oxide superconductors two decades ago, our results highlight
the importance of reduced dimensionality spin ladder compounds in the study of
the coupling of spin, charge, and atom positions in superconducting materials
Density of Phonon States in Superconducting FeSe as a Function of Temperature and Pressure
The temperature and pressure dependence of the partial density of phonon
states of iron atoms in superconducting Fe1.01Se was studied by 57Fe nuclear
inelastic scattering (NIS). The high energy resolution allows for a detailed
observation of spectral properties. A sharpening of the optical phonon modes
and shift of all spectral features towards higher energies by ~4% with
decreasing temperature from 296 K to 10 K was found. However, no detectable
change at the tetragonal - orthorhombic phase transition around 100 K was
observed. Application of a pressure of 6.7 GPa, connected with an increase of
the superconducting temperature from 8 K to 34 K, results in an increase of the
optical phonon mode energies at 296 K by ~12%, and an even more pronounced
increase for the lowest-lying transversal acoustic mode. Despite these strong
pressure-induced modifications of the phonon-DOS we conclude that the
pronounced increase of Tc in Fe1.01Se with pressure cannot be described in the
framework of classical electron-phonon coupling. This result suggests the
importance of spin fluctuations to the observed superconductivity
Disorder from order among anisotropic next-nearest-neighbor Ising spin chains in SrHoO
We describe why Ising spin chains with competing interactions in segregate into ordered and disordered ensembles at low temperatures
(). Using elastic neutron scattering, magnetization, and specific heat
measurements, the two distinct spin chains are inferred to have N\'eel
() and double-N\'eel
() ground states respectively. Below
~K, the N\'eel chains develop three dimensional (3D) long
range order (LRO), which arrests further thermal equilibration of the
double-N\'eel chains so they remain in a disordered incommensurate state for
below ~K. distills an important
feature of incommensurate low dimensional magnetism: kinetically trapped
topological defects in a quasidimensional spin system can preclude order
in dimensions.Comment: 10 pages, 10 figure
Factors associated with alcohol reduction in harmful and hazardous drinkers following alcohol brief intervention in Scotland: a qualitative enquiry
Background: Alcohol Brief Intervention (ABI) uses a motivational counselling approach to support individuals to
reduce excessive alcohol consumption. There is growing evidence on ABI’s use within various health care settings,
although how they work and which components enhance success is largely unknown. This paper reports on the
qualitative part of a mixed methods study. It explores enablers and barriers associated with alcohol reduction
following an ABI. It focuses on alcohol’s place within participants’ lives and their personal perspectives on reducing
consumption. There are a number of randomised controlled trials in this field though few ABI studies have
addressed the experiences of hazardous/harmful drinkers. This study examines factors associated with alcohol
reduction in harmful/hazardous drinkers following ABI.
Methods: This qualitative study was underpinned by a realist evaluation approach and involved semistructured
interviews with ten harmful or hazardous alcohol drinkers. Participants (n = 10) were from the
intervention arm of a randomised controlled trial (n = 124). All had received ABI, a 20 min motivational
counselling interview, six months previously, and had reduced their alcohol consumption. Interviews were
recorded, transcribed verbatim and thematically analysed.
Results: Participants described their views on alcohol, its’ place in their lives, their personal perspectives on
reducing their consumption and future aspirations.
Conclusions: The findings provide an insight into participants’ views on alcohol, ABI, and the barriers and enablers
to change. Participants described a cost benefit analysis, with some conscious consideration of the advantages and
disadvantages of reducing intake or abstaining from alcohol. Findings suggest that, whilst hospital admission can act
as a catalyst, encouraging individuals to reflect on their alcohol consumption through ABI may consolidate this, turning
this reflective moment into action. Sustainability may be enhanced by the presence of a ‘significant other’ who
encourages and experiences benefit. In addition having a purpose or structure with activities linked to employment
and/or social and leisure pursuits offers the potential to enhance and sustain reduced alcohol consumption.
Trial registration: Trial registration number TRN NCT00982306 September 22nd 200
Paramagnetic Phase of a Heavy-Fermion Compound, CeFePO, Probed by 57Fe M\"{o}ssbauer Spectroscopy
57Fe M\"{o}ssbauer spectroscopy was applied to an iron-based layered compound
CeFePO. At temperatures from 9.4 to 293 K, no magnetic splitting was observed
in the M\"ossbauer spectra of CeFePO indicating a paramagnetic phase of the Fe
magnetic sublattice. All the spectra were fitted with a small quadrupole
splitting, and the Debye temperature of CeFePO was found to be \sim448 K. The
isomer shift at room temperature, 0.32 mm/s, was almost equal to those of
LnFeAsO (Ln = La, Ce, Sm). Comparing s-electron density using the isomer shifts
and unit cell volumes, it was found that the Fe of CeFePO has a similar valence
state to other layered iron-based quaternary oxypnictides except LaFePO
Tuning the Charge Density Wave and Superconductivity in CuxTaS2
We report the characterization of layered, 2H-type CuxTaS2, for x between 0
and 0.12. The charge density wave (CDW), at 70 K for TaS2, is destabilized with
Cu doping. The sub-1K superconducting transition in undoped 2H-TaS2 jumps
quickly to 2.5 K at low x, increases to 4.5 K at the optimal composition
Cu0.04TaS2, and then decreases at higher x. The electronic contribution to the
specific heat, first increasing and then decreasing as a function of Cu
content, is 12 mJ mol-1 K-2 at Cu0.04TaS2. Electron diffraction studies show
that the CDW remains present at the optimal superconducting composition, but
with both a changed q vector and decreased coherence length. We present an
electronic phase diagram for the system.Comment: 7 pages, 9 figures. To be published in Physical Review
Extreme Sensitivity of Superconductivity to Stoichiometry in FeSe (Fe1+dSe)
The recently discovered iron arsenide superconductors, which display
superconducting transition temperatures as high as 55 K, appear to share a
number of general features with high-Tc cuprates, including proximity to a
magnetically ordered state and robustness of the superconductivity in the
presence of disorder. Here we show that superconductivity in Fe1+dSe, the
parent compound of the superconducting arsenide family, is destroyed by very
small changes in stoichiometry. Further, we show that non-superconducting
Fe1+dSe is not magnetically ordered down to low temperatures. These results
suggest that robust superconductivity and immediate instability against an
ordered magnetic state should not be considered as intrinsic characteristics of
iron-based superconducting systems, and that Fe1+dSe may present a unique
opportunity for determining which materials characteristics are critical to the
existence of superconductivity in high Tc iron arsenide superconductors and
which are not.Comment: Updated to reflect final version and include journal referenc
IDLaS-NL – A platform for running customized studies on individual differences in Dutch language skills via the internet
We introduce the Individual Differences in Language Skills (IDLaS-NL) web platform, which enables users to run studies on individual differences in Dutch language skills via the internet. IDLaS-NL consists of 35 behavioral tests, previously validated in participants aged between 18 and 30 years. The platform provides an intuitive graphical interface for users to select the tests they wish to include in their research, to divide these tests into different sessions and to determine their order. Moreover, for standardized administration the platform provides an application (an emulated browser) wherein the tests are run. Results can be retrieved by mouse click in the graphical interface and are provided as CSV-file output via email. Similarly, the graphical interface enables researchers to modify and delete their study configurations. IDLaS-NL is intended for researchers, clinicians, educators and in general anyone conducting fundamental research into language and general cognitive skills; it is not intended for diagnostic purposes. All platform services are free of charge. Here, we provide a description of its workings as well as instructions for using the platform. The IDLaS-NL platform can be accessed at www.mpi.nl/idlas-nl
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