1,101 research outputs found
Structural, optical and magnetic properties of Zn1−xMnxO micro-rod arrays synthesized by spray pyrolysis method
Undoped and Mn-doped ZnO micro-rod arrays were fabricated by the spray pyrolysis method on glass substrates. X-ray diffraction and scanning electron microscopy showed that these micro-rod arrays had a polycrystalline wurtzite structure and high c-axis preferred orientation. Photoluminescence studies at 10 K show that the increase of manganese content leads to a relative decrease in deep level band intensity with respect to undoped ZnO. Magnetic measurements indicated that undoped ZnO was diamagnetic in nature whereas Mn-doped ZnO samples exhibited ferromagnetic behavior at room temperature, which is possibly related to the substitution of Mn ions (Mn2+) for Zn ions in the ZnO lattice
Classifying the metal dependence of uncharacterized nitrogenases
Nitrogenase enzymes have evolved complex iron–sulfur (Fe–S) containing cofactors that most commonly contain molybdenum (MoFe, Nif) as a heterometal but also exist as vanadium (VFe, Vnf) and heterometal-independent (Fe-only, Anf) forms. All three varieties are capable of the reduction of dinitrogen (N_2) to ammonia (NH_3) but exhibit differences in catalytic rates and substrate specificity unique to metal type. Recently, N_2 reduction activity was observed in archaeal methanotrophs and methanogens that encode for nitrogenase homologs which do not cluster phylogenetically with previously characterized nitrogenases. To gain insight into the metal cofactors of these uncharacterized nitrogenase homologs, predicted three-dimensional structures of the nitrogenase active site metal-cofactor binding subunits NifD, VnfD, and AnfD were generated and compared. Dendrograms based on structural similarity indicate nitrogenase homologs cluster based on heterometal content and that uncharacterized nitrogenase D homologs cluster with NifD, providing evidence that the structure of the enzyme has evolved in response to metal utilization. Characterization of the structural environment of the nitrogenase active site revealed amino acid variations that are unique to each class of nitrogenase as defined by heterometal cofactor content; uncharacterized nitrogenases contain amino acids near the active site most similar to NifD. Together, these results suggest that uncharacterized nitrogenase homologs present in numerous anaerobic methanogens, archaeal methanotrophs, and firmicutes bind FeMo-co in their active site, and add to growing evidence that diversification of metal utilization likely occurred in an anoxic habitat
Structural, optical and magnetic properties of Cr doped ZnO microrods prepared by spray pyrolysis
A series of Cr-doped ZnO micro-rod arrays were fabricated by a spray pyrolysis method. X-ray diffraction patterns
of the samples showed that the undoped and Cr-doped ZnO microrods exhibit hexagonal crystal structure. Surface
morphology analysis of the samples has revealed that pure ZnO sample has a hexagonal microrod morphology. From X-ray photoelectron spectroscopy studies, the Cr 2p3/2 binding energy is found to be 577.34 eV indicating that the electron binding energy of the Cr in ZnO is almost the same as the binding energy of Cr3+ states in Cr2O3. The optical band gap Eg decreases slightly from 3.26 to 3.15 eV with the increase of actual Cr content from x = 0.00 to 4.63 at % in ZnO. Photoluminescence studies at 10 K show that the incorporation of chromium leads to a relative increase of deep level band intensity. It was also observed that Cr doped samples clearly showed ferromagnetic behavior; however, 2.49 % Cr doped ZnO showed remnant magnetization higher than that of 1.07 % and 4.63 % Cr doped samples, while 4.63 % Cr doped ZnO samples had a coercive field higher than the other dopings
Discovery of a New Nearby Star
We report the discovery of a nearby star with a very large proper motion of
5.06 +/- 0.03 arcsec/yr. The star is called SO025300.5+165258 and referred to
herein as HPMS (high proper motion star). The discovery came as a result of a
search of the SkyMorph database, a sensitive and persistent survey that is well
suited for finding stars with high proper motions. There are currently only 7
known stars with proper motions > 5 arcsec/yr. We have determined a preliminary
value for the parallax of 0.43 +/- 0.13 arcsec. If this value holds our new
star ranks behind only the Alpha Centauri system (including Proxima Centauri)
and Barnard's star in the list of our nearest stellar neighbors. The spectrum
and measured tangential velocity indicate that HPMS is a main-sequence star
with spectral type M6.5. However, if our distance measurement is correct, the
HPMS is underluminous by 1.2 +/- 0.7 mag.Comment: 5 pages, 3 figures. Submitted to ApJ Letter
Microbial diversity and iron oxidation at Okuoku-hachikurou Onsen, a Japanese hot spring analog of Precambrian iron formations
Banded iron formations (BIFs) are rock deposits common in the Archean and Paleoproterozoic (and regionally Neoproterozoic) sedimentary successions. Multiple hypotheses for their deposition exist, principally invoking the precipitation of iron via the metabolic activities of oxygenic, photoferrotrophic, and/or aerobic iron-oxidizing bacteria. Some isolated environments support chemistry and mineralogy analogous to processes involved in BIF deposition, and their study can aid in untangling the factors that lead to iron precipitation. One such process analog system occurs at Okuoku-hachikurou (OHK) Onsen in Akita Prefecture, Japan. OHK is an iron- and CO_2-rich, circumneutral hot spring that produces a range of precipitated mineral textures containing fine laminae of aragonite and iron oxides that resemble BIF fabrics. Here, we have performed 16S rRNA gene amplicon sequencing of microbial communities across the range of microenvironments in OHK to describe the microbial diversity present and to gain insight into the cycling of iron, oxygen, and carbon in this ecosystem. These analyses suggest that productivity at OHK is based on aerobic iron-oxidizing Gallionellaceae. In contrast to other BIF analog sites, Cyanobacteria, anoxygenic phototrophs, and iron-reducing micro-organisms are present at only low abundances. These observations support a hypothesis where low growth yields and the high stoichiometry of iron oxidized per carbon fixed by aerobic iron-oxidizing chemoautotrophs like Gallionellaceae result in accumulation of iron oxide phases without stoichiometric buildup of organic matter. This system supports little dissimilatory iron reduction, further setting OHK apart from other process analog sites where iron oxidation is primarily driven by phototrophic organisms. This positions OHK as a study area where the controls on primary productivity in iron-rich environments can be further elucidated. When compared with geological data, the metabolisms and mineralogy at OHK are most similar to specific BIF occurrences deposited after the Great Oxygenation Event, and generally discordant with those that accumulated before it
Effects of Cu diffusion-doping on structural, optical and magnetic properties of ZnO nanorod arrays grown by VPT
Well-aligned ZnO nanorods were prepared by the vapor phase transport method on Si covered with a ZnO buffer layer. After the nanostructure growth, Cu was doped into the ZnO nanorods by diffusion at three different temperatures and for different times. Undoped and Cu diffusion-doped ZnO samples are highly textured, with the c axis of the wurtzite structure along the growth direction. The incorporation of Cu caused some slight changes in the nanorod alignment, although the wurtzite crystal structure was maintained. X-ray photoelectron spectroscopy measurements revealed that Cu ions were in a divalent state and substituted for the Zn2+ ions of the ZnO matrix. Photoluminescence results at 10 K indicate that the incorporation of copper leads to a relative increase of Cu-related structured green band deep level intensity. Magnetic measurements revealed that both undoped and Cu diffusion-doped ZnO samples exhibited room temperature ferromagnetism. It was also found that bound magnetic polarons play an important role in the appearance of room temperature ferromagnetism in Cu diffusion-doped ZnO nanorods
Chandra Observation of the Cluster Environment of a WAT Radio Source in Abell 1446
Wide-angle tail (WAT) radio sources are often found in the centers of galaxy
clusters where intracluster medium (ICM) ram pressure may bend the lobes into
their characteristic C-shape. We examine the low redshift (z=0.1035) cluster
Abell 1446, host to the WAT radio source 1159+583. The cluster exhibits
possible evidence for a small-scale cluster-subcluster merger as a cause of the
WAT radio source morphology. This evidence includes the presence of temperature
and pressure substructure along the line that bisects the WAT as well as a
possible wake of stripped interstellar material or a disrupted cool core to the
southeast of the host galaxy. A filament to the north may represent cool,
infalling gas that's contributing to the WAT bending while spectroscopically
determined redshifts of member galaxies may indicate some component of a merger
occurring along the line-of-sight. The WAT model of high flow velocity and low
lobe density is examined as another scenario for the bending of 1159+583. It
has been argued that such a model would allow the ram pressure due to the
galaxy's slow motion through the ICM to shape the WAT source. A temperature
profile shows that the cluster is isothermal (kT= 4.0 keV) in a series of
annuli reaching a radius of 400 kpc. There is no evidence of an ongoing cooling
flow. Temperature, abundance, pressure, density, and mass profiles, as well as
two-dimensional maps of temperature and pressure are presented.Comment: 40 AASTeX pages including 15 postscript figures; accepted for
publication in Ap
Current-Driven Conformational Changes, Charging and Negative Differential Resistance in Molecular Wires
We introduce a theoretical approach based on scattering theory and total
energy methods that treats transport non-linearities, conformational changes
and charging effects in molecular wires in a unified way. We apply this
approach to molecular wires consisting of chain molecules with different
electronic and structural properties bonded to metal contacts. We show that
non-linear transport in all of these systems can be understood in terms of a
single physical mechanism and predict that negative differential resistance at
high bias should be a generic property of such molecular wires.Comment: 9 pages, 4 figure
Control of ZnO nanowire arrays by nanosphere lithography (NSL) on laser-produced ZnO substrates
Abstract Nanosphere lithography (NSL) is a successful technique for fabricating highlyordered arrays of ZnO nanowires typically on sapphire and GaN substrates. In this work, we investigate the use of thin ZnO films deposited on Si by pulsed laser deposition (PLD) as the substrate. This has a number of advantages over the alternatives above, including cost and potential scalability of production and it removes any issue of inadvertent n-type doping of nanowires by diffusion from the substrate. We demonstrate ordered arrays of ZnO nanowires, on ZnO-coated substrates by PLD, using a conventional NSL technique with gold as the catalyst. The nanowires were produced by Vapor Phase Transport (VPT) growth in a tube furnace system and grew only on the areas pre-patterned by Au. We have also investigated the growth of ZnO nanowires using ZnO catalyst points deposited by PLD through an NSL mask on a bare silicon substrate
Merger Dynamics of the Pair of Galaxy Clusters -- A399 and A401
Convincing evidence of a past interaction between two rich clusters A399 and
A401 was recently found by the X-ray imaging observations. In this paper we
examine the structure and dynamics of this pair of galaxy clusters. A
mixture-modeling algorithm has been applied to obtain a robust partition into
two clusters, which allows us to discuss the virial mass and velocity
distribution for each cluster. Assuming that these two clusters follow a linear
orbit and they have once experienced a close encounter, we model the binary
cluster as a two-body system. As a result, four gravitationally bound solutions
are obtained. The recent X-ray observations seem to favor a scenario in which
the two clusters with a true separation of Mpc are currently
expanding at 583 km/s along the direction with a projection angle of 67.5
degree, and they will reach a maximum extent of Mpc in about
Gyr.Comment: 11 pages, including 6 EPS figures and 4 tables, uses chjaa.cls,
Accepted by the ChJA
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