3 research outputs found
Extensional viscosity of copper nanowire suspensions in an aqueous polymer solution
Suspensions of copper nanowires are emerging as new electronic inks for
next-generation flexible electronics. Using a novel surface acoustic wave
driven extensional flow technique we are able to perform currently lacking
analysis of these suspensions and their complex buffer. We observe extensional
viscosities from 3 mPas (1 mPas shear viscosity) to 37.2
Pas via changes in the suspension concentration, thus capturing low
viscosities that have been historically very challenging to measure. These
changes equate to an increase in the relative extensional viscosity of nearly
12,200 times at a volume fraction of just 0.027. We also find that interactions
between the wires and the necessary polymer additive affect the rheology
strongly. Polymer-induced elasticity shows a reduction as the buffer relaxation
time falls from 819 to 59 s above a critical particle concentration. The
results and technique presented here should aid in the future formulation of
these promising nanowire suspensions and their efficient application as inks
and coatings.Comment: 7 pages, 5 figures, under review for Soft Matter RS
Motility induced changes in viscosity of suspensions of swimming microbes in extensional flows
Suspensions of motile cells are model systems for understanding the unique
mechanical properties of living materials which often consist of ensembles of
self-propelled particles. We present here a quantitative comparison of theory
against experiment for the rheology of such suspensions. The influence of
motility on viscosities of cell suspensions is studied using a novel
acoustically-driven microfluidic capillary-breakup extensional rheometer.
Motility increases the extensional viscosity of suspensions of algal pullers,
but decreases it in the case of bacterial or sperm pushers. A recent model
[Saintillan, Phys. Rev. E, 2010, 81:56307] for dilute active suspensions is
extended to obtain predictions for higher concentrations, after independently
obtaining parameters such as swimming speeds and diffusivities. We show that
details of body and flagellar shape can significantly determine macroscale
rheological behaviour.Comment: 12 pages, 1 appendix, 7 figures, submitted to Soft Matter - under
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