Growth of zinc oxide nanowires for field emission application

There is much interest in the development of field emitters for a number of applications, such as field emission displays and small x-ray sources. For these applications robust, sharp field emitters, capable of delivering suffi- cient current densities are needed. This thesis describes the development of an apparatus to test the field emission properties of a variety of sam- ples. This apparatus included a metal electrode to measure current-voltage characteristics, and a phosphor electrode to determine distribution and uni- formity of emission. Results are presented from a variety of zinc oxide (ZnO) nanostructures (grown by vapour phase transport, chemical bath, and pulsed laser deposition), and zirconium alloy films. The samples were analysed by a variety of techniques such as scanning electron microscopy and x-ray diffrac- tion, and their field emission properties determined using the field emission apparatus developed. A new treatment for analysing field emission results was developed and applied to the data. The results of these analyses were evaluated in the context of the current literature. The suitability of the aforementioned growth methods for growing ZnO nanostructures for field emission applications was investigated. The effect of inter-rod spacing and aluminium doping on the field emission properties of ZnO nanostructures was also investigated

Methodology of laser processing for precise control of surface micro-topology

Laser surface texturing of materials potentially offers precise control of surface structure and mechanical properties. This has a wide range of applications such as control of frictional forces, control of bond strength in interference fit joints, and production of antifouling surfaces. To achieve such texturing in a well-defined, useful manner, precise control of the applied laser processing parameters over a sizeable surface area is required. This paper presents the development of a method for creating highly repeatable and predetermined moiré textured patterns on metallic samples via laser processing. While the method developed is broadly applicable to various materials and laser systems, in the example detailed here the surfaces of cylindrical stainless steel samples were processed with a pulsed CO2 laser. The resulting modified surfaces contained texture geometries with pre-definable peak-to-peak widths, valleyto-peak heights, and texture directions. The method of achieving this theoretically and experimentally is detailed in this paper. The relationship between the laser processing parameters and resulting diameter increase was confirmed via Design of Experiment response surface methodology. Precise control of the laser textured cylindrical surface outer diameter and texture pattern are key factors in determining the potential suitability of this process for application to the production of interference fit fasteners. The effects of the laser processing parameters and topologies of the resulting re-solidified metal profile on the surfaces were assessed in detail with a focus on this application

Laser surface texturing of stainless steel 316L cylindrical pins for interference fit applications

This study is focused on the development of a novel method for designing high-end interference fit fasteners. In this work, a new surface laser treatment process was utilized to enable enhanced usability and bond strength control of press-fit connections. Cylindrical 10 mm diameter pins of 316L were textured over a 10 mm length using a pulsed CO2 laser beam focused one millimeter below the surface, with the thermal energy adjusted to bring the surface to just above the melting point of the metal. The pin surface morphology and dimensions were precisely controlled by controlling the laser processing parameters specifically the laser beam power, the pulse repetition frequency, and the overlap between scan tracks. The pin was inserted into a hub hole diameter of 10.05±0.003 mm and pull out joint bond strengths were examined. The results of this study showed that surface thus altered provided improved control of the bond strength which is a particular novelty of this new interference fit joining method. Surface roughness, Ra, from 40 to 160 µm, melt pool depths from 0.4 to 1.7 mm, increases in the pin outer diameter from 0.5 to 1.1 mm, and pull out forces of up to 7.51 kN were achieved. The bond joint was found to re-grip before final failure providing a more secure joint and increased safety. This joining method allows for the possibility of joining different materials. The pulse repetition frequency was measured to be the most significant processing parameter for control of the resulting mechanical properties and the bond strength with a clear inverse relationship

Ti6Al4V functionally graded material via high power and high speed laser surface modification

This study investigates the fabrication of Ti6Al4V functionally graded material via high power and high speed laser surface modification (LSM). The original sample microstructures consisted of elongated equiaxed α phase with a grain boundary of β phase. Nine different LSM process parameter sets were applied to these samples. Scanning electron microscopy showed a fine acicular martensitic phase next to the surface of the laser treated samples in all cases. A transition microstructure zone beneath the martensitic zone was observed, with larger, equiaxed grains and some martensitic α phase growth. The interior of the sample contained the original microstructure. The surface roughness was found to increase after the surface modification for all process parameter sets. Nanoindentation tests were performed in order to obtain the hardness and modulus of the three phases, i.e. martensitic α, equiaxed α and the grain boundary β. A dual phase crystal plasticity finite element model was developed to investigate the three zone functionally graded microstructure under uniaxial tensile loading. The hardened surface zone prevented the propagation of continuous slip bands, while the transition zone prevented excessively sharp stress concentrations between the outer surface and interior of the samples

Multi-messenger radio frequency and optical diagnostics of pulsed laser ablation processes

: In this report, a novel non-contact, non-invasive methodology for near and quasi real-time measurement of the structuring of metal surfaces using pulsed laser ablation is described. This methodology is based on the use of a multi-messenger data approach using data from Optical Emission Spectroscopy (OES) and Radio Emission Spectroscopy (RES) in parallel. In this research, radio frequency (RF) emission (in the range of 100–400 MHz) and optical emission (200–900 nm) were investigated and acquired in real-time. The RES and OES data were post-processed and visualized using heat maps, and, because of the large data sets acquired particularly using in RES, Principal Component Analysis (PCA) statistics were used for data analysis. A comparison between in-process RES-OES data and post-process 3D images of the different ablated holes generated by a picosecond laser with different powers (1.39 W, 1.018 W, and 0.625 W) on aluminum (Al) and copper (Cu) was performed. The real-time time-series data acquired using the Radio and Optical Emission Spectroscopy technique correlate well with post-process 3D microscopic images. The capability of RES-OES as an in operando near real-time diagnostic for the analysis of changes of ablation quality (cleanliness and symmetry), and morphology and aspect ratios (including the diameter of ablated holes) in the process was confirmed by PCA analysis and heat map visualization. This technique holds great promise for in-process quality detection in metal micromachining and laser-metal base manufacturing

Poly(ethylene glycol)-Based Peptidomimetic “PEGtide” of Oligo-Arginine allows for efficient siRNA Transfection and gene inhibition

While a wide range of experimental and commercial transfection reagents are currently available, persistent problems remain regarding their suitability for continued development. These include the transfection efficiency for difficult-to-transfect cell types and the risks of decreased cell viability that may arise from any transfection that does occur. Therefore, research is now turning toward alternative molecules that improve the toxicity profile of the gene delivery vector (GDV), while maintaining the transfection efficiency. Among them, cell-penetrating peptides, such as octa-arginine, have shown significant potential as GDVs. Their pharmacokinetic and pharmacodynamic properties can be enhanced through peptidomimetic conversion, whereby a peptide is modified into a synthetic analogue that mimics its structure and/or function, but whose backbone is not solely based on α-amino acids. Using this technology, novel peptidomimetics were developed by co- and postpolymerization functionalization of substituted ethylene oxides, producing poly(ethylene glycol) (PEG)-based peptidomimetics termed “PEGtides”. Specifically, a PEGtide of the poly(α-amino acid) oligo-arginine [poly(glycidylguanidine)] was assessed for its ability to complex and deliver a small interfering ribonucleic acid (siRNA) using a range of cell assays and high-content analysis. PEGtide–siRNA demonstrated significantly increased internalization and gene inhibition over 24 h in Calu-3 pulmonary epithelial cells compared to commercial controls and octa-arginine-treated samples, with no evidence of toxicity. Furthermore, PEGtide–siRNA nanocomplexes can provide significant levels of gene inhibition in “difficult-to-transfect” mouse embryonic hypothalamic (mHypo N41) cells. Overall, the usefulness of this novel PEGtide for gene delivery was clearly demonstrated, establishing it as a promising candidate for continued translational research

Parametric investigation of ultrashort pulsed laser surface texturing on aluminium alloy 7075 for hydrophobicity enhancement

Hydrophobicity plays a pivotal role in mitigating surface fouling, corrosion, and icing in critical marine and aerospace environments. By employing ultrafast laser texturing, the characteristic properties of a material’s surface can be modified. This work investigates the potential of an advanced ultrafast laser texturing manufacturing process to enhance the hydrophobicity of aluminium alloy 7075. The surface properties were characterized using goniometry, 3D profilometry, SEM, and XPS analysis. The findings from this study show that the laser process parameters play a crucial role in the manufacturing of the required surface structures. Numerical optimization with response surface optimization was conducted to maximize the contact angle on these surfaces. The maximum water contact angle achieved was 142º, with an average height roughness (Sa) of 0.87 ± 0.075 μm, maximum height roughness (Sz) of 19.4 ± 2.12 μm, and texture aspect ratio of 0.042. This sample was manufactured with the process parameters of 3W laser power, 0.08 mm hatch distance, and a 3 mm/s scan speed. This study highlights the importance of laser process parameters in the manufacturing of the required surface structures and presents a parametric modeling approach that can be used to optimize the laser process parameters to obtain a specific surface morphology and hydrophobicity

Laser surface polishing of Ti-6Al-4V parts manufactured by laser powder bed fusion

Poor surface quality of Additively Manufactured (AM) components, can greatly increase the overall cost and lead time of high-performance components. Examples are medical devices where surfaces may contact the patient’s skin and hence need to be smooth and aerospace components with high fatigue strength requirements where surface roughness could reduce fatigue life. The average surface roughness (Ra) of AM parts can reach high levels greater than 50 microns and maximum distance between the high peaks and the low valleys of more than 300 microns. As such, there is a need for fast, cost effective and selective finishing methods of AM produced components targeted at high-performance industries. In this paper Ti-6Al-4V Grade 23 ELI, popular for medical devices and aerospace parts production, was L-PBF processed to manufacture parts which were subsequently treated via laser polishing. Here in this work, CO2 laser polishing was used for the surface modification of the Ti-6Al-4V produced samples. The most significant processing parameters were optimised to achieve approximately an 80% reduction in the average surface roughness and a 90% reduction in the peak-to-valley distance with a processing time of 0.1 sec/mm2 and cost of 0.2 €/cm2

Silver nanocolloid generation using dynamic laser ablation synthesis in solution system and drop-casting

Conductive inks allow for low cost and scalable deposition of conductive tracks and patterns for printed electronics. Metal nanoparticle colloids are a novel form for producing conductive inks. Laser Ablation Synthesis in Solution (LASiS) is a “green” method for the production of metal nanoparticle colloids without the need for environmentally hazardous chemicals, however the method has typically been limited by its low production rates. This study reports on the generation of an additive free silver nanocolloid with maximized productivity using a flow-based LASiS system and its characterization using dynamic light scattering, UV–VIS, transmission electron microscopy and field emission scanning electron microscopy. The productivity of the LASiS silver nanoparticle (size 34 ± 5 nm) was 0.9 mg mL−1. While the flow-based system achieves high laser ablation rates in the mass of nanomaterial generated per unit time, the volume of liquid required for the flow leads to relatively low concentrations. Therefore, in this work, LASiS concentrated ink was formulated via a centrifugal method, which was then drop-cast and heat treated to produce a conductive silver layer. Centrifuging to concentrate the ink was shown to be a necessary step to achieve good results, with the lowest resistance across the drop-cast material of 60.2 after annealing

Digitisation of metal AM for part microstructure and property control

Metal additive manufacturing, which uses a layer-by-layer approach to fabricate parts, has many potential advantages over conventional techniques, including the ability to produced complex geometries, fast new design part production, personalised production, have lower cost and produce less material waste. While these advantages make AM an attractive option for industry, determining process parameters which result in specific properties, such as the level of porosity and tensile strength, can be a long and costly endeavour. In this review, the state-of-the-art in the control of part properties in AM is examined, including the effect of microstructure on part properties. The simulation of microstructure formation via numerical simulation and machine learning is examined which can provide process quality control and has the potential to aid in rapid process optimisation via closed loop control. In-situ monitoring of the AM process, is also discussed as a route to enable first time right production in the AM process, along with the hybrid approach of AM fabrication with post-processing steps such as shock peening, heat treatment and rolling. At the end of the paper, an outlook is presented with a view towards potential avenues for further research required in the field of metal AM