22 research outputs found
Synthesis and Characterization of Tungstite (WO3.H2O) Nanoleaves and Nanoribbons
An environmentally benign method capable of producing large quantities of
materials was used to synthesize tungstite (WO3.H2O) leaf-shaped nanoplatelets
(LNPs) and nanoribbons (NRs). These materials were simply obtained by aging of
colloidal solutions prepared by adding hydrochloric acid (HCl) to dilute sodium
tungstate solutions (Na2WO4.2H2O) at a temperature of 5-10oC. The aging medium
and the pH of the precursor solutions were also investigated. Crystallization
and growth occurred by Ostwald ripening during the aging of the colloidal
solutions at ambient temperature for 24 to 48hrs. When dispersed in water, the
LNPs and NRs take many days to settle, which is a clear advantage for some
applications (e.g., photocatalysis). The materials were characterized using
scanning and transmission electron microscopy, Raman and UV/Vis spectroscopies.
The current versus voltage characteristics of the tungstite NRs showed that the
material behaved as a Schottky diode with a breakdown electric field of
3.0x105V.m-1. They can also be heat treated at relatively low temperatures
(300oC) to form tungsten oxide (WO3) NRs and be used as photoanodes for
photoelectrochemical water splitting.Comment: 12 pages, 5 figure
Synthesis of Tungsten Oxide Nanoparticles using a Hydrothermal Method at Ambient Pressure
Tungstite (WO3.H2O) nanoparticles were synthesized using a simple and
inexpensive low temperature and low pressure hydrothermal method by adding
hydrochloric acid to diluted sodium tungstate solutions (Na2WO4.2H2O) at
temperatures below 5oC. A heat treatment at temperatures at or above 300oC
resulted in a phase transformation to monoclinic WO3, while preserving the
nanoparticles morphology. The products were characterized using powder x-ray
diffraction, transmission electron microscopy (including electron energy-loss
spectroscopy and electron diffraction) and x-ray photoelectron spectroscopy.Comment: 11 pages, 1 table and 5 figure
Influence of nanostructured ceria support on platinum nanoparticles for methanol electrooxidation in alkaline media
The catalytic activity of platinum (Pt) nanoparticles (NPs) towards methanol electrooxidation in alkaline media was demonstrated to be dependent on their interactions with their nanostructured ceria support. Ceria nanorods (NRs) with diameters of 5 to 10 nm and lengths of 15 to 50 nm as well as ceria NPs with diameters of 2 to 6 nm were applied as supports for similarly sized Pt NPs with diameters of 2 to 5 nm. Cyclic voltammetry data showed that Pt NPs supported on ceria NPs exhibited a 2-to-5-fold higher catalytic current density versus ceria NRs. X-ray photoelectron spectroscopic data indicated that Pt NPs deposited onto ceria NRs were disproportionally composed of oxidized species (Pt2+, Pt4+ and Pt–O–M) rather than Pt0 while Pt NPs on ceria NPs mainly consisted of Pt0. Stronger metal-support interactions between Pt NPs and ceria NRs are postulated to induce preferential oxidation of Pt NPs and consequently decrease the catalytic sites and overall activity
Nickel oxide crystalline nano flakes: synthesis, characterization and their use as anode in lithium-ion batteries
Bottom-up solution synthesis of narrow nitrogen-doped graphene nanoribbons
Large quantities of narrow graphene nanoribbons with edgeincorporated nitrogen atoms can be synthesized via Yamamoto coupling of molecular precursors containing nitrogen atoms followed by cyclodehydrogenation using Scholl reaction