3 research outputs found

    Penta­carbonyl-2κ5 C-chlorido-1κCl-bis­[1(η5)-cyclo­penta­dien­yl](μ-α-oxido­benzyl­idene-1:2κ2 O:C)titanium(IV)tungsten(0)

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    The title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpenta­carbon­yl)oxy­phenyl­carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo­penta­dienyl rings undergoes an offset face-to-face π–π inter­action [3.544 (6) Å] with the symmetry-related cyclo­penta­dienyl ring of a neighbouring mol­ecule
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