3 research outputs found
PentaÂcarbonyl-2κ5 C-chlorido-1κCl-bisÂ[1(η5)-cycloÂpentaÂdienÂyl](μ-α-oxidoÂbenzylÂidene-1:2κ2 O:C)titanium(IV)tungsten(0)
The title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpentaÂcarbonÂyl)oxyÂphenylÂcarbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cycloÂpentaÂdienyl rings undergoes an offset face-to-face π–π interÂaction [3.544 (6) Å] with the symmetry-related cycloÂpentaÂdienyl ring of a neighbouring molÂecule