Mechanism of Poisoning the Catalytic Activity of Pd(100) by a Sulfur Adlayer

The modification of the potential-energy surface (PES) of H_2 dissociation over Pd(100) as induced by the presence of a (2x2) S adlayer is investigated by density-functional theory and the linear augmented plane wave method. It is shown that the poisoning effect of S originates from the formation of energy barriers hindering the dissociation of H_2. The barriers are in the entrance channel of the PES and their magnitude strongly depends on the lateral distance of the H_2 molecule from the S adatoms.Comment: RevTeX, 14 pages, 3 figure

Localized Support for Injection Point Election in Hybrid Networks

Ad-hoc networks, a promising trend in wireless technology, fail to work properly in a global setting. In most cases, self-organization and cost-free local communication cannot compensate the need for being connected, gathering urgent information just-in-time. Equipping mobile devices additionally with GSM or UMTS adapters in order to communicate with arbitrary remote devices or even a fixed network infrastructure provides an opportunity. Devices that operate as intermediate nodes between the ad-hoc network and a reliable backbone network are potential injection points. They allow disseminating received information within the local neighborhood. The effectiveness of different devices to serve as injection point differs substantially. For practical reasons the determination of injection points should be done locally, within the ad-hoc network partitions. We analyze different localized algorithms using at most 2-hop neighboring information. Results show that devices selected this way spread information more efficiently through the ad-hoc network. Our results can also be applied in order to support the election process for clusterheads in the field of clustering mechanisms.Comment: The Sixth International Conference on Networking (ICN 2007

Small Worlds: Strong Clustering in Wireless Networks

Small-worlds represent efficient communication networks that obey two distinguishing characteristics: a high clustering coefficient together with a small characteristic path length. This paper focuses on an interesting paradox, that removing links in a network can increase the overall clustering coefficient. Reckful Roaming, as introduced in this paper, is a 2-localized algorithm that takes advantage of this paradox in order to selectively remove superfluous links, this way optimizing the clustering coefficient while still retaining a sufficiently small characteristic path length.Comment: To appear in: 1st International Workshop on Localized Algorithms and Protocols for Wireless Sensor Networks (LOCALGOS 2007), 2007, IEEE Compuster Society Pres

Does Foreign Aid Improve Governance?

This paper analyses the impact of aid flows on governance. Using an instrumental variable approach and a large country sample, we find that aid has a negative rather than a positive influence on governance. This outcome is robust to various model specifications. --Official Development Assistance,Governance

Modeling the diffuse X-ray emission of Planetary Nebulae with different chemical composition

Based on time-dependent radiation-hydrodynamics simulations of the evolution of Planetary Nebulae (PNe), we have carried out a systematic parameter study to address the non-trivial question of how the diffuse X-ray emission of PNe with closed central cavities is expected to depend on the evolutionary state of the nebula, the mass of the central star, and the metallicity of stellar wind and circumstellar matter. We have also investigated how the model predictions depend on the treatment of thermal conduction at the interface between the central `hot bubble' and the `cool' inner nebula, and compare the results with recent X-ray observations. Our study includes models whose properties resemble the extreme case of PNe with Wolf-Rayet type central stars. Indeed, such models are found to produce the highest X-ray luminosities.Comment: 5 pages, 2 figures, to appear in proceedings of the IAU Symposium 283: "Planetary Nebulae: An Eye to the Future", Eds.: A. Manchado, L. Stanghellini and D. Schoenberne

Multimedia Content Distribution in Hybrid Wireless Networks using Weighted Clustering

Fixed infrastructured networks naturally support centralized approaches for group management and information provisioning. Contrary to infrastructured networks, in multi-hop ad-hoc networks each node acts as a router as well as sender and receiver. Some applications, however, requires hierarchical arrangements that-for practical reasons-has to be done locally and self-organized. An additional challenge is to deal with mobility that causes permanent network partitioning and re-organizations. Technically, these problems can be tackled by providing additional uplinks to a backbone network, which can be used to access resources in the Internet as well as to inter-link multiple ad-hoc network partitions, creating a hybrid wireless network. In this paper, we present a prototypically implemented hybrid wireless network system optimized for multimedia content distribution. To efficiently manage the ad-hoc communicating devices a weighted clustering algorithm is introduced. The proposed localized algorithm deals with mobility, but does not require geographical information or distances.Comment: 2nd ACM Workshop on Wireless Multimedia Networking and Performance Modeling 2006 (ISBN 1-59593-485