Pretreatment of automobile shredder residue (ASR) for fuel utilization

Automobile shredder residue (ASR) was pretreated to improve its quality for fuel utilization. Composition analysis revealed that ASR components could be classified into four groups: (1) urethane and textile―light fraction and combustibles containing low levels of ash and Cl; (2) plastics and rubber―light or heavy fraction and combustibles containing high levels of Cl; (3) metals and electrical wire―heavy fraction and incombustibles, and (4) particles smaller under 5.6 mm with high ash contents. Based on these results, we successively performed sieving to remove particles smaller than 5.6 mm, float and sink separations to reject the heavy fraction and plastics and rubber containing Cl, thermal treatment under an inert atmosphere to remove Cl derived from PVC, and char washing to remove soluble chlorides. This series of pretreatments enabled removal of 78% of the ash and 91% of the Cl from ASR. Sieving using a 5.6-mm mesh removed a considerable amount of ash. Product quality was markedly improved after the float and sink method. Specifically, the sink process using a 1.1 g cm-3 medium fluid rejected almost all rubber containing Cl and a large amount of PVC. The remaining Cl in char after heating at 300 oC under an inert atmosphere and washing was considered to be present as insoluble chlorides that volatilized at temperatures above 300 ℃. Based on a tradeoff relationship between product quality and treatment cost, ASR may be utilized as a form of refuse plastic fuel or char

Water-soluble characteristics of chlorine in char derived from municipal solid wastes

Chlorine in char derived from municipal solid waste (MSW) was characterized and quantified based on its water solubility: easily water-soluble, hardly water-soluble, and non-water-soluble chlorine. For that, a four-cycle process of water-washing, heating or carbonation were carried out. In order to confirm the characteristics of non-water-soluble chlorine, additional thermal treatment and an alkali- acid washing process were applied to washed char. It was found that a large particle size of char (0.5 to 1.0 mm) significantly contributed to the amount of non-water-soluble chlorine. Pulverization and HNO_3 HF digestion were performed to identify a factor to interfere chlorine release from char with a large particle size. Pulverization was proven ineffective for release of non-water-soluble chlorine, whereas approximately 32% of non-water-soluble chlorine was extracted by HNO_3 HF digestion. Therefore, the presence of non-water-soluble chlorine is likely to originate from its chemical property rather than simply from its physical one

Flow analysis of metals in a municipal solid waste management system

This study aimed to identify the metal flow in a municipal solid waste (MSW) management system. Outputs of a resource recovery facility, refuse derived fuel (RDF) production facility, carbonization facility, plastics liquefaction facility, composting facility, and bio-gasification facility were analyzed for metal content and leaching concentration. In terms of metal content, bulky and incombustible waste had the highest values. Char from a carbonization facility, which treats household waste, had a higher metal content than MSW incinerator bottom ash. A leaching test revealed that Cd and Pb in char and Pb in RDF production residue exceeded the Japanese regulatory criteria for landfilling, so special attention should be paid to final disposal of these substances. By multiplying metal content and the generation rate of outputs, the metal content of input waste to each facility was estimated. For most metals except Cr, the total contribution ratio of paper/textile/plastics, bulky waste, and incombustible waste was over 80%. Approximately 30% of Cr originated from plastic packaging. Finally, several MSW management scenarios showed that most metals are transferred to landfills and the leaching potential of metals to the environment is quite small

Characteristics of leachate from pyrolysis residue of sewage sludge

The pyrolysis residue (SP) of sewage sludge (SS) produced at 500 ℃ was subjected to batch and column leaching tests to investigate the release of its organic and inorganic constituents and metals. For comparison, incineration ash (SI) obtained from a SS incinerator was also tested. Pyrolysis and incineration reduced organic matter of SS from 0.78 kg kg–1-dry SS to 0.16 and 0.01 kg kg–1-dry SS, respectively. Heavy metals remained in SP without being volatilized, although Cd and Pb were transferred into the off-gas during incineration. In the batch leaching test with the leaching liquid-to-solid mass ratio (L/S) = 10, the pH of the SS, SP, and SI filtrates was 6.3, 7.9, and 11.0, respectively. The total organic carbon concentrations were in the order SS (877l mg l–1) >> SP (99 mg l–1) > SI (26 mg l–1). The SP and SI filtrates met the landfill standard for the Cd and Pb concentrations (< 0.3 mg l–1). In the column tests, although the SP contained more organic matter than that of SI, its carbon discharge into the leachate under aerobic conditions was similar to that of SI under anaerobic conditions. The leaching of heavy metals, such as Cd, Cr, Pb, and Zn, was also suppressed in SP during the active decomposition of organic matter. We demonstrated that pyrolysis reduces the potential release of pollutants from sewage sludge in landfill, making it a promising method of treating sewage sludge before landfilling

Behavior of metals in ash melting and gasification-melting of municipal solid waste (MSW)

In this study, metal behavior in ash-melting and municipal solid waste (MSW) gasification-melting facilities were investigated. Eight ash-melting and three MSW gasification-melting facilities with a variety of melting processes and feedstocks were selected. From each facility, melting furnace fly ash (MFA) and molten slag were sampled, and feedstock of the ash-melting processes was also taken. For the ash melting process, the generation rate of MFA was well correlated with the ratio of incineration fly ash (IFA) in feedstock, and this was because MFA was formed mostly by mass transfer from IFA and a limited amount from bottom ash (BA). Distribution ratios of metal elements to MFA were generally determined by volatility of the metal element, but chlorine content in feedstock had a significant effect on Cu and a marginal effect on Pb. Distribution ratio of Zn to MFA was influenced by the oxidizing atmosphere in the furnace. High MFA generation and distribution ratio of non-volatile metals to MFA in gasification-melting facilities was probably caused by carry-over of fine particles to the air pollution control system due to large gas volume. Finally, dilution effect was shown to have a significant effect on metal concentration in MFA

Material and heavy metal balance in a recycling facility for home electrical appliances

Collection and recycling of home electrical appliances was started in Japan in 2001 under a new recycling law. The law is aimed at promoting material recycling and at reducing the amount of waste to be landfilled. End of life products are processed by manual disassembly, shredding, and separation in 38 recycling facilities. The authors conducted a questionnaire survey and interviewed at some facilities to obtain information on process flow and material balance. By using the detailed records offered by one facility and by estimating the composition of recovered components, the material balance in the facilities was determined for four typical recycling processes. The heavy metal content of the recovered components was analyzed, then metal flow in the process was determined for each scenario. As a result, it was concluded that emissions to the environment of most heavy metals have been substantially reduced by the new recycling system, while a modest improvement in the rate of material recovery has been achieved

Resident's concerns and attitudes towards Solid Waste Management facilities

Because of limited space, the siting and construction of a new SWM facility is a big challenge in Japan. An SWM facility should be socially accepted as well as environmentally and economically sound. This study aimed to investigate people’s concerns about SWM facilities and their attitudes towards such facilities. A questionnaire was designed based on literature reviews and was sent to residents in three municipalities with different backgrounds. The questions covered concerns on the impact of an SWM facility, management aspects, unfairness of facility siting, and attitudes to facility construction. Of the many concerns, “pollution and health effect” had the highest rating, followed by “reliability”, “damage to nature” and “cost”. The rating was different between municipalities, reflecting their geographic and social backgrounds. Using factor analysis, correlations among concerns were analyzed, and five principal components were extracted, namely “pollution”, “nuisance”, “facility management”, “planning of facility”, and “merit/demerit”. Although obvious correlations were not found between individual items of concern and attitudes to construction of a facility, the discriminant analysis indicated dominant concerns of attitudes, but the disagreement between actual impact and citizens were found. As for attributes, the “opposed” attitude decreased for residents who had visited an SWM facility, even if they had only seen it from outside

Metal distribution in incineration residues of municipal solid waste (MSW) in Japan

This study aimed to identify distribution of metals and the influential factors on metal concentrations in incineration residues. Bottom ash and fly ash were sampled from 19 stoker and seven fluidized bed incinerators, which were selected to have a variety of furnace capacity, furnace temperature, and input waste. In the results, shredded bulky waste in input waste increased the concentration of some metals, such as Cd and Pb, and the effect was confirmed by analysis of shredded bulky waste. During MSW incineration, lithophilic metals such as Fe, Cu, Cr, and Al remained mainly in the bottom ash while Cd volatilized from the furnace and condensed to the fly ash. About two thirds of Pb and Zn was found in the bottom ash despite their high volatility. Finally, based on the results obtained in this study, the amount of metal in incineration residues of MSW was calculated and the loss of metal was estimated in terms of mass and money. A considerable amount of metal was found to be lost as waste material by landfilling of incineration residues

Improving the quality of waste-derived char by removing ash

This study characterized and removed ash from waste-derived char to improve the quality of char as fuel. Municipal solid waste (MSW) and automobile shredder residue (ASR) were carbonized at 450 ℃ and at 500 ℃ respectively in a rotary kiln with a nitrogen atmosphere for 1 h. MSW and ASR char were subjected to sieving and pulverization-sieving to screen incombustibles and the ash-rich fraction, after which float–sink separation, froth floatation, and oil agglomeration were applied to remove ash from the char. The established target quality was less than 30% ash content and more than 20000 kJ/kg heating value. However, the rate of combustibles recovery had to be lowered to produce a good quality of char along with a high heating value. MSW char attained the targeted quality level using froth floatation or oil agglomeration whereas neither separation method was able to make ASR-derived char satisfy the target. Based on the assumption that particle properties of char are determined by the weight ratio of combustibles and ash, the densities of combustibles and ash in char were estimated using the results of float–sink separation, X-ray diffraction (XRD) analysis, and elemental content. To verify the above assumption, an energy dispersive X-ray/scanning electron microscope (EDX/SEM) analyzer was used to observe char particles