111 research outputs found

    Iron-Based Heavy Quasiparticles in SrFe4_{4}Sb12_{12}: An Infrared Spectroscopic Study

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    Temperature-dependent infrared reflectivity spectra of SrFe4_{4}Sb12_{12} has been measured. A renormalized Drude peak with a heavy effective mass and a pronounced pseudogap of 10 meV develops in the optical conductivity spectra at low temperatures. As the temperature decreases below 100 K, the effective mass (mm^{*}) rapidly increases, and the scattering rate (1/τ1/\tau) is quenched. The temperature dependence of mm^{*} and 1/τ1/\tau indicates that the hybridization between the Fe 3d spins and the charge carriers plays an important role in determining the physical properties of SrFe4_{4}Sb12_{12} at low temperatures. This result is the clear evidence of the iron-based heavy quasiparticles.Comment: 5 pages, 5 figure

    Proton chemical shifts of molecular complexes

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