6 research outputs found
A triazine-based Ni(II) PNP pincer complex as catalyst for Kumada鈥揅orriu and Negishi cross-coupling reactions
Kumada鈥揅orriu and Negishi cross-coupling reactions, catalyzed efficiently by a Ni(II) PNP pincer complex containing a triazine backbone, are described. The catalyst is able to react with both activated and inactivated aryl halides including chlorides as well as phenol derivatives such as tosylates and mesylates to give the corresponding cross-coupling products in good to excellent isolated yields. A high diversity of substrates was tested under moderate conditions for both types of reactions.Austrian Science Fund (FWF
Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N2,N6-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue
The MnBr2 complex of N2,N6-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine (1路MnBr2) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O路MnBr2) and two tetrahydrofuran (THF) molecules, namely [N2,N6-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II)鈥揫bis(di-tert-butylphosphanyl)({6-[(di-tert-butylphosphanyl)amino]pyridin-2-yl}amino)phosphine oxide]dibromidomanganese(II)鈥搕etrahydrofuran (0.94/0.06/2), [MnBr2(C21H41N3P2)]0.94[MnBr2(C21H41N3OP2)]0.06路2C4H8O. The 1路MnBr2 and 1O路MnBr2 complexes are occupationally disordered about general positions. Both complexes feature square-pyramidal coordination of the MnII atoms. They are connected by weak N鈥擧...Br hydrogen bonding into chains extending along [001]. The THF molecules are located between the layers formed by these chains. One THF molecule is involved in hydrogen bonding to an amine H atom
Sustainable Synthesis of Quinolines and Pyrimidines Catalyzed by Manganese PNP Pincer Complexes
This study represents the first example
an environmentally benign,
sustainable, and practical synthesis of substituted quinolines and
pyrimidines using combinations of 2-aminobenzyl alcohols and alcohols
as well as benzamidine and two different alcohols, respectively. These
reactions proceed with high atom efficiency via a sequence of dehydrogenation
and condensation steps that give rise to selective C鈥揅 and
C鈥揘 bond formations, thereby releasing 2 equiv of hydrogen
and water. A hydride Mn颅(I) PNP pincer complex recently developed in
our laboratory catalyzes this process in a very efficient way. A total
of 15 different quinolines and 14 different pyrimidines were synthesized
in isolated yields of up to 91 and 90%, respectively
A Convenient Solvothermal Synthesis of Group 6 PNP Pincer Tricarbonyl Complexes
The
solvothermal synthesis of a series of zerovalent Cr, Mo, and W complexes
of the type [M颅(PNP)颅(CO)<sub>3</sub>] featuring PNP pincer ligands
based on 2,6-diaminopyridine is described. We demonstrate that the
solvothermal synthesis technique presented provides a powerful, simple,
and practical synthetic method resulting in high isolated yields in
a short time. In particular, Cr and W complexes are not readily accessible
via conventional methods. Moreover, this study allows a direct comparison
of steric and electronic properties of group 6 metal PNP pincer tricarbonyl
complexes