Solid Waste Landfill Performance During the 1994 Northridge Earthquake

The performance of 22landfills in the Los Angeles area during the January 17, 1994 Northridge earthquake has been investigated. Observations of damage at these landfills indicate that the overall performance of solid waste landfills was encouraging. None of the surveyed landfills showed any signs of major damage. However, one geosynthetic-lined landfill experienced two tears in the geomembrane liner. Most landfills within 30 km of the zone of energy release experienced some form of cracking in the soil cover. Beyond approximately 40 km from the zone of energy release, little to no damage was observed

The 1,3-Dioctadecyl-1H-imidazol-3-ium Based Potentiometric Surfactant Sensor for Detecting Cationic Surfactants in Commercial Products

A low-cost and fast potentiometric surfactant sensor for cationic surfactants, based on the new ion-pair 1,3-dioctadecyl-1H-imidazol-3-ium-tetraphenylborate (DODI-TPB), is presented. The new cationic surfactant DODI-Br was synthesized and characterized by NMR, LC-MS, and elemental analysis, and was used for synthesis of the DODI-TPB ionophore. The DODI-TPB surfactant sensor was obtained by implementation of the ionophore in PVC. The sensor showed excellent response characteristics with near-Nernstian slopes to the cationic surfactants DMIC, CPC, CTAB, and Hyamine 1622. The highest voltage responses were obtained for DMIC and CPC (58.7 mV/decade of activity). DMIC had the lowest detection limit (0.9 × 10−6 M) and the broadest useful linear concentration range (1.8 × 10−6 to 1.0 × 10−4 M). An interference study showed remarkable stability. Potentiometric titration curves for the titration of cationic surfactants (DMIC, CPC, CTAB, and Hyamine 1622), with DDS and TPB used as titrants, showed sigmoidal curves with well-defined inflexion points and a broad signal change. The standard addition method was successfully applied with recovery rates from 98.9 to 101.2 at two concentrations. The amount of cationic surfactant found in disinfectants and antiseptics was in good agreement with the referent two-phase titration method and the surfactant sensor on the market. This new surfactant sensor represents a low-cost alternative to existing methods for cationic surfactant detection

Relative Differences between Nonlinear and Equivalent-Linear 1-D Site Response Analyses

This study investigates the conditions for which one-dimensional (1-D) nonlinear (NL) site response analysis results are distinct from equivalent-linear (EL) results and provides guidance for predicting when differences are large enough to be of practical significance. Relative differences in spectral accelerations and Fourier amplitudes computed from NL and EL analyses are assessed for a range of site conditions and for suites of input motions appropriate for active crustal and stable continental regions. Among several considered parameters, EL/NL differences are most clearly dependent on shear strain index (I-gamma), defined as the ratio of input motion peak velocity to time-averaged shear-wave velocity in the top 30 m of the soil profile. For small I-gamma (generally under 0.03%), EL and NL results are practically identical, whereas at larger strains, differences can be significant for frequencies >0.3 Hz. Frequency-dependent I-gamma, values are recommended for conditions above which NL analyses are preferred to EL.ope