Design of Conformationally Distorted Donor–Acceptor Dyads Showing Efficient Thermally Activated Delayed Fluorescence

A highly potent donor-acceptor biaryl thermally activated delayed fluorescence (TADF) dye is accessible by a concise two-step sequence employing two-fold Ullmann arylation and a sequentially Pd-catalyzed Masuda borylation-Suzuki arylation (MBSA). Photophysical investigations show efficient TADF at ambient temperature due to the sterical hindrance between the donor and acceptor moieties. The photoluminescence quantum yield amounts to Phi(PL) = 80% in toluene and 90% in PMMA arising from prompt and delayed fluorescence with decay times of 21 ns and 30 mu s, respectively. From an Arrhenius plot, the energy gap Delta E(S-1 - T-1) between the lowest excited singlet S(1 )and triplet T-1 state was determined to be 980 cm(-1) (120 meV). A new procedure is proposed that allows us to estimate the intersystem crossing time to similar to 10(2) ns