Anisotropy parameters for two-color photoionization phases in randomly oriented molecules: theory and experiment in methane and deuteromethane

We present a combined theoretical and experimental work investigating the angle-resolved phases of the photoionization process driven by a two-color field consisting of an attosecond pulse train and an infrared pulse in an ensemble of randomly oriented molecules. We derive a general form for the two-color photoelectron (and time-delay) angular distribution valid also in the case of chiral molecules and when relative polarizations of the photons contributing to the attosecond photoelectron interferometer differ. We show a comparison between the experimental data and the theoretical predictions in an ensemble of methane and deuteromethane molecules, discussing the effect of nuclear dynamics on the photoionization phases. Finally, we demonstrate that the oscillating component and the phase of the two-color signal can be fitted using complex asymmetry parameters, in perfect analogy with the atomic case

Electron scattering cross sections from anthracene over a broad energy range

We report a computational investigation of electron scattering by anthracene (C14H10) in the gas phase. Integral and differential cross sections have been calculated by employing two distinct ab-initio quantum scattering methods: the symmetry adapted-single centre expansion method (ePOLYSCAT) and a screening corrected form of the independent atom model (IAM-SCAR) at low and high energies, respectively. After a detailed evaluation of the current results, we present a complete set of integral scattering cross sections from 0.00001 to 10,000eV. 2013 Elsevier Ltd