420 research outputs found

    Degradation of PVC insulated cable by Small Punch test considering molecular weight change

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    PVC used as insulation material for industrial power cable was tried to evaluate degradation by Small Punch test (SP test) as a simple and easy assessment method. It was suggested that the SP test can analyze chemical changes from the correlation with IR. Qualitative assessment shows agreement between SP test and tensile test, and it is possible to apply to evaluation of strength at long aging times. However, the failure load in the SP test samples is complex and scattered, so that detailed study on SP test is required. Thus, we focused chemical reaction mechanisms and tried to clarify their influence on SP behavior. Molecular weight change was measured for each aging time by SEC and discussed how polymer chains are cut based on IR result. We discuss the relationship between molecular weight and the mechanical properties of PVC by SP test. The effectiveness of SP test as the evaluation method for residual life prediction will be addressed

    Network-level analysis of damage in amine-crosslinked diglycidyl ether resins degraded by acid

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    有機材料の腐食劣化

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    Degradation of PVC insulated cable by Small Punch test considering molecular weight change

    No full text
    PVC used as insulation material for industrial power cable was tried to evaluate degradation by Small Punch test (SP test) as a simple and easy assessment method. It was suggested that the SP test can analyze chemical changes from the correlation with IR. Qualitative assessment shows agreement between SP test and tensile test, and it is possible to apply to evaluation of strength at long aging times. However, the failure load in the SP test samples is complex and scattered, so that detailed study on SP test is required. Thus, we focused chemical reaction mechanisms and tried to clarify their influence on SP behavior. Molecular weight change was measured for each aging time by SEC and discussed how polymer chains are cut based on IR result. We discuss the relationship between molecular weight and the mechanical properties of PVC by SP test. The effectiveness of SP test as the evaluation method for residual life prediction will be addressed
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