Anisotropic Assembly of Colloidal Nanoparticles: Exploiting Substrate Crystallinity

We show that the crystal structure of a substrate can be exploited to drive the anisotropic assembly of colloidal nanoparticles. Pentanethiol-passivated Au particles of approximately 2 nm diameter deposited from toluene onto hydrogen-passivated Si(111) surfaces form linear assemblies (rods) with a narrow width distribution. The rod orientations mirror the substrate symmetry, with a high degree of alignment along principal crystallographic axes of the Si(111) surface. There is a strong preference for anisotropic growth with rod widths substantially more tightly distributed than lengths. Entropic trapping of nanoparticles provides a plausible explanation for the formation of the anisotropic assemblies we observe

Instructional Alignment of Workplace Readiness Skills in Marketing Education

This study examined high school marketing education teachers’ knowledge of workplace readiness skills and whether that knowledge had an impact on student workplace readiness skill achievement. Further, this study examined the usage of Virginia’s 13 Workplace Readiness Skills curriculum and identified the teaching methods and instructional strategies used to disseminate the skills to students. Three sets of data were used for this study: teacher workplace readiness skills data, teacher survey data, and student workplace readiness skills post-test data. Pearson’s correlation was used to determine whether teacher knowledge of workplace readiness skills had an impact on student attainment of the same. The results showed that while overall teacher scores did not show a statistical significance on overall student scores, there were four individual skill areas in which there was a relationship between teacher and student scores

Disc precession in Be/X-ray binaries drives superorbital variations of outbursts and colour

Superorbital periods that are observed in the brightness of Be/X-ray binaries may be driven by a misaligned and precessing Be star disc. We examine how the precessing disc model explains the superorbital variation of (i) the magnitude of the observed X-ray outbursts and (ii) the observed colour. With hydrodynamical simulations we show that the magnitude of the average accretion rate on to the neutron star, and therefore the X-ray outbursts, can vary by over an order of magnitude over the superorbital period for Be star spin-orbit misalignments $\gtrsim 70^\circ$ as a result of weak tidal truncation. Most Be/X-ray binaries are redder at optical maximum when the disc is viewed closest to face-on since the disc adds a large red component to the emission. However, A0538-66 is redder at optical minimum. This opposite behaviour requires an edge-on disc at optical minimum and a radially narrow disc such that it does not add a large red signature when viewed face-on. For A0538-66, the misalignment of the disc to the binary orbit must be about $70-80^\circ$ and the inclination of the binary orbit to the line of sight must be similarly high, although restricted to $<75^\circ$ by the absence of X-ray eclipses.Comment: Accepted for publication in MNRA