Estudio preliminar sobre el efecto del ultrasonido en las propiedades fisicoquímicas del vino tinto

Ultrasound is regarded as a potential alternative method for improving the quality of some wines. This study was initiated with the objective of evaluating the effects of ultrasound on some important physicochemical properties of red wine such as chromatic characteristics (CC), electrical conductivity (EC), pH, titratable acidity (TA), total phenolic compounds (TPCs) and DPPH (1,1-diphenyl-2-picryl-hydrazyl) free radical scavenging activity (DFRSA). The operational parameters assessed were ultrasound power, ultrasound frequency, exposure time and bath temperature. Results illustrated that there were significant changes in CC, EC and TPC while pH and TA hardly changed except for samples treated at high temperatures. DFRSA was correlated to TPC during ultrasonic treatment. Application of principal component analysis to the experimental data suggested that exposure time was the factor with the greatest ability to induce changes on wine. Results suggested that ultrasound may be applied to improve some physicochemical properties of red wine.El ultrasonido se considera uno de los métodos alternativos potenciales para mejorar la calidad de algunos vinos. Se comenzó este estudio con el objetivo de evaluar los efectos del ultrasonido en algunas de la propiedades fisicoquímicas importantes del vino tinto como son: las características cromáticas (CC), la conductividad eléctrica (EC), el pH, la acidez (TA), los compuestos fenólicos totales (TPC) y el DPPH (1,1-difenil-2-picrilhidrazil) de actividad de eliminación de radicales libres (DFRSA). Los parámetros operacionales examinados fueron: la potencia de ultrasonido, la frecuencia de ultrasonido, el tiempo de exposición y la temperatura de baño. Los resultados ilustraron la existencia de cambios significativos en CC, EC y TPC, mientras que el pH y TA prácticamente no cambiaron excepto en las muestras tratadas con altas temperaturas. DFRSA tuvo correlación con TPC durante el tratamiento con ultrasonido. La aplicación de análisis de componentes principales a los datos experimentales sugirió que el tiempo de exposición era el factor con mayor habilidad para inducir cambios en el vino. Los resultados sugirieron que el ultrasonido podría aplicarse para mejorar algunas de las propiedades fisicoquímicas del vino tinto.National Natural Science Foundation of China [No. 31101324]Natural Science Foundation of Shaanxi Province, China [No. 2015JM3097]Technology Transfer Promotion Project of Xi’an, Shaanxi Province, China [No.CXY1434(5)]Fundamental Research Funds for the Central Universities of China [Nos. GK201302039, GK201404006

Perturbation expansion for 2-D Hubbard model

We develop an efficient method to calculate the third-order corrections to the self-energy of the hole-doped two-dimensional Hubbard model in space-time representation. Using the Dyson equation we evaluate the renormalized spectral function in various parts of the Brillouin zone and find significant modifications with respect to the second-order theory even for rather small values of the coupling constant U. The spectral function becomes unphysical for $U \simeq W$, where W is the half-width of the conduction band. Close to the Fermi surface and for U<W, the single-particle spectral weight is reduced in a finite energy interval around the Fermi energy. The increase of U opens a gap between the occupied and unoccupied parts of the spectral function.Comment: 17 pages, 11 Postscript figures, Phys. Rev. B, accepte

Individual and Multi Vortex Pinning in Systems with Periodic Pinning Arrays

We examine multi and individual vortex pinning in thin superconductors with periodic pinning arrays. For multi-vortex pinning we observe peaks in the critical current of equal magnitude at every matching field, while for individual vortex pinning we observe a sharp drop in the critical current after the first matching field in agreement with experiments. We examine the scaling of the critical current at commensurate and incommensurate fields for varied pinning strength and show that the depinning force at incommensurate fields decreases faster than at the commensurate fields.Comment: 4 figuure

Experimental and predicted vapour-liquid equilibrium of the binary mixtures n-heptane + chlorobutane isomers

The study of the isothermal vapour-liquid equilibrium (VLE) of the binary mixtures n-heptane plus chlorobutane isomers (1-chlorobutane, 2-chlorobutane, 1-chloro-2-methylpropane or 2-chloro-2-methylpropane) at three different temperatures, T = 288.15, 298.15 and 308.15 K, is presented in this contribution. The experimental results were correlated using Wilson equation and the thermodynamic consistency of the data was checked by the van Ness method. Furthermore, two different methods have been used to predict the phase equilibrium in isothermal conditions: a pure group contribution method (modified-UNIFAC) and a group contribution equation of state (VTPR)

Hysteresis and Fractional Matching in Thin Nb Films with Rectangular Arrays of Nanoscaled Magnetic Dots

We have investigated the periodic pinning of magnetic flux quanta in thin Nb films with rectangular arrays of magnetic dots. In this type of pinning geometry, a change in the periodicity and shape of the minima in the magnetoresistance occurs for magnetic fields exceeding a certain threshold value. This has been explained recently in terms of a reconfiguration transition of the vortex lattice due to an increasing vortex-vortex interaction with increasing magnetic field. In this picture the dominating elastic energy at high fields forces the vortex lattice to form a square symmetry rather than being commensurate to the rectangular geometry of the pinning array. In this paper we present a comparative study of rectangular arrays with Ni-dots, Co-dots and holes. In the magnetic dot arrays, we found a strong fractional matching effect up to the second order matching field. In contrast, no clear fractional matching is seen after the reconfiguration. Additionally, we discovered the existence of hysteresis in the magnetoresistance in the crossover between the low and the high field regime. We found evidence that this effect is correlated to the reconfiguration phenomenon rather than to the magnetic state of the dots. The temperature and angular dependences of the effect have been measured and possible models are discussed to explain this behavior.Comment: 1 Table, 5 Figure

A model for the doped copper oxide compounds

We present a relativistic spin-fermion model for the cuprates, in which both the charge and spin degrees of freedom are treated dynamically. The spin-charge coupling parameter is associated with the doping fraction. The model is able to account for the various phases of the cuprates and their properties, not only at low and intermediate doping but also for (highly) over-doped compounds. In particular, we acquire a qualitative understanding of high-T_c superconductivity through Bose-Einstein condensation of bound charge pairs. The mechanism that binds these pairs does not require a Fermi sea.Comment: 9 pages, 2 postscript figures. Version accepted for publication in Europhys. Let

Order in driven vortex lattices in superconducting Nb films with nanostructured pinning potentials

Driven vortex lattices have been studied in a material with strong pinning, such as Nb films. Samples in which natural random pinning coexists with artificial ordered arrays of defects (submicrometric Ni dots) have been fabricated with different geometries (square, triangular and rectangular). Three different dynamic regimes are found: for low vortex velocities, there is a plastic regime in which random defects frustrate the effect of the ordered array; then, for vortex velocities in the range 1-100 m/s, there is a sudden increase in the interaction between the vortex lattice and the ordered dot array, independent on the geometry. This effect is associated to the onset of quasi long range order in the vortex lattice leading to an increase in the overlap between the vortex lattice and the magnetic dots array. Finally, at larger velocities the ordered array-vortex lattice interaction is suppresed again, in agreement with the behavior found in numerical simulations.Comment: 8 text pages + 4 figure

Resistively-shunted superconducting quantum point contacts

We have studied the Josephson dynamics of resistively-shunted ballistic superconducting quantum point contacts at finite temperatures and arbitrary number of conducting modes. Compared to the classical Josephson dynamics of tunnel junctions, dynamics of quantum point contacts exhibits several new features associated with temporal fluctuations of the Josephson potential caused by fluctuations in the occupation of the current-carrying Andreev levels.Comment: 5 pages, RevTex, 3 postscript figures include

Singular sources in the Demianski-Newman spacetimes

The analysis of singular regions in the NUT solutions carried out in the recent paper (Manko and Ruiz, 2005 Class. Quantum Grav. 22, p.3555) is now extended to the Demianski-Newman vacuum and electrovacuum spacetimes. We show that the effect which produces the NUT parameter in a more general situation remains essentially the same as in the purely NUT solutions: it introduces the semi-infinite singularities of infinite angular momenta and positive or negative masses depending on the interrelations between the parameters; the presence of the electromagnetic field additionally endows the singularities with electric and magnetic charges. The exact formulae describing the mass, charges and angular momentum distributions in the Demianski-Newman solutions are obtained and concise general expressions P_n=(m+i\nu)(ia)^n, Q_n=(q+ib)(ia)^n for the entire set of the respective Beig-Simon multipole moments are derived. These moments correspond to a unique choice of the integration constant in the expression of the metric function \omega which is different from the original choice made by Demianski and Newman.Comment: 22 pages, 5 figures; submitted to Classical and Quantum Gravit

Symmetry-induced interference effects in metalloporphyrin wires

Organo-metallic molecular structures where a single metallic atom is embedded in the organic backbone are ideal systems to study the effect of strong correlations on their electronic structure. In this work we calculate the electronic and transport properties of a series of metalloporphyrin molecules sandwiched by gold electrodes using a combination of density functional theory and scattering theory. The impact of strong correlations at the central metallic atom is gauged by comparing our results obtained using conventional DFT and DFT+U approaches. The zero bias transport properties may or may not show spin-filtering behavior, depending on the nature of the d state closest to the Fermi energy. The type of d state depends on the metallic atom and gives rise to interference effects that produce different Fano features. The inclusion of the U term opens a gap between the d states and changes qualitatively the conductance and spin-filtering behavior in some of the molecules. We explain the origin of the quantum interference effects found as due to the symmetry-dependent coupling between the d states and other molecular orbitals and propose the use of these systems as nanoscale chemical sensors. We also demonstrate that an adequate treatment of strong correlations is really necessary to correctly describe the transport properties of metalloporphyrins and similar molecular magnets