Fluid flow during accretion in sediment-dominated margins: evidences of a high-permeability fossil fault zone from the Internal Ligurian accretionary units of the northern Apennines, Italy

We report here a detailed structural study carried out in the Internal Ligurian Units of the Northern Apennines, Italy, formed during the building of the Alpine accretionary complex through subduction of the sediment-filled Ligure-Piemontese oceanic basin. The deformation mechanisms associated with fluid migration across an accretion-related fault zone have been studied through a detailed analysis of different generations of syn-tectonic veins. Hydrofracturing occurred mainly sub-parallel to bedding in unlithified to semi-lithified sediments. Transient, upward-directed fluid injection locally connected the de´collement-parallel veins through bedding-normal hydrofractures of lithified sandstone layers. A third vein system comprises fibrous hydrofractures developed on the limbs of accretion-related folds. Crosscutting vein sets and the peculiar features of each identified vein set suggest that deformation was intricately associated with lithification and diagenetic processes. Dehydration-produced fluids transiently injected the lithifying sediments leading to local stress permutations. The proposed model provides a ‘‘ramp-flat’’ migration of fluids in which fluid flow is enhanced along high permeability, less cohesive layers, leading to the development of regional dilated hydrofracture channels like those recognized along the de´collement zone of modern margins. The more competent layers are truncated by high angle fractures representing the transient connectivity that existed between horizontal conduits

Updated picture of the Ligurian and Sub-Ligurian units in the Mt. Amiata area (Tuscany, Italy): Elements for their correlation in the framework of the Northern Apennines

The Mt. Amiata region (Southern Tuscany, Italy) represents the southernmost area of the Northern Apennines in which different lithologies belonging to the Ligurian and Sub-Ligurian units crop out widely. This paper provides an update on the stratigraphic, paleontological and structural features of the Ligurian and Sub-Ligurian units in the Mt. Amiata area by integrating new data from the Regional Geological Mapping project with those available from the existing literature. In the study area, the Sub-Ligurian units are represented by the Canetolo unit, which comprises the middle Eocene (Zone NP15) Argille e Calcari and Vico Fms showing heteropic relationships. The Ligurian units are represented by the Ophiolitic and Santa Fiora units. The Ophiolitic unit consists mainly of Early Cretaceous Palombini Shale associated with scattered Middle-Late Jurassic ophiolites. The age of the Palombini Shale spans from late Hauterivian-Barremian Zone CC5 to Aptian Zone CC7 of SISSINGH (1977). The Ophiolitic unit overlies the Santa Fiora unit consisting of the Pietraforte Fm and Varicoloured Shales topped by the Santa Fiora Fm. The Pietraforte Fm shows heteropic relationships with the Varicoloured Shale, and both formations can be referred to the ?Aptian to middle Coniacian. The age of the Santa Fiora Fm seems to span from the late Coniacian-early Santonian (Zone CC14) to middle-late Campanian (Zones CC21-CC22). Structural analyses indicate that all the Ligurian and Sub-Ligurian units experienced complex polyphase deformation through several folding phases during the closure of the Ligurian-Piemontese oceanic basin and the subsequent continental collision, which began in the middle Eocene. The Ligurian and Sub-Ligurian units now come into contact through low-angle shear zones developed during the last deformation phase identified in these units, i.e. middle Miocene extensional tectonics. This tectonic phase produced strong delamination through low-angle faults with staircase geometry, so that not only several stratigraphic levels but also entire tectonic units were omitted. Despite the extensional tectonics, the collected stratigraphic and structural data suggest a correlation between the Ligurian and Sub-Ligurian units of the Mt. Amiata area and the units cropping out in Southern Tuscany and the Ligurian-Emilian Apennines

Radiolarian biostratigraphic evidence for a Late Jurassic age of the El Tambor Group ophiolites (Guatemala)

We present a radiolarian biostratigraphic study of the metacherts of the El Tambor Group ophiolites (South Motagua Unit), Guatemala. The ophiolite sequence comprises MOR pillow metabasalts, massive metabasalts, metacherts and micaschists. The age of the studied metacherts is referable to the Late Jurassic (Oxfordian - Kimmeridgian). The radiolarian assemblage described in this paper is the first Jurassic finding in the ophiolitic MOR succession of the Motagua zone and represents a valuable tool to constrain the geodynamic evolution of the Caribbean area. A review of the ages of Jurassic rocks associated with the ophiolites from the Caribbean area is also reported

Andesitic dyke swarms in the Araç-Boyalı foredeep basin, N Anatolia: Evidence for Eocene extension

A number of dykes and sills have been investigated in the Araç-Boyalı Flysch Basin, a foreland basin formed on the platform of the Sakarya Composite Terrane following the closure of the Intra-Pontide Ocean during the Late Cretaceous – Late Paleocene. The andesitic dyke swarms, characterized by well-developed chilled margins, flow textures and elongated vesicles, intrude the basin sediments, among which massive and pillow lavas, as well as lava and pillow breccias are also found. Major element data plotted on SiO2 indicates plagioclase, pyroxene and biotite fractioation, as well Fe-Ti oxides in the samples, that are andesites and andesitic basalts of calc- alkaline character. Tectono-magmatic discrimination diagrams of lavas as well as the dykes are indicative for destructive plate margin volcanism. Lava and dyke samples display similar patterns in REE and Spider diagrams. A depletion of heavy REE, enrichment of LREE is observed, as well as a marked Nb-Ta trough, characteristic of arc magmas. Based on low Mg numbers, together with low compatible trace element concentrations and low Nb/La ratios, compositions of examined samples might have been modified by assimilation processes. Geochemical characteristics of the volcanic rocks reveal that they are products of continental arc magmatism within the Sakarya Composite Terrane above the N-ward subducting Izmir-Ankara oceanic lithosphere of Neotethys.Similarities in major, minor and trace element geochemistry are in favour of dykes being the feeders of the Eocene lava flows within the Eocene basins that formed as a result of post-collisional extention

Ophiolite-bearing Vermoshi Flysch (Albanian Alps, Northern Albania): elements for its correlation in the frame of Dinaric-Hellenic Belt

The tectonic setting of the Albanian Alps, Northern Albania, is characterized by a thick pile of tectonic units whose uppermost structural level is represented by the Vermoshi Unit, cropping out just few km north of the Shkoder-Péc Line. This unit includes a single formation, the Vermoshi Flysch, characterized by turbidite deposits consisting of arenites, shales and marls. The Vermoshi Flysch has been sampled for paleontological datings and petrographical analyses of the arenite beds along five selected and well exposed sections in the Vermoshi Valley. The nannoplancton and forams associations detected in the analyzed samples point out to a Barremian age, whereas the petrographical modal analysis of arenites indicates that all the samples have a mixed/hybrid silicilastic-carbonate composition, ranging from quartz-rich sublitharenites to quartz-poor litharenites. However, the main feature ot these arenites is the occurrence of fragments derived from an ophiolite sequence. The petrographical data suggest that these deposits can be regarded as supplied by two different source areas, represented by the margins of the basin where the Vermoshi Flysch was deposited. Whereas one of the border was represented by the Adria continental margin, the opposite one was characterized by an advancing nappe, constituted by ophiolites and their sedimentary cover. In this frame, the Vermoshi Flysch can be regarded as the southernmost part of the Vranduk Flysch, cropping out in Serbia and Croatia. This type of deposits, widespread in the Dinaric-Hellenic belt, can be considered as the sedimentary marker of the Late Jurassic - Early Cretaceous tectonic phases related to the closure of the oceanic area present between the Adria and the Eurasia plate

Deformation history of the eclogite- and jadeitite-bearing mélange from North Motagua Fault Zone, Guatemala: insights in the processes of a fossil subduction channel

In Guatemala, along the northern side of the Motagua Valley, a me ́lange consisting of blocks of eclogite and jadeitite set in a metaserpentinitic and metasedimentary matrix crops out. The metasedimentary rocks display a complex deformation history that includes four tectonic phases, from D1 to D4. The D1 phase occurs only as a relic and is characterized by a mineral assemblage developed under pressure temperature (P–T) conditions of 1.00–1.25GPa and 206–2638C. The D2 phase, characterized by isoclinal folds, schistosity and mineral/stretching lineation, developed at P–T conditions of 0.70–1.20 GPa and 279–4098C. The following D3 and D4 phases show deformations developed at shallower structural levels. Whereas the D1 phase can be interpreted as the result of underplating of slices of oceanic lithosphere during an intraoceanic subduction, the following phases have been acquired by the me ́lange during its progressive exhumation through different mechanisms. The deformations related to the D2 and D3 phases can be regarded as acquired by extrusion of the me ́lange within a subduction channel during a stage of oblique subduction. In addition, the structural evidences indicate that the coupling and mixing of different blocks occurred during the D2 phase, as a result of flow reverse and upward trajectory in the subduction channel. By contrast, the D4 phase can be interpreted as related to extension at shallow structural levels. In this framework, the exhumation- related structures in the me ́lange indicate that this process, probably long-lived, developed through different mechanisms, active in the subduction channel through time

Tectono-metamorphic history of the ophiolitic Lento unit (northern Corsica): evidences for the complexity of accretion-exhumation processes in a fossil subduction system

The Alpine Corsica (Corsica Island, France) is characterized by a stack of continent- and ocean-derived tectonic units, known as Schistes Lustres complex. This complex is affected by deformation and metamorphic imprint achieved during Late Cretaceous – Early Tertiary subduction- related processes connected with the closure of the Ligure-Piemontese oceanic basin and subsequent continental collision. In the Schistes Lustres complex, the Lento oceanic unit is characterized by four deformation phases, from D1 to D4 phase. The D1 phase, characterized by blueschist metamorphism, is regarded as related to coherent underplating in a subduction zone at a depth of about 25-30 km. The subsequent deformation phases can be referred to exhumation history, as suggested by the continuous decrease of metamorphic conditions. The transition from accretion to exhumation is represented by the D2 phase, achieved during the development of a duplex structure of accreted units. The D3 phase is in turn achieved by a further horizo..

The coupling of high-pressure oceanic and continental units in Alpine Corsica: Evidence for syn-exhumation tectonic erosion at the roof of the plate interface

The subduction of continental crust is now a matter of fact but which are the mechanisms and the factors control- ling the exhumation of continental units and their coupling with oceanic units are still a matter of debate. We herein present the tectono-metamorphic study of selected continental units belonging to the Alpine Corsica (Corte area, Central Corsica, France). The tectonic pile in the study area features thin slices of oceanic units (i.e. Schistes Lustrés Complex) tectonically stacked between the continental units (i.e. the Lower Units), which record a pressure–temperature-deformation (P-T-d) evolution related to their burial, down to P-T-peak conditions in the blueschist facies and subsequent exhumation during the Late Cretaceous – Early Oligocene time span. The metamorphic conditions were calculated crossing the results of three different thermobarometers based on the HP-LT metapelites. The continental units only recorded the P-peak conditions of 1.2 GPa-250 °C, up to the T-peak conditions of 0.8 GPa-400 °C, and the retrograde path up to LP-LT conditions. The metamorphic record of the oceanic units includes part of the prograde path occurring before the peak conditions reached at 1.0 GPa-250 °C followed by the last metamorphic event related to LP-LT conditions. The results indicate that each unit experienced a multistage independent pressure–temperature-deformation (P-T-d) evolution and sug- gest that the oceanic and continental units were coupled during the rising of the last ones at about 10 km of depth, where the oceanic units were stored at the base of the wedge. Subsequently they were deformed together by the last ductile deformation event during exhumation. We propose a mechanism of tectonic erosion at the base of the wedge, by which slices of Schistes Lustrés Complex were removed at the roof of the plate interface during the exhumation of the Lower Units

Ophiolitic sequences from the central sector of the Catena Costiera (Calabria): stratigraphy, petrology and structural analyses

Mesozoic ophiolites crop out in the Catena Costiera (Northern Calabrian Arc). The Northern Calabrian Arc is characterized by the superposition of three structural elements (OGNIBEN, 1973): the uppermost Hercynian continental section intruded by late- Variscan granitoids (Calabrian Nappe), the intermediate ophiolitic Nappe and the lowermost Mesozoic passive margin carbonate sequences (Apenninic Units). The studied area is located in the central Catena Costiera (fig. 1) where the ophiolitic sequences are characterized by both aphyric and porphyritic metabasalts with a T-MORB affinity (LIBERI et alii, 2006). They represent the basement of a peliticarenaceous metasedimentary sequence, previously interpreted as a pre-Mesozoic continental basement (Bagni Unit of AMODIO MORELLI et alii, 1976). In the metasedimentary cover, a remarkable increase in the carbonatic supply is noticed moving from south to north of the study area. According to this evidence two stratigraphic sequences have been defined for the southernmost Cozzo Cervello area and the northernmost San Martino di Finita area. The Cozzo Cervello area ophiolitic sequence is characterized by: metabasites, thin levels of volcanoclastic metasediments, rare metacarbonates, metapelites and metarenites. The San Martino di Finita area ophiolitic sequence is instead characterized by: metabasites, volcanoclastic metasediments and calcschists. The studied rocks underwent a polyphase deformation history and the meso- and microstructural analyses allowed distinguishing three main (D1-D3) deformation phases: – D1, this phase is characterized by a S1 foliation locally developed and preserved as microlithons inside the S2 main foliation; – D2, a N-S trending isoclinal folding event (F2; fig. 2 a,b) is responsible for the formation of the S2 foliation (fig. 2 d), that represent the main surface recognizable in the field; – D3, this phase is characterized by asymmetric folds (F3) developed at different scales and showing a WNW-ESE trending axes. An incipient foliation (S3) is locally developed in the phyllosilicate-rich levels (fig. 2 c,d). *Dipartimento di Scienze della Terra, Università della Calabria. ([email protected]) **Dipartimento di Scienze della Terra, Università di Pisa The petrographic analysis allows to define the mineralogical assemblage of the different lithotypes and to determine the relationships between deformation and blastesis. The metabasites are characterized by the mineralogical assemblage: Epidote + Na-amphibole + Lawsonite + Phengite + Chlorite + Albite Calcite Quartz + Magnetite. Metapelites and metarenites are characterized by: Epidote + Phengite + Stilpnomelane + Na-Amphibole + Pumpellyite + Chlorite + Albite + Quartz + Magnetite. The calcschist are constituted by: Calcite + Phengite + Chlorite + Albite + Quartz + Magnetite. The described mineralogical assemblages suggest that the studied rocks underwent P-T conditions typical of the blueschist facies as suggested by the blastesis of Na-amphiboles, lawsonite, stilpnomelane and phengite along the S2 foliation. The blastesis of white mica can be observed along the S3 foliation also. The following metamorphic retrogression developed within the prehnitepumpellyite facies and is characterized by a static recrystalization. Fig. 1 – Tectonic sketch map of central sector of the Catena Costiera, after LIBERI et alii (2006). 64 OPHIOLITIC SEQUENCES FROM THE CATENA COSTIERA 65 Fig. 2 – a) isoclinal folds (F2) in the metapelites of Cozzo Cervello area; b) isoclinal folds (F2) in the calcschists of San Martino di Finita area; c) crenulation F3 in the metabasites; d) microscopic view of the main foliation S2 deformed by the later D3 phase in the metapelites. The white line indicates white mica flakes along S3. The field study and the tectonometamorphic evolution reconstructed for the ophiolitic sequences cropping out in the central sector of the Catena Costiera of Calabria show that a subduction and exhumation history inside an accretionary wedge can be proposed. In particular, the characterization and the definition of the complex relationships existing within the ophiolitic metasedimentary cover allow us to propose: 1. the source area was composite, with both carbonatic and siliciclastic contributions; 2. the presence of terrigenous deposit, even in the lowermost part of the sedimentary sequence, seem to indicate that this part of oceanic crust was located close to the continental margin; 3. the San Martino di Finita type sedimentary cover can be correlated with that of the Malvito ophiolitic unit (sensu AMODIO MORELLI et alii, 1976), cropping out in the northernmost sector of the Catena Costiera; 4. the subdivision between the Bagni and Gimigliano-Monte Reventino Units, as proposed by DIETRICH & SCANDONE (1972) and AMODIO MORELLI et alii (1976) for the study area, is not supported by the data collected in this work. REFERENCES AMODIO MORELLI L., BONARDI G., COLONNA V., DIETRICH D., GIUNTA G., IPPOLITO F., LIGUORI V., LORENZONI S., PAGLIONICO A., PERRONE V., PICCARRETA G., RUSSO M., SCANDONE P., ZANETTIN-LORENZONI E. & ZUPPETTA A. (1976) - L’arco Calabro-peloritano nell’orogene appenninicomagrebide. Mem. Soc. Geol. It, 17, 1–60. DIETRICH D. & SCANDONE P. (1972) - The position of the basic and ultrabasic rocks in the tectonic units of the southern Apennines. Atti Acc. Pont., 21, 61–75. LIBERI F., MORTEN L. & PILUSO E. (2006) - Geodynamic significance of the ophiolites within the Calabrian Arc. Island Arc, 15, 26–43. OGNIBEN L. (1973) - Schema geologico della Calabria in base ai dati odierni. Geologia Romana, 12, 243