2 research outputs found
Synthesis and Reactivity of Palladium- and Platinum-Bridged Heterobimetallic [3]Trochrocenophanes
No full textHeterobimetallic [3]trochrocenophanes with PdCl<sub>2</sub> and
PtCl<sub>2</sub> bridges were prepared in reasonable yields. The PdCl<sub>2</sub> species possess, like their Pt analogues, poor solubility
but can be made more soluble by ligand substitution. By reaction of
Pd-bridged [3]trochrocenophanes with MeLi, both Cl atoms can be substituted
by a Me group. Likewise, reaction of Pt-bridged complexes with LiCCPh
leads to the expected disubstituted compound. Herein we present the
synthesis of MCl<sub>2</sub>- and MR<sub>2</sub>-bridged (M = Pd,
Pt; R = Me, CCPh) [3]trochrocenophanes, as well as some solid-state
structures of these [3]trochrocenophanes
Synthesis and Reactivity of Palladium- and Platinum-Bridged Heterobimetallic [3]Trochrocenophanes
No full textHeterobimetallic [3]trochrocenophanes with PdCl<sub>2</sub> and
PtCl<sub>2</sub> bridges were prepared in reasonable yields. The PdCl<sub>2</sub> species possess, like their Pt analogues, poor solubility
but can be made more soluble by ligand substitution. By reaction of
Pd-bridged [3]trochrocenophanes with MeLi, both Cl atoms can be substituted
by a Me group. Likewise, reaction of Pt-bridged complexes with LiCCPh
leads to the expected disubstituted compound. Herein we present the
synthesis of MCl<sub>2</sub>- and MR<sub>2</sub>-bridged (M = Pd,
Pt; R = Me, CCPh) [3]trochrocenophanes, as well as some solid-state
structures of these [3]trochrocenophanes
