5 research outputs found
Graphene Oxide-Mediated Protection from Photodamage
This
Letter presents the unique properties of graphene oxide (GO)
as a multitask material protecting from UVB-induced photodamage. Three
mechanisms of GO action on fibroblast in vitro cultures are verified
here: physical - a barrier blocking UV radiation; chemical - antioxidative
activity; and biological - activation of cellular antioxidative defense.
The changes in GO physicochemical properties appearing due to UVB
exposure underpin the observed UV protection phenomena. The results
reveal the simultaneous occurrence of two opposed processes, i.e.,
under small doses of UVB, the tested material undergoes oxidation
and sp<sup>2</sup> network rebuilding. In the vicinity of the GO surface,
the locally triggered high temperature is responsible for a reduction
process, while strong oxidative agents such as OH radicals cause parallel
GO oxidation. This phenomenon is enabled thanks to the exceptional
properties of carbonaceous materials. As a consequence, GO turns out
to be a multitask UV protector increasing fibroblast survival
Nanoscale Water Contact Angle on Polytetrafluoroethylene Surfaces Characterized by Molecular Dynamics–Atomic Force Microscopy Imaging
The
aim of this study is to link polytetrafluoroethylene (PTFE)
surface characteristics with its wetting properties in the nanoscale.
To do this using molecular dynamics (MD) simulation, three series
of rough PTFE surfaces were generated by annealing and compressing
and next characterized by the application of the MD version of the
atomic force microscopy (AFM) method. The values of specific surface
areas were additionally calculated. The TIP4P/2005 water model was
used to study the wetting properties of obtained PTFE samples. The
simulated water contact angle (WCA) value for the most flat (but slightly
rough) sample having PTFE density is equal to 106.94°, and it
is close to the value suggested for a perfect PTFE surface on the
basis of experimental results. Also, the changes in the WCA with PTFE
compression are in the same range as experimentally reported. The
obtained MD simulation results make it possible to link, for the first
time, the WCA values with the surface MD–AFM root-mean-square
roughness and with the PTFE density. Finally, we show that for PTFE
wetting in the nanoscale, the line tension is negligible and the Bormashenko’s
equation reduces to the Cassie–Baxter (CB) model. In fact,
our simulation results are close to the CB mechanism
Water at Curved Carbon Surface: Mechanisms of Adsorption Revealed by First Calorimetric Study
Water adsorption isotherms and calorimetrically
measured enthalpy of this process are reported for a series of modified
chemically single and multiwalled nanotubes. On the basis of calorimetric
measurements, entropy of adsorption is calculated and discussed. Next
the data are described using popular models of adsorption, and finally
a new approach for simultaneous description of water adsorption and
enthalpy of this process is discussed. On the basis of the results
of this model, four different possible mechanisms of water adsorption
in nanotubes are proposed
Carbon Molecular Sieves: Reconstruction of Atomistic Structural Models with Experimental Constraints
We propose a novel methodology for
developing experimentally informed
structural models of disordered carbon molecular sieves. The hybrid
reverse Monte Carlo simulation method coupled with wide-angle X-ray
scattering experiments is used for constructing an atomistic level
model of a representative sample of carbon molecular sieve film (CMS-F)
synthesized in our laboratory. We found that CMS-F possesses a disordered
matrix enriched with bended carbon chains and various carbon clusters
as opposed to the turbostratic carbon or graphite-like microcrystals.
The pore structure of CMS-F has a defected lamellar morphology of
one-dimensional periodicity with narrow (∼0.4 nm) micropores.
The model is applied to study adsorption properties of CMS-F with
respect to adsorbates of practical interest, such as N<sub>2</sub>, H<sub>2</sub>, CO, and C<sub>6</sub>H<sub>6</sub>. Special attention
is paid to the phase transformations in the course of adsorption.
In particular, we show theoretically and confirm experimentally that
nitrogen solidifies within CMS-F pores at 77 K upon adsorption of
5 mmol/g, and its further adsorption is associated with the adsorbed
phase compression induced by strong surface forces
Carbon Molecular Sieves: Reconstruction of Atomistic Structural Models with Experimental Constraints
We propose a novel methodology for
developing experimentally informed
structural models of disordered carbon molecular sieves. The hybrid
reverse Monte Carlo simulation method coupled with wide-angle X-ray
scattering experiments is used for constructing an atomistic level
model of a representative sample of carbon molecular sieve film (CMS-F)
synthesized in our laboratory. We found that CMS-F possesses a disordered
matrix enriched with bended carbon chains and various carbon clusters
as opposed to the turbostratic carbon or graphite-like microcrystals.
The pore structure of CMS-F has a defected lamellar morphology of
one-dimensional periodicity with narrow (∼0.4 nm) micropores.
The model is applied to study adsorption properties of CMS-F with
respect to adsorbates of practical interest, such as N<sub>2</sub>, H<sub>2</sub>, CO, and C<sub>6</sub>H<sub>6</sub>. Special attention
is paid to the phase transformations in the course of adsorption.
In particular, we show theoretically and confirm experimentally that
nitrogen solidifies within CMS-F pores at 77 K upon adsorption of
5 mmol/g, and its further adsorption is associated with the adsorbed
phase compression induced by strong surface forces