Positive Commutators in Non-Equilibrium Statistical Mechanics

The method of positive commutators, developed for zero temperature problems over the last twenty years, has been an essential tool in the spectral analysis of Hamiltonians in quantum mechanics. We extend this method to positive temperatures, i.e. to non-equilibrium quantum statistical mechanics. We use the positive commutator technique to give an alternative proof of a fundamental property of a certain class of large quantum systems, called {\it Return to Equilibrium}. This property says that equilibrium states are (asymptotically) stable: if a system is slightly perturbed from its equilibrium state, then it converges back to that equilibrium state as time goes to infinity.Comment: 1 figur

Overlapping Resonances in Open Quantum Systems

An $N$-level quantum system is coupled to a bosonic heat reservoir at positive temperature. We analyze the system-reservoir dynamics in the following regime: The strength $\lambda$ of the system-reservoir coupling is fixed and small, but larger than the spacing $\sigma$ of system energy levels. For vanishing $\sigma$ there is a manifold of invariant system-reservoir states and for $\sigma>0$ the only invariant state is the joint equilibrium. The manifold is invariant for $\sigma=0$ but becomes quasi-invariant for $\sigma>0$. Namely, on a first time-scale of the order $1/\lambda^2$, initial states approach the manifold. Then they converge to the joint equilibrium state on a much larger time-scale of the order $\lambda^2/\sigma^2$. We give a detailed expansion of the system-reservoir evolution showing the above scenario.Comment: Annales Henri Poincare 201

Thermal Ionization

In the context of an idealized model describing an atom coupled to black-body radiation at a sufficiently high positive temperature, we show that the atom will end up being ionized in the limit of large times. Mathematically, this is translated into the statement that the coupled system does not have any time-translation invariant state of positive (asymptotic) temperature, and that the expectation value of an arbitrary finite-dimensional projection in an arbitrary initial state of positive (asymptotic) temperature tends to zero, as time tends to infinity. These results are formulated within the general framework of $W^*$-dynamical systems, and the proofs are based on Mourre's theory of positive commutators and a new virial theorem. Results on the so-called standard form of a von Neumann algebra play an important role in our analysis

Repeated interactions in open quantum systems

Analyzing the dynamics of open quantum systems has a long history in mathematics and physics. Depending on the system at hand, basic physical phenomena that one would like to explain are, for example, convergence to equilibrium, the dynamics of quantum coherences (decoherence) and quantum correlations (entanglement), or the emergence of heat and particle fluxes in non-equilibrium situations. From the mathematical physics perspective, one of the main challenges is to derive the irreversible dynamics of the open system, starting from a unitary dynamics of the system and its environment. The repeated interactions systems considered in these notes are models of non-equilibrium quantum statistical mechanics. They are relevant in quantum optics, and more generally, serve as a relatively well treatable approximation of a more difficult quantum dynamics. In particular, the repeated interaction models allow to determine the large time (stationary) asymptotics of quantum systems out of equilibrium.Comment: Lecture notes of the summer school "Non-equilibrium statistical mechanics" (Montreal, July 2011

Dissipative Transport: Thermal Contacts and Tunnelling Junctions

The general theory of simple transport processes between quantum mechanical reservoirs is reviewed and extended. We focus on thermoelectric phenomena, involving exchange of energy and particles. Entropy production and Onsager relations are relevant thermodynamic notions which are shown to emerge from the microscopic description. The theory is illustrated on the example of two reservoirs of free fermions coupled through a local interaction. We construct a stationary state and determine energy- and particle currents with the help of a convergent perturbation series. We explicitly calculate several interesting quantities to lowest order, such as the entropy production, the resistance, and the heat conductivity. Convergence of the perturbation series allows us to prove that they are strictly positive under suitable assumptions on the interaction between the reservoirs.Comment: 55 pages; 2 figure

Multiscale dynamics of open three-level quantum systems with two quasi-degenerate levels

We consider a three-level quantum system interacting with a bosonic thermal reservoir. Two energy levels of the system are nearly degenerate but well separated from the third one. The system-reservoir interaction constant is larger than the energy difference of the degenerate levels, but it is smaller than the separation between the latter and the remaining level. We show that the quasi-degeneracy of energy levels leads to the existence of a manifold of quasi-stationary states, and the dynamics exhibits two characteristic time scales. On the first, shorter one, initial states approach the quasi-stationary manifold. Then, on the much longer second time scale, the final unique equilibrium is reached.Comment: Final text as publishe

Repeated and continuous interactions in open quantum systems

We consider a finite quantum system S coupled to two environments of different nature. One is a heat reservoir R (continuous interaction) and the other one is a chain C of independent quantum systems E (repeated interaction). The interactions of S with R and C lead to two simultaneous dynamical processes. We show that for generic such systems, any initial state approaches an asymptotic state in the limit of large times. We express the latter in terms of the resonance data of a reduced propagator of S+R and show that it satisfies a second law of thermodynamics. We analyze a model where both S and E are two-level systems and obtain the asymptotic state explicitly (lowest order in the interaction strength). Even though R and C are not direcly coupled, we show that they exchange energy, and we find the dependence of this exchange in terms of the thermodynamic parameters. We formulate the problem in the framework of W*-dynamical systems and base the analysis on a combination of spectral deformation methods and repeated interaction model techniques. We do not use master equation approximations

Dynamical Localization of Quantum Walks in Random Environments

The dynamics of a one dimensional quantum walker on the lattice with two internal degrees of freedom, the coin states, is considered. The discrete time unitary dynamics is determined by the repeated action of a coin operator in U(2) on the internal degrees of freedom followed by a one step shift to the right or left, conditioned on the state of the coin. For a fixed coin operator, the dynamics is known to be ballistic. We prove that when the coin operator depends on the position of the walker and is given by a certain i.i.d. random process, the phenomenon of Anderson localization takes place in its dynamical form. When the coin operator depends on the time variable only and is determined by an i.i.d. random process, the averaged motion is known to be diffusive and we compute the diffusion constants for all moments of the position