Параметры эффекта памяти формы в сплавах на основе TiNi с серебром

Статья представляет исследования влияния добавки серебра с разной концентрацией до 1,5 ат.% на сплавы на основе TiNi. Построены температурные зависимости накопления и возврата деформации при многократном эффекте памяти формы (ЭПФ) сплавов (TiNiMoFe)Ag и определены параметры ЭПФ (температуры начала и конца накопления и возврата деформации, остаточная и обратимая деформации, ширина петли гистерезиса). Показано, что увеличение концентрации серебра приводит к росту ширины петли гистерезиса и величины обратимой деформации. Изменение состава в В2 структуре приводит к смещению характеристических температур превращения исследуемых сплаво

The influence of the surface layer on the combination of properties of thin TiNi alloy wires

We have studied the influence of the surface layer on the parameters of the multiply repeated shape memory effect, developing stresses, characteristic temperatures, and intervals of martensitic transformations in thin (1 mm diameter) wires made of TiNi-based alloys. Examination of the surface layer structure showed that, in 1-mm-diameter TN-1V grade alloy wire, the oxide layer is about 15 μm thick and consists mostly of titanium, nickel, oxygen, and carbon. Removal of this surface layer leads to an increase in the maximum accumulated deformation, shift of the temperature interval of formation toward higher temperatures, and increase in the strength and plasticity characteristics

Influence of wire geometry on the mechanical behavior of the TiNi design

The present article is aimed at studying the deformation behavior of TiNi wire and knitted metal TiNi mesh under uniaxial tension and revealing the role of wire geometry on their main mechanical characteristics and mechanisms of deformation behavior. The temperature dependence curve of the electrical resistance indicates that a two-stage martensitic transformation of B2!R!B190 is occurring, and is responsible for the superelasticity effect. The TEM results showed that at room temperature, the TiNi wire has a nanocrystalline structure composed of B2 austenite grains. A change in the deformation mechanism was established under the uniaxial tension, where the TiNi wire exhibits the effect of superelasticity, while the knitted metal TiNi mesh made from this wire is characterized by hyperelastic behavior. Fracturing of the knitted metal TiNi mesh requires significant loads of up to 3500 MPa compared to the fracture load of the TiNi wire. With the uniaxial tension of the wire, which maximally repeats the geometry of the wire in knitted metal mesh, an increase in mechanical characteristics was observed

The effect of subsequent stress‐induced martensite aging on the viscoelastic properties of aged NiTiHf polycrystals

This study investigated the effect of stress‐induced martensite aging under tensile and compressive stresses on the functional and viscoelastic properties in Ni50.3Ti32.2Hf17.5 polycrystals containing dispersed H‐phase particles up to 70 nm in size obtained by preliminary austenite aging at 873 K for 3 h. It was found that stress‐induced martensite aging at 428 K for 12 h results in the appearance of a two‐way shape memory effect of −0.5% in compression and +1.8% in tension. Moreover, a significant change in viscoelastic properties can be observed: an increase in internal friction (by 25%) and a change in elastic modulus in tensile samples. The increase in internal friction during martensitic transformation after stress‐induced martensite aging is associated with the oriented growth of thermal‐induced martensite. After stress‐induced martensite aging, the elastic modulus of martensite (EM) increased by 8 GPa, and the elastic modulus of austenite (EA) decreased by 8 GPa. It was shown that stress‐induced martensite aging strongly affects the functional and viscoelastic properties of material and can be used to control them

The effect of stress-induced martensite aging in tension and compression on B2–B19′ martensitic transformation in Ni50.3Ti32.2Hf17.5 high-temperature shape memory alloy

The present study investigates the high-temperature shape memory effect (SME) in heterophase Ni50.3Ti32.2Hf17.5 polycrystals with nanosized H-phase particles after stress-induced martensite (SIM) aging in tension and compression. SIM aging created the conditions for fully reversible two-way SME with a strain of up to 50% of the one-way shape memory strain. SIM aging altered the viscoelastic properties of material, in particular, the elastic moduli of austenite and martensite increased, as did internal friction. Increased interface mobility is suggested as the reason for internal friction growth

Improved mechanical properties of porous nitinol by aluminum alloying

Aluminum alloying effects (up to 2 at %) on the macrostructure, microstructure, and mechanical properties of porous nitinol (NiTi) obtained by self-propagating high-temperature synthesis (SHS) were studied. It has been established that Ni and Ti interactions with liquid Al (0.5–1 at % Al) in the SHS process significantly change macrostructure, decrease the size of the interpore bridges, and increase their number, resulting in a larger effective cross-sectional area. An increase in the aluminum content above 1 at % leads to larger interpore bridges in the SHS product. The microhardness of TiNi(Al) increases from 305 HV50 g to 422 HV50 g with aluminum concentration, while the fraction of the TiNi(Al) (B2 + B19′) phases decreases from 75% to 50%. The Ti2Ni(Al) phase fraction increases from 25% to 50% with Al concentration. The 64 MPa tensile strength and 2.9% fracture strain of porous Ti50Ni49Al1 alloy are higher than without Al. The increase in strength is due to the formation of a more homogeneous macrostructure and solid solution strengthening of the alloy-forming phases

Investigation of the orientation dependence of marforming on superelasticity and shape memory effect in equiatomic TiNi single crystals under compression

The shape memory effect (SME) and superelasticity (SE) after marforming (deformation in the martensitic phase at 203 K, followed by annealing at 713 K, 0.5 h) were studied in the equiatomic TiNi crystals under compression. Marforming was carried out along [0 0 1]B2 and [0 1 1]B2 directions of B2-phase after strain of ε = 1.5ε0 (ε0 is the lattice deformation, which depends on the crystal orientation). SME and SE after marforming were studied along [0 0 1]B2 direction. It was shown that the maximum stress level of B2-phase σcr(B2) = 750 MPa, the lowest values of mechanical Δσ = 100 MPa and thermal ΔTh = 32 K hysteresis and the maximum temperature range of SE ΔTSE = 77 K were observed when marforming under compression was realized along the [0 0 1]B2 direction

Study of the effect of diamond nanoparticles on the structure and mechanical properties of the medical Mg–Ca–Zn magnesium alloy

The paper addresses the production and investigation of the Mg–Ca–Zn alloy dispersionhardened by diamond nanoparticles. Structural studies have shown that diamond nanoparticles have a modifying effect and make it possible to reduce the average grain size of the magnesium alloy. Reduction of the grain size and introduction of particles into the magnesium matrix increased the yield strength, tensile strength, and ductility of the magnesium alloy as compared to the original alloy after vibration and ultrasonic treatment. The magnesium alloy containing diamond nanoparticles showed the most uniform fracture due to a more uniform deformation of the alloy with particles, which simultaneously increased its strength and ductilit

Biocompatibility assessment of coatings obtained in argon and nitrogen atmospheres for TiNi materials

This work aims to study the cytocompatibility of protective coatings obtained in argon and nitrogen atmospheres on a TiNi surface. Particular attention is paid to comparing the interaction of cell culture with coatings and an uncoated TiNi sample, using for comparison the number of viable cells on the surface, the phase composition, structure, wettability, surface charge and topography. The Ti/Ni/Ti nanolaminate was deposited on a TiNi substrate by magnetron sputtering. Reaction annealing of Ti/Ni/Ti nanolaminate on a TiNi substrate, when heated to 900 ◦C in argon, leads to the formation of a dense two-layer coating 2.0–2.1 µm thick: layer I (TiO + Ti2N), layer II (Ti4Ni2 O(N)). Reaction annealing in nitrogen leads to the formation of a thin three-layer nanocoating 250 nm thick: I (TiO2 + TiN), II (Ti4Ni2N(O) + Ti3Ni4), III (TiN). The coating synthesized in nitrogen is more favorable for cell attachment and proliferation because of the moderately hydrophilic rough surface and mixed phase composition of titanium nitrides and oxides