Geochemistry of Aquatic Sediments

The type and composition of freshwater and marine sediments are key factors in environmental research of (a) natural processes such as sediment transport and accumulation, biodiversity, and biogeochemical reactions within sediments and (b) evaluation of source and progress of contamination, as aquatic sediments act as a sink for nonorganic and organic toxic substances. Above certain levels, such substances could harm biological diversity and human health. Geochemical investigations of aquatic sediments in fluvial, lacustrine, estuarine, and marine environments are of fundamental interest for the assessment of natural ecosystems and the level of pollution that potentially harms them. Detailed determination of the chemical constituents of aquatic sediments assists in detecting sources of pollution as sewage, industry, agriculture, abandoned and active mines, landfills, harbor activities, and oil drilling [leakage]. In addition, natural anomalies may indicate mineral resources in a particular region. New methods and approaches for sampling and analysis are continuously being introduced in aquatic sediment research. More attention is given to qualitative and quantitative monitoring of sediment and sediment fluxes, which is regularly established in most European countries and many others worldwide. Unfortunately, uniform legislation of sediment quality [and load] still does not exist on an international level and in most countries does not exist even on the national level. Therefore, more attention should be given to further expansion of sediment monitoring and of establishing criteria for assessing sediment quality and legislative for toxic inorganic and organic pollutants

Integrated Monitoring of Particle-Associated Transport of Persistent Organic Pollutants (PAHs as case study) in Contrasting Catchments in Southwest Germany

Strongly sorbing hydrophobic pollutants such as polycylic aromatic hydrocarbons (PAHs) are primarily subjected to particle-associated transport and thus are mobilized especially during high flow conditions when soils and sediments undergo erosion and urban runoff is intensified. Whereas soil pollutants reach rivers only slowly by erosion, untreated surface runoff from sealed urban space and stormwater releases are major immediate sources of particle bound pollutants. Chemical loads to rivers in general may increase with increasing population density or urban development of watersheds due to abundance of sources and impervious surface. Given the scope of anthropogenic impact, integrated and cost-effective strategies for containment monitoring in catchments are needed

Towards an integrated understanding of how micro scale processes shape groundwater ecosystem functions

Micro scale processes are expected to have a fundamental role in shaping groundwater ecosystems and yet they remain poorly understood and under-researched. In part, this is due to the fact that sampling is rarely carried out at the scale atwhich microorganisms, and their grazers and predators, function and thus we lack essential information. While set within a larger scale framework in terms of geochemical features, supply with energy and nutrients, and exchange intensity and dynamics, the micro scale adds variability, by providing heterogeneous zones at the micro scalewhich enable awider range of redox reactions. Here we outline howunderstanding micro scale processes better may lead to improved appreciation of the range of ecosystemsfunctions taking place at all scales. Such processes are relied upon in bioremediation and we demonstrate that ecosystem modelling as well as engineering measures have to take into account, and use, understanding at the micro scale. We discuss the importance of integrating faunal processes and computational appraisals in research, in order to continue to secure sustainable water resources from groundwater

Particle bound pollutants in rivers: Results from suspended sediment sampling in Globaqua River Basins

Transport of hydrophobic pollutants in rivers such as polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and heavy metals is often facilitated by suspended sediment particles, which are typically mobilized during high discharge events. Suspended sediments thus represent a means of transport for particle related pollutants within river reaches and may represent a suitable proxy for average pollutant concentrations estimation in a river reach or catchment. In this study, multiple high discharge/turbidity events were sampled at high temporal resolution in the Globaqua River Basins Sava (Slovenia, Serbia), Adige (Italy), and Evrotas (Greece) and analysed for persistent organic pollutants such as PAHs (polycyclic aromatic hydrocarbons) or PCBs (polychlorinated biphenyls) and heavy metals. For comparison, river bed sediment samples were analysed as well. Further, results are compared to previous studies in contrasting catchments in Germany, Iran, Spain, and beyond. Overall results show that loadings of suspended sediments with pollutants are catchment-specific and relatively stable over time at a given location. For PAHs, loadings on suspended particles mainly correlate to urban pressures (potentially diluted by sediment mass fluxes) in the rivers, whereas metal concentrations mainly display a geogenic origin. By cross-comparison with known urban pressure/sediment yield relationships (e.g. for PAHs) or soil background values (for metals) anthropogenic impact – e.g. caused by industrial activities – may be identified. Sampling of suspended sediments gives much more reliable results compared to sediment grab samples which typically show a more heterogeneous contaminant distribution. Based on mean annual suspended sediment concentrations and distribution coefficients of pollutants the fraction of particle facilitated transport versus dissolved fluxes can be calculated