70 research outputs found
Sodium atoms and clusters on graphite: a density functional study
Sodium atoms and clusters (N<5) on graphite (0001) are studied using density
functional theory, pseudopotentials and periodic boundary conditions. A single
Na atom is observed to bind at a hollow site 2.45 A above the surface with an
adsorption energy of 0.51 eV. The small diffusion barrier of 0.06 eV indicates
a flat potential energy surface. Increased Na coverage results in a weak
adsorbate-substrate interaction, which is evident in the larger separation from
the surface in the cases of Na_3, Na_4, Na_5, and the (2x2) Na overlayer. The
binding is weak for Na_2, which has a full valence electron shell. The presence
of substrate modifies the structures of Na_3, Na_4, and Na_5 significantly, and
both Na_4 and Na_5 are distorted from planarity. The calculated formation
energies suggest that clustering of atoms is energetically favorable, and that
the open shell clusters (e.g. Na_3 and Na_5) can be more abundant on graphite
than in the gas phase. Analysis of the lateral charge density distributions of
Na and Na_3 shows a charge transfer of about 0.5 electrons in both cases.Comment: 20 pages, 6 figure
Long-Term Efficacy of Adding Fenofibric Acid to Moderate-Dose Statin Therapy in Patients with Persistent Elevated Triglycerides
Children's vomiting following posterior fossa surgery: A retrospective study
<p>Abstract</p> <p>Background</p> <p>Nausea and vomiting is a problem for children after neurosurgery and those requiring posterior fossa procedures appear to have a high incidence. This clinical observation has not been quantified nor have risk factors unique to this group of children been elucidated.</p> <p>Methods</p> <p>A six year retrospective chart audit at two Canadian children's hospitals was conducted. The incidence of nausea and vomiting was extracted. Hierarchical multivariable logistic regression was used to quantify risk and protective factors at 120 hours after surgery and early vs. late vomiting.</p> <p>Results</p> <p>The incidence of vomiting over a ten day postoperative period was 76.7%. Documented vomiting ranged from single events to greater than 20 over the same period. In the final multivariable model: adolescents (age 12 to <17) were less likely to vomit by 120 hours after surgery than other age groups; those who received desflurane, when compared to all other volatile anesthetics, were more likely to vomit, yet the use of ondansetron with desflurane decre kelihood. Children who had intraoperative ondansetron were more likely to vomit in the final multivariable model (perhaps because of its use, in the clinical judgment of the anesthesiologist, for children considered at risk). Children who started vomiting in the first 24 hours were more likely to be school age (groups 4 to <7 and 7 to <12) and receive desflurane. Nausea was not well documented and was therefore not analyzed.</p> <p>Conclusion</p> <p>The incidence of vomiting in children after posterior fossa surgery is sufficient to consider all children requiring these procedures to be at high risk for POV. Nausea requires better assessment and documentation.</p
Depressive symptoms and alcohol correlates among Brazilians aged 14 years and older: a cross-sectional study
Patients' perceptions of awake and outpatient craniotomy for brain tumor: a qualitative study
Anesthesia for cerebral aneurysms: a comparison between interventional neuroradiology and surgery
Prospective study of awake craniotomy used routinely and nonselectively for supratentorial tumors
Nefopam or clonidine in the pharmacologic prevention of shivering in patients undergoing conscious sedation for interventional neuroradiology
Evoked potential monitoring during posterior fossa aneurysm surgery: a comparison of two modalities
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