331 research outputs found
1-(4-Chloro-3-fluorophenyl)-2-[(3-phenylisoquinolin-1-yl)sulfanyl]ethanone
In the title compound, C23H15ClFNOS, the isoquinoline system and the 4-chloro-3-fluorophenyl ring are aligned at 80.4 (1)°. The dihedral angle between the isoquinoline system and the pendant (unsubstituted) phenyl ring is 19.91 (1)°
Effective constructions in plethysms and Weintraub's conjecture
We give a short proof of Weintraub's conjecture by constructing explicit
highest weight vectors in the symmetric power of an even exterior power
1-(4-Chlorophenyl)-2-[(3-phenylisoquinolin-1-yl)sulfanyl]ethanone
The title compound, C23H16ClNOS, exhibits dihedral angles of 11.73 (1) and 66.07 (1)°, respectively, between the mean plane of the isoquinoline system and the attached phenyl ring, and between the isoquinoline system and the chlorophenyl ring. The dihedral angle between the phenyl and chlorophenyl rings is 54.66 (1)°
2-[2-(Hydroxymethyl)phenyl]-1-(1-naphthyl)ethanol
The molecular conformation of the title compound, C19H18O2, is stabilized by an intramolecular O—H—O hydrogen bond. In addition, intermolecular O—H—O interactions link the molecules into zigzag chains running along the c axis
Effect of Mn Concentration on Magneto-mechnaical Properties in Directionally Solidified Ferromagnetic Shape Memory Ni-Mn-Ga Alloys
Heusler type alloys Ni50Mn25+xGa25-x (x=2,3,4 and 5) based on near stoichiometric Ni2MnGa compositions were directionally solidified using modified Bridgman method. The alloys thus prepared were characterized for their chemical composition, crystal structure, microstructure, phase transformation, magnetic and magneto-mechanical properties. The directionally solidified Ni50Mn30Ga20 alloy rod exhibited maximum magnetocrystalline value of 95 kJm-3 and lowest detwinning stresses for martensite phase of about 5MPa. The reversible room temperature magnetic field induced strain of 0.2% under external magnetic field of 0.6T and 0.05kN bias load was obtained for the directionally solidified Ni50Mn30Ga20 alloy
Interpolation in non-positively curved K\"ahler manifolds
We extend to any simply connected K\"ahler manifold with non-positive
sectional curvature some conditions for interpolation in and in
the unit disk given by Berndtsson, Ortega-Cerd\`a and Seip. The main tool is a
comparison theorem for the Hessian in K\"ahler geometry due to Greene, Wu and
Siu, Yau.Comment: 9 pages, Late
3-Phenyl-1-[2-(3-phenylisoquinolin-1-yl)diselanyl]isoquinoline
The complete molecule of the title compound, C30H20N2Se2, is generated by a crystallographic inversion centre at the mid-point of the Se—Se bond. The dihedral angle between the isoquinoline-1-selenol group and the phenyl ring is 14.92 (2)°. The herringbone-like packing of the structure is supported by intermolecular π–π stacking interactions with a shortest perpendicular distance between isoquinoline groups of 3.514 Å; the slippage between these ring systems is 0.972 Å, and the distance between the centroids of the six-membered carbon rings is 3.645 (3) Å
1-[3-(4-Chlorophenyl)isoquinolin-1-yl]-3,5-diphenyl-1H-pyrazole
The title compound, C30H20ClN3, is composed of a diaryl-substituted pyrazole ring connected to an aryl-substituted isoquinoline ring system with a dihedral angle of 65.1 (1)° between the pyrazole ring and the isoquinoline ring system. The 3-phenyl and 4-phenyl substitutents are twisted by 8.1 (1) and 43.0 (1)°, respectively, with respect to the pyrazole ring. The chlorophenyl ring and the isoquinoline ring system are twisted by 21.2 (1)° with respect to each other
1-(4-Chlorophenyl)-2-phenyl-2-(3-phenyl-1-isoquinolylsulfanyl)ethanone
The title compound, C29H20ClNOS, is a 1-substituted-3-phenylisoquinoline that crystallizes with four independent molecules in the asymmtric unit. The four molecules have similar C—S—C angles. The most noteworthy differences between the molecules relate to the inclination of the 3-phenyl subsituent with respect to the isoquinoline fused-ring [dihedral angles of 21.2 (1), 25.6 (2), 34.3 (1) and 36.5 (2)°]
2-[2-(Cyclohexylcarbonyl)phenyl]-1-phenylethanone
The title diketone, C21H22O2, features a phenylene ring having benzoylmethyl and cyclohexanoyl substituents ortho to each other. The cyclohexyl ring adopts a chair conformation with the ketonic group occupying an equatorial position; the four-atom –C(O)–C ketonic unit is twisted out of the plane of the phenylene ring by 34.9 (1)°
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