331 research outputs found

    1-(4-Chloro-3-fluoro­phen­yl)-2-[(3-phenyl­isoquinolin-1-yl)sulfan­yl]ethanone

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    In the title compound, C23H15ClFNOS, the isoquinoline system and the 4-chloro-3-fluoro­phenyl ring are aligned at 80.4 (1)°. The dihedral angle between the isoquinoline system and the pendant (unsubstituted) phenyl ring is 19.91 (1)°

    Effective constructions in plethysms and Weintraub's conjecture

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    We give a short proof of Weintraub's conjecture by constructing explicit highest weight vectors in the symmetric power of an even exterior power

    1-(4-Chloro­phen­yl)-2-[(3-phenyl­isoquinolin-1-yl)sulfan­yl]ethanone

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    The title compound, C23H16ClNOS, exhibits dihedral angles of 11.73 (1) and 66.07 (1)°, respectively, between the mean plane of the isoquinoline system and the attached phenyl ring, and between the isoquinoline system and the chloro­phenyl ring. The dihedral angle between the phenyl and chlorophenyl rings is 54.66 (1)°

    2-[2-(Hydroxy­meth­yl)phen­yl]-1-(1-naphth­yl)ethanol

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    The mol­ecular conformation of the title compound, C19H18O2, is stabilized by an intra­molecular O—H—O hydrogen bond. In addition, inter­molecular O—H—O inter­actions link the mol­ecules into zigzag chains running along the c axis

    Effect of Mn Concentration on Magneto-mechnaical Properties in Directionally Solidified Ferromagnetic Shape Memory Ni-Mn-Ga Alloys

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    Heusler type alloys Ni50Mn25+xGa25-x  (x=2,3,4 and 5) based on near stoichiometric Ni2MnGa compositions were directionally solidified using modified Bridgman method. The alloys thus prepared were characterized for their chemical composition, crystal structure, microstructure, phase transformation, magnetic  and magneto-mechanical properties. The directionally solidified Ni50Mn30Ga20 alloy rod exhibited maximum magnetocrystalline value of 95 kJm-3 and lowest detwinning stresses for martensite phase of about 5MPa. The reversible room temperature magnetic field induced strain of 0.2% under external magnetic field of 0.6T and 0.05kN bias load was obtained for the directionally solidified Ni50Mn30Ga20 alloy

    Interpolation in non-positively curved K\"ahler manifolds

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    We extend to any simply connected K\"ahler manifold with non-positive sectional curvature some conditions for interpolation in C\mathbb{C} and in the unit disk given by Berndtsson, Ortega-Cerd\`a and Seip. The main tool is a comparison theorem for the Hessian in K\"ahler geometry due to Greene, Wu and Siu, Yau.Comment: 9 pages, Late

    3-Phenyl-1-[2-(3-phenyl­isoquinolin-1-yl)­diselan­yl]isoquinoline

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    The complete molecule of the title compound, C30H20N2Se2, is generated by a crystallographic inversion centre at the mid-point of the Se—Se bond. The dihedral angle between the isoquinoline-1-selenol group and the phenyl ring is 14.92 (2)°. The herringbone-like packing of the structure is supported by inter­molecular π–π stacking inter­actions with a shortest perpendicular distance between isoquinoline groups of 3.514 Å; the slippage between these ring systems is 0.972 Å, and the distance between the centroids of the six-membered carbon rings is 3.645 (3) Å

    1-[3-(4-Chloro­phen­yl)isoquinolin-1-yl]-3,5-diphenyl-1H-pyrazole

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    The title compound, C30H20ClN3, is composed of a diaryl-substituted pyrazole ring connected to an aryl-substituted isoquinoline ring system with a dihedral angle of 65.1 (1)° between the pyrazole ring and the isoquinoline ring system. The 3-phenyl and 4-phenyl substitutents are twisted by 8.1 (1) and 43.0 (1)°, respectively, with respect to the pyrazole ring. The chloro­phenyl ring and the isoquinoline ring system are twisted by 21.2 (1)° with respect to each other

    1-(4-Chloro­phen­yl)-2-phenyl-2-(3-phenyl-1-isoquinolylsulfan­yl)ethanone

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    The title compound, C29H20ClNOS, is a 1-substituted-3-phenyl­isoquinoline that crystallizes with four independent mol­ecules in the asymmtric unit. The four mol­ecules have similar C—S—C angles. The most noteworthy differences between the mol­ecules relate to the inclination of the 3-phenyl subsituent with respect to the isoquinoline fused-ring [dihedral angles of 21.2 (1), 25.6 (2), 34.3 (1) and 36.5 (2)°]

    2-[2-(Cyclo­hexyl­carbon­yl)phen­yl]-1-phenyl­ethanone

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    The title diketone, C21H22O2, features a phenyl­ene ring having benzoyl­methyl and cyclo­hexa­noyl substituents ortho to each other. The cyclo­hexyl ring adopts a chair conformation with the ketonic group occupying an equatorial position; the four-atom –C(O)–C ketonic unit is twisted out of the plane of the phenyl­ene ring by 34.9 (1)°
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