Torrefaction of Sewage Sludge: Kinetics and Fuel Properties of Biochars

We propose a ‘Waste to Carbon’ thermal transformation of sewage sludge (SS) via torrefaction to a valuable product (fuel) with a high content of carbon. One important, technological aspect to develop this concept is the determination of activation energy needed for torrefaction. Thus, this research aimed to evaluate the kinetics of SS torrefaction and determine the effects of process temperature on fuel properties of torrefied products (biochars). Torrefaction was performed using high ash content SS at six (200~300 °C) temperatures and 60 min residence (process) time. Mass loss during torrefaction ranged from 10~20%. The resulting activation energy for SS torrefaction was ~12.007 kJ·mol−1. Initial (unprocessed) SS higher heating value (HHV) was 13.5 MJ·kg−1. However, the increase of torrefaction temperature decreased HHV from 13.4 to 3.8 MJ·kg−1. Elemental analysis showed a significant decrease of the H/C ratio that occurred during torrefaction, while the O/C ratio fluctuated with much smaller differences. Although the activation energy was significantly lower compared with lignocellulosic materials, low-temperature SS torrefaction technology could be explored for further SS stabilization and utilization (e.g., dewatering and hygienization)

Low-Temperature Pyrolysis of Municipal Solid Waste Components and Refuse-Derived Fuel—Process Efficiency and Fuel Properties of Carbonized Solid Fuel

New technologies to valorize refuse-derived fuels (RDFs) will be required in the near future due to emerging trends of (1) the cement industry’s demands for high-quality alternative fuels and (2) the decreasing calorific value of the fuels derived from municipal solid waste (MSW) and currently used in cement/incineration plants. Low-temperature pyrolysis can increase the calorific value of processed material, leading to the production of value-added carbonized solid fuel (CSF). This dataset summarizes the key properties of MSW-derived CSF. Pyrolysis experiments were completed using eight types of organic waste and their two RDF mixtures. Organic waste represented common morphological groups of MSW, i.e., cartons, fabrics, kitchen waste, paper, plastic, rubber, PAP/AL/PE composite packaging (multi-material packaging also known as Tetra Pak cartons), and wood. The pyrolysis was conducted at temperatures ranging from 300 to 500 °C (20 °C intervals), with a retention (process) time of 20 to 60 min (20 min intervals). The mass yield, energy densification ratio, and energy yield were determined to characterize the pyrolysis process efficiency. The raw materials and produced CSF were tested with proximate analyses (moisture content, organic matter content, ash content, and combustible part content) and with ultimate analyses (elemental composition C, H, N, S) and high heating value (HHV). Additionally, differential scanning calorimetry (DSC) and thermogravimetric analyses (TGA) of the pyrolysis process were performed. The dataset documents the changes in fuel properties of RDF resulting from low-temperature pyrolysis as a function of the pyrolysis conditions and feedstock type. The greatest HHV improvements were observed for fabrics (up to 65%), PAP/AL/PE composite packaging (up to 56%), and wood (up to 46%)

Some environmental aspects of ship repair work on floating docks – management of wastes

This paper contains summary of investigations and analyses performed by Institute of Environment Engineering Systems, Warsaw University of Technology, in the area of management of the wastes produced in the course of ship repair work on floating docks. During the investigations carried out in Gdynia Naval Shipyard, were determined substances which qualitatively characterize selected wastes (in their original form as well as their water extracts), and amount of the wastes of basic groups, produced during floating dock service and repair and modernization work carried out on it, was estimated. Recommendations for waste managing on floating docks are presented, including possible ways of utilization of the wastes as well as their final usage (recovery and/or neutralization)

An Insight into Post-Consumer Food Waste Characteristics as the Key to an Organic Recycling Method Selection in a Circular Economy

Reducing the phenomenon of food waste and effective management of already wasted food in the form of post-consumer waste, included in the source-separated organic fraction of municipal solid waste (SS-OFMSW) from households and catering facilities, are some of the key challenges of the circular economy (CE), in particular in highly urbanized areas. The basis for the effective use of this waste is the knowledge of its physical and chemical properties. The main objective of the paper is to identify the key technological and organizational parameters for selective collection determining the characteristics of the SS-OFMSW and, consequently, the optimal path for its management. This paper presents the results of qualitative research of SS-OFMSW generated in the capital of Poland—Warsaw—coming from three sources: multi- and single-family housing and catering facilities. The collection efficiency of this waste was determined in the form of quality in container rate (QCR = 92–97%) and variability in terms of impurities and admixtures present in it (CV = 56–87%). High variability indicates that the system of selective waste collection in Warsaw is immature, which may hinder undertaking activities in the field of waste management planning. The study confirmed the suitability of the tested SS-OFMSW for organic recycling, especially using anaerobic digestion (AD), to which it is predisposed by water content, C/N, and biomethane potential (BMP). All tested food waste is characterized by a high yield of biogas in the range of 384–426 m3/Mg VS and an average share of methane in biogas at the level of 52–61%. Fertilizer properties, moisture, and its gas potential show little variability (CV ≤ 16%), which means that these data can be treated as stable data. The obtained results indicate the optimal direction for the collection and processing of SS-OFMSW based on post-consumer food waste in urbanized areas

Stomatal Conductance Measurement for Toxicity Assessment in Zero-Effluent Constructed Wetlands: Effects of Landfill Leachate on Hydrophytes

In this research, we explore for the first time the use of leaf stomatal conductance (gs) for phytotoxicity assessment. Plants respond to stress by regulating transpiration. Transpiration can be correlated with stomatal conductance when the water vapor pressure gradient for transpiration is constant. Thus, our working hypothesis was that the gs measurement could be a useful indicator of the effect of toxic compounds on plants. This lab-scale study aimed to test the measurement of gs as a phytotoxicity indicator. Our model plants were two common hydrophytes used in zero-effluent constructed wetlands for treating landfill leachate. The toxic influence of two types of leachate from old landfills (L1, L2) on common reed (Phragmites australis (Cav.) Trin. ex Steud.) and sweet flag (Acorus calamus L.) was tested. The gs measurements correlated well with plant response to treatments with six solutions (0 to 100%) of landfill leachate. Sweet flag showed higher tolerance to leachate solutions compared to common reed. The estimated lowest effective concentration (LOEC) causing the toxic effect values for these leachates were 3.94% of L1 and 5.76% of L2 in the case of reed, and 8.51% of L1 and 10.44% of L2 in the case of sweet flag. Leachate L1 was more toxic than L2. The leaf stomatal conductance measurement can be conducted in vivo and in the field. The proposed approach provides a useful parameter for indicating plant responses to the presence of toxic factors in the environment.This article is published as Białowiec, Andrzej, Jacek A. Koziel, and Piotr Manczarski. "Stomatal Conductance Measurement for Toxicity Assessment in Zero-Effluent Constructed Wetlands: Effects of Landfill Leachate on Hydrophytes." International Journal of Environmental Research and Public Health 16, no. 3 (2019): 468. DOI: 10.3390/ijerph16030468. Posted with permission.</p