32 research outputs found
Reaction of 3,4,3',4'-tetradehydrobiphenyl (bisbenzyne) with tetracyclone and acecyclone
173-1763,4,3',4'-Tetradehydrobiphenyl
2 as a reactive intermediate was
generated from aprotic diazotization reaction of 3,3'dicarboxy-4,4'-diaminobiphenyl
1<span style="font-size:15.5pt;
mso-bidi-font-size:9.5pt"> <span style="font-size:15.0pt;mso-bidi-font-size:
9.0pt">with isoamyl nitrite and subsequent thermal decomposition of the
resulting diazonium salt. This intermediate is reacted with 2,3,4,5-tetraphenylcyclopentadienone
(tetracyclone) 3 and 7,9-diphenyl-8H-cyclopenta[a]acenaphthylene-8-one
(acecyclone) 6 and the resulting
polycyclic aromatic hydrocarbons (PAH's) 4
and 9 are
obtained in high yield.</span
Synthesis of new heterocyclic compounds via cycloaddtion reaction
812-816The reaction of bis-(p-3,5-dioxo-1,2,4-triazolin-4-yl)methane
(diphenyl methanebistriazol- inedione. DPMBTAD) with monomeric cyclopentadiene,
5,5- dimethoxy-1,2,3,4-tetrachlorocyclopentadiene, hexachlorocyclopentadiene, isoprene,
1,3-cyclohexadiene, and anthracene has been investigated. These reactions
occurred via [4+2] Diels-Alder cycloaddition reaction and lead to the format ion
of novel heterocyclic bis-adducts in quantitative yields. The reaction of
DPMBTAD with monomeric cyclopentadiene, 1,3-cyc lohexadiene and isoprene are extremely
fast even at -10°C in methylene chloride solution
Reaction of indanocyclone with 3,4,3',4'-tetradehydrobiphenyl(bisbenzyne)
465-469Diphenyl-4,4'- bis-diazonium-3,3'-dicarboxylate
has been prepared from diazotization reaction of 3,3'-dicarboxy-4,4'diaminobiphenyl
4 with isoamylnitrite under aprotic conditions. Thermal decomposition in
situ of this diazonium salt in 1,1,2- trichloroethane as a solvent yields
3,4,3',4'-tetradehydrobiphenyl 5 as a reactive intermediate. This reactive
intermediate has been trapped with indanocyclone
via a [4+2] Diels-Alder cycloaddition reaction. Three isomeric products are formed
after loss of carbon monoxide which have been isolated by praparitive TLC. Although
these novel polycyclic aromatic hydrocarbons (PAH·s) have similar (IR,1H
NMR, mass) spectra and elemental analysis, but they have different Rf
values. Three different structures have been proposed for these novel compounds
Synthesis of naphthalene and binaphthyl derivatives via arynes intermediates
376-378Benzyne from anthranilic acid has been reacted
with 2,5-di-n-propyl-3,4 diphenylcyclopentadienone (n-propylcyclone)
in boiling 1,2-dichloroethane to get 1,4-di-n-propyl-2 ,3-diphen-ylnaphthalene
in quantitative yield. Bis-benzyne from aprotic diazotization of
3,3'-dicarboxyl-4,4'-diaminobiphenyl is also reacted with this cyclone leading to
the formation of a novel polyaromatic adduct 1,1',4,4'-tetra-n-propyl-2,2'
,3,3'-tetraphenyl-6,6'-binaphthyl 6 in a good yield. The above
polycyclic aromatic hydrocarbons (PAH,s) have been characterized by high field 1H-NMR,
13C-NMR, IR, mass spectra and elemental analysis. These compounds
can be used as analytical samples for the studies of their possible presence in
combustion pollutants
Synthesis of novel azo dyes derived from 4-phenylurazole
169-174A novel and convenient method for the
preparation of 4-(4-aminophenyl) urazole has been developed. Protic diazotization
of amino group of this compound and subsequent coupling reaction with some
electron rich aromatic compounds such as phenols, naphthols, and ani lines lead
to the formation of novel azo dyes with a phenylurazole linkage in moderate to
high yields.
Stereoselective chlorination of non-conjugated heterocyclic alkenes
777-782Diels-Alder adducts of 4-substituted triazolinediones (4-Ph, 4-n-Pr) with cyclopellladienes have heen
reacted with chlorine in carbon tetrachloride. When R = Ph only, cis-dichloride adduct is obtained in a
stereos pecific manner. However,
when R = n-Pr,
two products, the cis-dichloride adduct
and the rearrangement adduct are obtained in a stereoselective manner. The
adducts of these triazolinediones with 1,3-cyclohexadiene have also been
reacted with chlorine. When R = Ph, the trans-dichloride
is formed with a high degree of stereoselectivity (98%). However, when R = n-Pr, two products, the trans-dichloride and the
rearrangement adduct are obtained in 4:1 ratio.</span
A new facile and rapid synthesis of acyl azides under solvent-free conditions
1234-1235A rapid and simple method for the preparation of acyl
azides is described. The reaction is carried out under solvent-free conditions
from the reaction of acid chlorides with sodium azide supported on silica gel.
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