A comparative study of the DR reactions of c-C3H+3 and l-C3H+3: Preliminary theoretical studies

International audiencePreliminary calculations related to the dissociative recombination (DR) of electrons with C3H+3 have been carried out. Both the linear and cyclic isomers of this ion exist in the interstellar medium, and accurate DR rate constants for both isomers are needed for astrophysical models. The electronic structure calculations reported here yield quasi-diabatic potential energy curves that can be used to assess the efficiency of dissociation of a CH bond. The calculations confirm a favorable position of a dissociative state for the cyclic isomer and suggest that dissociation of the linear isomer is less probable. More detailed dynamical studies are planned, and a normal mode analysis of the vibrational modes of C3H+3 is reported as the first step in that direction

Theoretical calculations of rotationally inelastic collisions of He with NaK( A 1 Σ + ): Transfer of population, orientation, and alignment

International audienc

The Applicability of Time-Integrated Unit Stream Power for Estimating Bridge Pier Scour Using Noncontact Methods in a Gravel-Bed River

In near-field remote sensing, noncontact methods (radars) that measure stage and surface water velocity have the potential to supplement traditional bridge scour monitoring tools because they are safer to access and are less likely to be damaged compared with in-stream sensors. The objective of this study was to evaluate the use of radars for monitoring the hydraulic conditions that contribute to bridge–pier scour in gravel-bed channels. Measurements collected with a radar were also leveraged along with minimal field measurements to evaluate whether time-integrated stream power per unit area (Ω) was correlated with observed scour depth at a scour-critical bridge in Colorado. The results of this study showed that (1) there was close agreement between radar-based and U.S. Geological Survey streamgage-based measurements of stage and discharge, indicating that radars may be viable tools for monitoring flow conditions that lead to bridge pier scour; (2) Ω and pier scour depth were correlated, indicating that radar-derived Ω measurements may be used to estimate scour depth in real time and predict scour depth based on the measured trajectory of Ω. The approach presented in this study is intended to supplement, rather than replace, existing high-fidelity scour monitoring techniques and provide data quickly in information-poor areas

The Applicability of Time-Integrated Unit Stream Power for Estimating Bridge Pier Scour Using Noncontact Methods in a Gravel-Bed River

In near-field remote sensing, noncontact methods (radars) that measure stage and surface water velocity have the potential to supplement traditional bridge scour monitoring tools because they are safer to access and are less likely to be damaged compared with in-stream sensors. The objective of this study was to evaluate the use of radars for monitoring the hydraulic conditions that contribute to bridge–pier scour in gravel-bed channels. Measurements collected with a radar were also leveraged along with minimal field measurements to evaluate whether time-integrated stream power per unit area (Ω) was correlated with observed scour depth at a scour-critical bridge in Colorado. The results of this study showed that (1) there was close agreement between radar-based and U.S. Geological Survey streamgage-based measurements of stage and discharge, indicating that radars may be viable tools for monitoring flow conditions that lead to bridge pier scour; (2) Ω and pier scour depth were correlated, indicating that radar-derived Ω measurements may be used to estimate scour depth in real time and predict scour depth based on the measured trajectory of Ω. The approach presented in this study is intended to supplement, rather than replace, existing high-fidelity scour monitoring techniques and provide data quickly in information-poor areas

Evidence for 2.0 Ga continental microbial mats in a paleodesert setting

Early evolved microbial communities characterized the initial biological invasion of Precambrian continental landscapes. In modern arid settings, microbial mats and biological soil crusts are well-developedand stabilize sediment. The Paleoproterozoic Makgabeng Formation in South Africa is one of the oldestand best preserved, dryland systems on Earth. Six types of microbial mat-related structures are nowrecognized within these depositional systems. This paper presents three newly discovered structures that include tufted microbial mat, biological soil crusts, and gas-escape features, in addition to three previously documented structures that include roll up features, sand cracks, and wrinkled features. These discoveries demonstrate that microbial communities were well-established and inhabited diverse continental settings by 2.0 Ga, approximately 200 million years after the onset of the Great Oxidation Event

Evidence for climate shifts in the similar to 2.0 Ga upper Makgabeng Formation erg, South Africa

Eolian ergs, and associated environs are sensitive to short- and long-term climate changes. In one of the oldest, erg deposits, the ~2.0 Ga Makgabeng Formation, facies association changes reflect one of the earliest recordings of short-term climatic shifts in a continental setting. The Makgabeng Formation is separated into lower and upper erg deposits by a playa or saline pan deposit. The lower erg deposit consists of dune sets with thin lenses of dry and deflationary interdunes that transitions vertically to thicker damp to wet interdunes. A laterally persistent playa deposit in the middle of the section consists of mudstone with deep and shallow penetrating mud cracks and subordinate siltstone and sandstone interbeds. Above this lower mudstone interval, the playa strata are sandy. Overlying the playa deposit, the upper erg deposit consists of thick eolian sets with thin lenses of dry interdune deposits. Grain size change near the top of the upper erg deposit corresponds to the appearance of fluvial, sheet flood, eolian cross-beds sculpted by mass flows, and thin playa deposits. The vertical facies association demonstrates shifts in precipitation and fluctuating water tables. Fluvial and playa deposits record high water tables whereas low-water tables are reflected in the core erg. The transition from a lower to higher water table is recorded by wet interdune interspersed within the dune strata towards the top of this interval. Rapid climatic amelioration occurred near the termination of the Makgabeng erg resulting in impingement of ephemeral river systems, development of playas, and generation of massive sand flows. This 2.0 Ga erg demonstrates the impact of climate change on erg development, resulting from shifts in the monsoonal impingement through time.Kutztown University Undergraduate Research Committee, Kutztown University Research Committee, Kutztown University Foundation, Kumba-Exxaro, the National Research Foundation, and the University of Pretoria in South Africa.http://elsevier.com/locate/palaeohb201