639 research outputs found

    Precipitation of carbon from martensite in ductile iron

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    Since metallographic studies of quenched and tempered cast iron have indicated that the carbon might precipitate directly as graphite rather than as carbides which are found in steels, this investigation used the Debye-Scherrer x-ray diffraction technique to examine electrolytically extracted residues from quenched and tempered ductile cast iron samples to determine if cementite was present. The precipitation of carbon in quenched samples of this ductile cast iron was found to be similar to the precipitation process in steels. Cementite was identified during the early stages of the tempering process when the tempering temperature was 800 degrees F, 900 degrees F, and 1000 degrees F. Cementite was not found in samples tempered at 600 degrees F and 700 degrees F. No attempt was made to identify carbides others than cementite, and it was not determined if transition carbides precipitated at the lower tempering temperatures. The cementite was found to be unstable in the cast iron and decomposed rather rapidly at the tempering temperatures at which it formed. No cementite was present after 30 minutes tempering at 800 degrees F, after 15 minutes at 900 degrees F or after 10 minutes at 1000 degrees F. The hardness was found to continue to drop after all the cementite had graphitized, presumably due to coarsening of the graphite precipitate and possibly also due to additional slow precipitation of carbon which could have graphitized as rapidly as it precipitated --Abstract, pages ii-iii

    Sternoclavicular joint arthropathy mimicking radiculopathy in a patient with concurrent C4-5 disc herniation

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    Background Patients with sternoclavicular joint arthropathy, which can result from septic arthritis, often present with localized sternoclavicular pain as well as shoulder pain. Such pain may be similar to the presenting symptoms of cervical intervertebral disc herniation. Clinical presentation A 47-year-old female presented with 1 month of significant pain in the neck as well as right anterior chest and deltoid. The patient was found to have reduced strength in the right deltoid muscle on physical examination. MRI revealed a C4-C5 herniated nucleus pulposus. The patient underwent successful C4-C5 anterior cervical discectomy, but subsequently developed painful swelling in the region of the right sternoclavicular joint with limited motor strength in the right shoulder and arm. A needle biopsy of the mass yielded negative results, but her erythrocyte sedimentation rate (ESR) and C-reactive protein (CRP) numbers did respond to antibiotics, consistent with infection of the sternoclavicular joint. A follow-up CT scan (6.5 months postoperatively) revealed apparent resolution right sternoclavicular joint arthropathy, thought the patient continued to experience pain. 15 months postoperatively, the patient was prescribed methotrexate due to persistent pain and mild weakness arising from a possible rheumatologic inflammation. 19 months postoperatively, the patient had full strength of the right shoulder and arm and visible decrease in swelling at the sternoclavicular joint. More than three years postoperatively, the patient was diagnosed with multiple myeloma, which was appropriately treated. At follow-up four years postoperatively, the patient had an MRI showing new C6-C7 herniated nucleus pulposus, but no longer had any right shoulder or chest pain or associated weakness. Conclusion This case demonstrates that sternoclavicular joint arthropathy results in symptoms that can mimic the presenting symptoms of shoulder or cervical spine pathology, such as shoulder and neck pain, necessitating careful diagnosis and management

    Social Bots for Online Public Health Interventions

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    According to the Center for Disease Control and Prevention, in the United States hundreds of thousands initiate smoking each year, and millions live with smoking-related dis- eases. Many tobacco users discuss their habits and preferences on social media. This work conceptualizes a framework for targeted health interventions to inform tobacco users about the consequences of tobacco use. We designed a Twitter bot named Notobot (short for No-Tobacco Bot) that leverages machine learning to identify users posting pro-tobacco tweets and select individualized interventions to address their interest in tobacco use. We searched the Twitter feed for tobacco-related keywords and phrases, and trained a convolutional neural network using over 4,000 tweets dichotomously manually labeled as either pro- tobacco or not pro-tobacco. This model achieves a 90% recall rate on the training set and 74% on test data. Users posting pro- tobacco tweets are matched with former smokers with similar interests who posted anti-tobacco tweets. Algorithmic matching, based on the power of peer influence, allows for the systematic delivery of personalized interventions based on real anti-tobacco tweets from former smokers. Experimental evaluation suggests that our system would perform well if deployed. This research offers opportunities for public health researchers to increase health awareness at scale. Future work entails deploying the fully operational Notobot system in a controlled experiment within a public health campaign

    Stochastic Re-weighted Gradient Descent via Distributionally Robust Optimization

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    We present Re-weighted Gradient Descent (RGD), a novel optimization technique that improves the performance of deep neural networks through dynamic sample importance weighting. Our method is grounded in the principles of distributionally robust optimization (DRO) with Kullback-Leibler divergence. RGD is simple to implement, computationally efficient, and compatible with widely used optimizers such as SGD and Adam. We demonstrate the broad applicability and impact of RGD by achieving state-of-the-art results on diverse benchmarks, including improvements of +0.7% (DomainBed), +1.44% (tabular classification), +1.94% (GLUE with BERT), and +1.01% (ImageNet-1K with ViT)
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