2 research outputs found
Re-Mediated CāC Coupling of Pyridines and Imidazoles
No full textRhenium tricarbonyl complexes with three <i>N</i>-heterocyclic
ligands (<i>N</i>-alkylimidazoles or pyridines) undergo
deprotonation with KNĀ(SiMe<sub>3</sub>)<sub>2</sub> and then oxidation
with AgOTf to afford complexes with pyridylimidazole or bipyridine
bidentate ligands resulting from deprotonation, CāC coupling
and rearomatization
Re-Mediated CāC Coupling of Pyridines and Imidazoles
No full textRhenium tricarbonyl complexes with three <i>N</i>-heterocyclic
ligands (<i>N</i>-alkylimidazoles or pyridines) undergo
deprotonation with KNĀ(SiMe<sub>3</sub>)<sub>2</sub> and then oxidation
with AgOTf to afford complexes with pyridylimidazole or bipyridine
bidentate ligands resulting from deprotonation, CāC coupling
and rearomatization
