6 research outputs found
Nitrogen-Doped Flower-Like Hybrid Structure Based on Three-Dimensional Graphene
A new flower-like hybrid structure consisting of nitrogen-doped 3-dimensional (3D) graphene and vertically aligned graphene has been synthesized using a combination of low-pressure chemical vapor deposition (LPCVD) and plasma-enhanced chemical vapor deposition (PECVD) techniques. Active nitrogen (N) species were found to be essential for the growth of the flower-like morphology. N-doping was responsible for enhanced electrical conductivity and wettability of the obtained nano-carbon hybrid structure. Based on the conducted studies a growth mechanism has been proposed. The high specific surface area, low resistance to charge transfer and enhanced specific capacitance of this nitrogen-doped hybrid structure, makes it an excellent candidate material for supercapacitors
Plasma-Enhanced Carbon Nanotube Fiber Cathode for Li-S Batteries
Fiber-shaped batteries have attracted much interest in the last few years. However, a major challenge for this type of battery is their relatively low energy density. Here, we present a freestanding, flexible CNT fiber with high electrical conductivity and applied oxygen plasma-functionalization, which was successfully employed to serve as an effective cathode for Li-S batteries. The electrochemical results obtained from the conducted battery tests showed a decent rate capability and cyclic stability. The cathode delivered a capacity of 1019 mAh g−1 at 0.1 C. It accommodated a high sulfur loading of 73% and maintained 47% of the initial capacity after 300 cycles. The demonstrated performance of the fiber cathode provides new insights for the designing and fabrication of high energy density fiber-shaped batteries
Asymmetric Fiber Supercapacitors Based on a FeC2O4/FeOOH-CNT Hybrid Material
The development of new flexible and lightweight electronics has increased the demand for compatible energy storage devices to power them. Carbon nanotube (CNT) fibers have long been known for their ability to be assembled into yarns, offering their integration into electronic devices. They are hindered, however, by their low intrinsic energy storage properties. Herein, we report a novel composite yarn, synthesized through solvothermal processes, that attained energy densities in the range between 0.17 µWh/cm2 and 3.06 µWh/cm2, and power densities between 0.26 mW/cm2 and 0.97 mW/cm2, when assembled in a supercapacitor with a PVDF-EMIMBF4 electrolyte. The created unique composition of iron oxalate + iron hydroxide + CNT as an anode worked well in synergy with the much-studied PANI + CNT cathode, resulting in a highly stable yarn energy storage device that maintained 96.76% of its energy density after 4000 cycles. This device showed no observable change in performance under stress/bend tests which makes it a viable candidate for powering wearable electronics
Lightweight Copper–Carbon Nanotube Core–Shell Composite Fiber for Power Cable Application
The substitution of traditional copper power transmission cables with lightweight copper–carbon nanotube (Cu–CNT) composite fibers is critical for reducing the weight, fuel consumption, and CO2 emissions of automobiles and aircrafts. Such a replacement will also allow for lowering the transmission power loss in copper cables resulting in a decrease in coal and gas consumption, and ultimately diminishing the carbon footprint. In this work, we created a lightweight Cu–CNT composite fiber through a multistep scalable process, including spinning, densification, functionalization, and double-layer copper deposition. The characterization and testing of the fabricated fiber included surface morphology, electrical conductivity, mechanical strength, crystallinity, and ampacity (current density). The electrical conductivity of the resultant composite fiber was measured to be 0.5 × 106 S/m with an ampacity of 0.18 × 105 A/cm2. The copper-coated CNT fibers were 16 times lighter and 2.7 times stronger than copper wire, as they revealed a gravimetric density of 0.4 g/cm3 and a mechanical strength of 0.68 GPa, suggesting a great potential in future applications as lightweight power transmission cables
Three-Dimensional Graphene Sheet-Carbon Veil Thermoelectric Composite with Microinterfaces for Energy Applications
Over
the years, various processing techniques have been explored
to synthesize three-dimensional graphene (3DG) composites with tunable
properties for advanced applications. In this work, we have demonstrated
a new procedure to join a 3D graphene sheet (3DGS) synthesized by
chemical vapor deposition (CVD) with a commercially available carbon
veil (CV) via cold rolling to create 3DGS-CV composites. Characterization
techniques such as scanning electron microscopy (SEM), Raman mapping,
X-ray diffraction (XRD), electrical resistance, tensile strength,
and Seebeck coefficient measurements were performed to understand
various properties of the 3DGS-CV composite. Extrusion of 3DGS into
the pores of CV with multiple microinterfaces between 3DGS and the
graphitic fibers of CV was observed, which was facilitated by cold
rolling. The extruded 3D graphene revealed pristine-like behavior
with no change in the shape of the Raman 2D peak and Seebeck coefficient.
Thermoelectric (TE) power generation and photothermoelectric responses
have been demonstrated with in-plane TE devices of various designs
made of p-type 3DGS and n-type CV couples yielding a Seebeck coefficient
of 32.5 μV K–1. Unlike various TE materials,
3DGS, CV, and the 3DGS-CV composite were very stable at high relative
humidity. The 3DGS-CV composite revealed a thin, flexible profile,
good moisture and thermal stability, and scalability for fabrication.
These qualities allowed it to be successfully tested for temperature
monitoring of a Li-ion battery during charging cycles and for large-area
temperature mapping