219 research outputs found
Numerically exact, time-dependent treatment of vibrationally coupled electron transport in single-molecule junctions
The multilayer multiconfiguration time-dependent Hartree (ML-MCTDH) theory
within second quantization representation of the Fock space, a novel
numerically exact methodology to treat many-body quantum dynamics for systems
containing identical particles, is applied to study the effect of vibrational
motion on electron transport in a generic model for single-molecule junctions.
The results demonstrate the importance of electronic-vibrational coupling for
the transport characteristics. For situations where the energy of the bridge
state is located close to the Fermi energy, the simulations show the
time-dependent formation of a polaron state that results in a pronounced
suppression of the current corresponding to the phenomenon of phonon blockade.
We show that this phenomenon cannot be explained solely by the polaron shift of
the energy but requires methods that incorporate the dynamical effect of the
vibrations on the transport. The accurate results obtained with the ML-MCTDH in
this parameter regime are compared to results of nonequilibrium Green's
function (NEGF) theory.Comment: 39 pages, 11 figure
Thermoelectric effects in a strongly correlated model for NaCoO
Thermal response functions of strongly correlated electron systems are of
appreciable interest to the larger scientific community both theoretically and
technologically. Here we focus on the infinitely correlated t-J model on a
geometrically frustrated two-dimensional triangular lattice.
Using exact diagonalization on a finite sized system we calculate the
dynamical thermal response functions in order to determine the thermopower,
Lorenz number, and dimensionless figure of merit. The dynamical thermal
response functions is compared to the infinite frequency limit and shown to be
very weak functions of frequency, hence, establishing the validity of the high
frequency formalism recently proposed by Shastry for the thermopower, Lorenz
number, and the dimensionless figure of merit. Further, the thermopower is
demonstrated to have a low to mid temperature enhancement when the sign of the
hopping parameter is switched from positive to negative for the
geometrically frustrated lattice considered.Comment: 16 pages, 10 figures, color version available at
http://physics.ucsc.edu/~peterson/mrpeterson-condmat-NCO.pdf. V.2 has fixed
minor typos in Eq. 11, 19, 25, and 26. V.3 is a color versio
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Smartphone-based pathogen diagnosis in urinary sepsis patients.
BackgroundThere is an urgent need for rapid, sensitive, and affordable diagnostics for microbial infections at the point-of-care. Although a number of innovative systems have been reported that transform mobile phones into potential diagnostic tools, the translational challenge to clinical diagnostics remains a significant hurdle to overcome.MethodsA smartphone-based real-time loop-mediated isothermal amplification (smaRT-LAMP) system was developed for pathogen ID in urinary sepsis patients. The free, custom-built mobile phone app allows the phone to serve as a stand-alone device for quantitative diagnostics, allowing the determination of genome copy-number of bacterial pathogens in real time.FindingsA head-to-head comparative bacterial analysis of urine from sepsis patients revealed that the performance of smaRT-LAMP matched that of clinical diagnostics at the admitting hospital in a fraction of the time (~1 h vs. 18-28 h). Among patients with bacteremic complications of their urinary sepsis, pathogen ID from the urine matched that from the blood - potentially allowing pathogen diagnosis shortly after hospital admission. Additionally, smaRT-LAMP did not exhibit false positives in sepsis patients with clinically negative urine cultures.InterpretationThe smaRT-LAMP system is effective against diverse Gram-negative and -positive pathogens and biological specimens, costs less than $100 US to fabricate (in addition to the smartphone), and is configurable for the simultaneous detection of multiple pathogens. SmaRT-LAMP thus offers the potential to deliver rapid diagnosis and treatment of urinary tract infections and urinary sepsis with a simple test that can be performed at low cost at the point-of-care. FUND: National Institutes of Health, Chan-Zuckerberg Biohub, Bill and Melinda Gates Foundation
Development of Fuses for Protection of Geiger-Mode Avalanche Photodiode Arrays
Current-limiting fuses composed of Ti/Al/Ni were developed for use in Geiger-mode avalanche photodiode arrays for each individual pixel in the array. The fuses were designed to burn out at ∼4.5 × 10[superscript −3] A and maintain post-burnout leakage currents less than 10[superscript −7] A at 70 V sustained for several minutes. Experimental fuse data are presented and successful incorporation of the fuses into a 256 × 64 pixel InP-based Geiger-mode avalanche photodiode array is reported
Molecular transport junctions: Current from electronic excitations in the leads
Using a model comprising a 2-level bridge connecting free electron reservoirs
we show that coupling of a molecular bridge to electron-hole excitations in the
leads can markedly effect the source-drain current through a molecular
junction.In some cases, e.g. molecules that exhibit strong charge transfer
transitions, the contribution from electron-hole excitations can exceed the
Landauer elastic current and dominate the observed conduction.Comment: 4 pages, 2 figures, submitted to PR
Inelastic effects in molecular junctions in the Coulomb and Kondo regimes: Nonequilibrium equation-of-motion approach
Inelastic effects in the Coulomb blockade and Kondo regimes of electron
transport through molecular junctions are considered within a simple
nonequilibrium equation-of-motion (EOM) approach. The scheme is
self-consistent, and can qualitatively reproduce the main experimental
observations of vibrational features in Coulomb blockade [H.Park et al., Nature
407, 57 (2000)] and Kondo [L.H.Yu et al., Phys. Rev. Lett. 93, 266802 (2004)]
regimes. Considerations similar to the equilibrium EOM approach by Meir et al.
[Phys. Rev. Lett. 66, 3048 (1991); ibid. 70, 2601 (1993)] are used on the
Keldysh contour to account for the nonequilibrium nature of the junction, and
dressing by appropriate Franck-Condon (FC) factors is used to account for
vibrational features. Results of the equilibrium EOM scheme by Meir et al. are
reproduced in the appropriate limit.Comment: 12 pages, 5 figure
Transport in molecular states language: Generalized quantum master equation approach
A simple scheme capable of treating transport in molecular junctions in the
language of many-body states is presented. An ansatz in Liouville space similar
to generalized Kadanoff-Baym approximation is introduced in order to reduce
exact equation-of-motion for Hubbard operator to quantum master equation
(QME)-like expression. A dressing with effective Liouville space propagation
similar to standard diagrammatic dressing approach is proposed. The scheme is
compared to standard QME approach, and its applicability to transport
calculations is discussed within numerical examples.Comment: 10 pages, 3 figure
Finite temperature Drude weight of an integrable Bose chain
We study the Drude weight at finite temperatures of an integrable
bosonic model where the particles interact via nearest-neighbour coupling on a
chain. At low temperatures, is shown to be universal in the sense that
this region is equivalently described by a Gaussian model. This low-temperature
limit is also relevant for the integrable one-dimensional Bose gas. We then use
the thermodynamic Bethe ansatz to confirm the low-temperature result, to obtain
the high temperature limit of and to calculate numerically.Comment: 11 pages, 2 figure
Phonon-assisted transitions from quantum dot excitons to cavity photons
For a single semiconductor quantum dot embedded in a microcavity, we
theoretically and experimentally investigate phonon-assisted transitions
between excitons and the cavity mode. Within the framework of the independent
boson model we find that such transitions can be very efficient, even for
relatively large exciton-cavity detunings of several millielectron volts.
Furthermore, we predict a strong detuning asymmetry for the exciton lifetime
that vanishes for elevated lattice temperature. Our findings are corroborated
by experiment, which turns out to be in good quantitative and qualitative
agreement with theory
Transport and optical response of molecular junctions driven by surface plasmon-polaritons
We consider a biased molecular junction subjected to external time-dependent
electromagnetic field. The field for two typical junction geometries (bowtie
antennas and metal nanospheres) is calculated within finite-difference
time-domain technique. Time-dependent transport and optical response of the
junctions is calculated within non-equilibrium Green's function approach
expressed in a form convenient for description of multi-level systems. We
present numerical results for a two-level (HOMO-LUMO) model, and discuss
influence of localized surface plasmon polariton modes on transport.Comment: 9 pages, 6 figure
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