CARS Spectral Fitting with Multiple Resonant Species using Sparse Libraries

The dual pump CARS technique is often used in the study of turbulent flames. Fast and accurate algorithms are needed for fitting dual-pump CARS spectra for temperature and multiple chemical species. This paper describes the development of such an algorithm. The algorithm employs sparse libraries, whose size grows much more slowly with number of species than a conventional library. The method was demonstrated by fitting synthetic "experimental" spectra containing 4 resonant species (N2, O2, H2 and CO2), both with noise and without it, and by fitting experimental spectra from a H2-air flame produced by a Hencken burner. In both studies, weighted least squares fitting of signal, as opposed to least squares fitting signal or square-root signal, was shown to produce the least random error and minimize bias error in the fitted parameters

Development of a Dual-Pump CARS System for Measurements in a Supersonic Combusting Free Jet

This work describes the development of a dual-pump CARS system for simultaneous measurements of temperature and absolute mole fraction of N2, O2 and H2 in a laboratory scale supersonic combusting free jet. Changes to the experimental set-up and the data analysis to improve the quality of the measurements in this turbulent, high-temperature reacting flow are described. The accuracy and precision of the instrument have been determined using data collected in a Hencken burner flame. For temperature above 800 K, errors in absolute mole fraction are within 1.5, 0.5, and 1% of the total composition for N2, O2 and H2, respectively. Estimated standard deviations based on 500 single shots are between 10 and 65 K for the temperature, between 0.5 and 1.7% of the total composition for O2, and between 1.5 and 3.4% for N2. The standard deviation of H2 is ~10% of the average measured mole fraction. Results obtained in the jet with and without combustion are illustrated, and the capabilities and limitations of the dual-pump CARS instrument discussed

Beam Shaping for CARS Measurements in Turbulent Environments

This paper describes a new technique to mitigate the effect of beam steering on CARS measurements in turbulent, variable density environments. The new approach combines Planar BOXCARS phase-matching with elliptical shaping of one of the beams to generate a signal insensitive to beam steering, while keeping the same spatial resolution. Numerical and experimental results are provided to demonstrate the effectiveness of this approach. One set of experiments investigated the effect of beam shaping in the presence of a controlled and well quantified displacement of the beams at the focal plane. Another set of experiments, more qualitative, proved the effectiveness of the technique in the presence of severe beam steering due to turbulence

Dual-Pump CARS Development and Application to Supersonic Combustion

A dual-pump Coherent Anti-Stokes Raman Spectroscopy (CARS) instrument has been developed to obtain simultaneous measurements of temperature and absolute mole fractions of N2, O2 and H2 in supersonic combustion and generate databases for validation and development of CFD codes. Issues that compromised previous attempts, such as beam steering and high irradiance perturbation effects, have been alleviated or avoided. Improvements in instrument precision and accuracy have been achieved. An axis-symmetric supersonic combusting coaxial jet facility has been developed to provide a simple, yet suitable flow to CFD modelers. Approximately one million dual-pump CARS single shots have been collected in the supersonic jet for varying values of flight and exit Mach numbers at several locations. Data have been acquired with a H2 co-flow (combustion case) or a N2 co-flow (mixing case). Results are presented and the effects of the compressibility and of the heat release are discussed

Development of Supersonic Combustion Experiments for CFD Modeling

This paper describes the development of an experiment to acquire data for developing and validating computational fluid dynamics (CFD) models for turbulence in supersonic combusting flows. The intent is that the flow field would be simple yet relevant to flows within hypersonic air-breathing engine combustors undergoing testing in vitiated-air ground-testing facilities. Specifically, it describes development of laboratory-scale hardware to produce a supersonic combusting coaxial jet, discusses design calculations, operability and types of flames observed. These flames are studied using the dual-pump coherent anti- Stokes Raman spectroscopy (CARS) - interferometric Rayleigh scattering (IRS) technique. This technique simultaneously and instantaneously measures temperature, composition, and velocity in the flow, from which many of the important turbulence statistics can be found. Some preliminary CARS data are presented

Dual-Pump CARS Measurements in the University of Virginia's Dual-Mode Scramjet: Configuration "A"

In this paper we describe efforts to obtain canonical data sets to assist computational modelers in their development of models for the prediction of mixing and combustion in scramjet combustors operating in the ramjet-scramjet transition regime. The CARS technique is employed to acquire temporally and spatially resolved measurements of temperature and species mole-fraction at four planes, one upstream of an H2 fuel injector and three downstream. The technique is described and results are presented for cases with and without chemical reaction. The vibrational energy mode in the heated airstream of the combustor was observed to be frozen at near facility heater conditions and significant nonuniformities in temperature were observed, attributed to nonuniformities of temperature exiting the heater. The measurements downstream of fuel injection show development of mixing and combustion, and are already proving useful to the modelers

Dual-Pump CARS Measurements in the University of Virginia's Dual-Mode Scramjet: Configuration "C"

Measurements have been conducted at the University of Virginia Supersonic Combustion Facility in configuration C of the dual-mode scramjet. This is a continuation of previously published works on configuration A. The scramjet is hydrogen fueled and operated at two equivalence ratios, one representative of the scram mode and the other of the ram mode. Dual-pump CARS was used to acquire the mole fractions of the major species as well as the rotational and vibrational temperatures of N2. Developments in methods and uncertainties in fitting CARS spectra for vibrational temperature are discussed. Mean quantities and the standard deviation of the turbulent fluctuations at multiple planes in the flow path are presented. In the scram case the combustion of fuel is completed before the end of the measurement domain, while for the ram case the measurement domain extends into the region where the flow is accelerating and combustion is almost completed. Higher vibrational than rotational temperature is observed in those parts of the hot combustion plume where there is substantial H2 (and hence chemical reaction) present

Measurement of Vibrational Non-Equilibrium in a Supersonic Freestream Using Dual-Pump CARS

Measurements have been conducted at the University of Virginia Supersonic Combustion Facility of the flow in a constant area duct downstream of a Mach 2 nozzle, where the airflow has first been heated to approximately 1200 K. Dual-pump CARS was used to acquire rotational and vibrational temperatures of N2 and O2 at two planes in the duct at different downstream distances from the nozzle exit. Wall static pressures in the nozzle are also reported. With a flow of clean air, the vibrational temperature of N2 freezes at close to the heater stagnation temperature, while the O2 vibrational temperature is about 1000 K. The results are well predicted by computational fluid mechanics models employing separate "lumped" vibrational and translational/rotational temperatures. Experimental results are also reported for a few percent steam addition to the air and the effect of the steam is to bring the flow to thermal equilibrium

OH PLIF Visualization of the UVa Supersonic Combustion Experiment: Configuration A

Hydroxyl radical (OH) planar laser-induced fluorescence (PLIF) measurements were performed in the University of Virginia s dual-mode scramjet experiment. The test section was set up in configuration A, which includes a Mach 2 nozzle, combustor, and extender section. Hydrogen fuel was injected through an unswept compression ramp at two different equivalence ratios. Through the translation of the optical system and the use of two separate camera views, the entire optical range of the combustor was accessed. Single-shot, average, and standard deviation images of the OH PLIF signal are presented at several streamwise locations. The results show the development of a highly turbulent flame structure and provide an experimental database to be used for numerical model assessment

OH PLIF Visualization of the UVa Supersonic Combustion Experiment: Configuration C

Non-intrusive hydroxyl radical (OH) planar laser-induced fluorescence (PLIF) measurements were obtained in configuration C of the University of Virginia supersonic combustion experiment. The combustion of hydrogen fuel injected through an unswept compression ramp into a supersonic cross-flow was imaged over a range of streamwise positions. Images were corrected for optical distortion, variations in the laser sheet profile, and different camera views. Results indicate an effect of fuel equivalence ratio on combustion zone shape and local turbulence length scale. The streamwise location of the reaction zone relative to the fuel injector was also found to be sensitive to the fuel equivalence ratio. The flow boundary conditions in the combustor section, which are sensitive to the fuel flow rate, are believed to have caused this effect. A combination of laser absorption and radiative trapping effects are proposed to have caused asymmetry observed in the images. The results complement previously published OH PLIF data obtained for configuration A along with other non-intrusive measurements to form a database for computational fluid dynamics (CFD) model validation