1 research outputs found
Donor−π–Acceptor-Type Configured, Dimethylamino-Based Organic Push–Pull Chromophores for Effective Reduction of Mild Steel Corrosion Loss in 1 M HCl
In this work, donor−π–acceptor-type
four crystalline
compounds have been tested for the first time to restrict the corrosion
of mild steel in 1 M HCl. The details of the compounds are: C1, 4-<i>N</i>,<i>N</i>-dimethylamino-β-nitrostyrene;
C2, 2-(4-(dimethylamino) benzylidene)Âmalononitrile; C3, ethyl 2-cyano-3-(4-(dimethylamino)
phenyl)Âacrylate; and C4, methyl 2-cyano-3-(4-(dimethylamino)Âphenyl)Âacrylate.
The corrosion inhibition potentials of the compounds have been primarily
investigated by electrochemical techniques, such as linear polarization
resistance, Tafel polarization curves, and electrochemical impedance
spectroscopy. The secondary investigation is performed by scanning
electron microscopy, fluorescence surface imaging, spectroscopic techniques
(UV–visible and Fourier transform infrared spectroscopy), and
X-ray diffraction patterns. The results disclosed that 50 mg L<sup>–1</sup> of the compounds (1–4) in 1 M HCl provided
the maximum inhibition efficiency as 93% (1), 88% (2), 82% (3), and
86% (4). The function of the compounds as corrosion inhibitors is
explained with equilibrium corrosion potential, adsorption isotherms,
and the frontier molecular orbital energies of the compounds (<i>E</i><sub>HOMO</sub> and <i>E</i><sub>LUMO</sub>)
estimated by cyclic voltammetry curves and UV–visible spectra