536 research outputs found
Atomic layer deposition of HfO2 on graphene from HfCl4 and H20
Atomic layer deposition of ultrathin HfO2 on unmodified graphene from HfCl4
and H2O was investigated. Surface RMS roughness down to 0.5 nm was obtained for
amorphous, 30 nm thick hafnia film grown at 180 degrees C. HfO2 was deposited
also in a two-step temperature process where the initial growth of about 1 nm
at 170 degrees C was continued up to 10-30 nm at 300 degrees C. This process
yielded uniform, monoclinic HfO2 films with RMS roughness of 1.7 nm for 10-12
nm thick films and 2.5 nm for 30 nm thick films. Raman spectroscopy studies
revealed that the deposition process caused compressive biaxial strain in
graphene whereas no extra defects were generated. An 11 nm thick HfO2 film
deposited onto bilayer graphene reduced the electron mobility by less than 10%
at the Dirac point and by 30-40% far away from it.Comment: 4 figures, accepted by CEJ
Tuning the properties of magnetic CdMnTe quantum dots
We show that CdMnTe self-assembled quantum dots can be formed by depositing a
submonolayer of Mn ions over a ZnTe surface prior to deposition of the CdTe dot
layer. Single dot emission lines and strongly polarized quantum dot
photoluminescence in an applied magnetic field confirm the presence of Mn in
individual quantum dots. The width of PL lines of the single CdMnTe dots is 3
meV due to magnetic moment fluctuations of the Mn ions. After rapid thermal
annealing, the emission lines of individual magnetic quantum dots narrow
significantly to 0.25 meV showing that effect of magnetic fluctuations is
strongly reduced most probably due to an increase in the average quantum dot
size. These results suggest a way to tune the spin properties of magnetic
quantum dots.Comment: 13 pages, 4 figure
Optical Studies of Zero-Field Magnetization of CdMnTe Quantum Dots: Influence of Average Size and Composition of Quantum Dots
We show that through the resonant optical excitation of spin-polarized
excitons into CdMnTe magnetic quantum dots, we can induce a macroscopic
magnetization of the Mn impurities. We observe very broad (4 meV linewidth)
emission lines of single dots, which are consistent with the formation of
strongly confined exciton magnetic polarons. Therefore we attribute the
optically induced magnetization of the magnetic dots results to the formation
of spin-polarized exciton magnetic polarons. We find that the photo-induced
magnetization of magnetic polarons is weaker for larger dots which emit at
lower energies within the QD distribution. We also show that the photo-induced
magnetization is stronger for quantum dots with lower Mn concentration, which
we ascribe to weaker Mn-Mn interaction between the nearest neighbors within the
dots. Due to particular stability of the exciton magnetic polarons in QDs,
where the localization of the electrons and holes is comparable to the magnetic
exchange interaction, this optically induced spin alignment persists to
temperatures as high as 160 K.Comment: 26 pages, 7 figs - submitted for publicatio
Polarization control of metal-enhanced fluorescence in hybrid assemblies of photosynthetic complexes and gold nanorods
Fluorescence imaging of hybrid nanostructures composed of a bacterial light-harvesting complex LH2 and Au nanorods with controlled coupling strength is employed to study the spectral dependence of the plasmon-induced fluorescence enhancement. Perfect matching of the plasmon resonances in the nanorods with the absorption bands of the LH2 complexes facilitates a direct comparison of the enhancement factors for longitudinal and transverse plasmon frequencies of the nanorods. We find that the fluorescence enhancement due to excitation of longitudinal resonance can be up to five-fold stronger than for the transverse one. We attribute this result, which is important for designing plasmonic functional systems, to a very different distribution of the enhancement of the electric field due to the excitation of the two characteristic plasmon modes in nanorods
Understanding and optimising the packing density of perylene bisimide layers on CVD-grown graphene
The non-covalent functionalisation of graphene is an attractive strategy to
alter the surface chemistry of graphene without damaging its superior
electrical and mechanical properties. Using the facile method of aqueous-phase
functionalisation on large-scale CVD-grown graphene, we investigated the
formation of different packing densities in self-assembled monolayers (SAMs) of
perylene bisimide derivatives and related this to the amount of substrate
contamination. We were able to directly observe wet-chemically deposited SAMs
in scanning tunnelling microscopy (STM) on transferred CVD graphene and
revealed that the densely packed perylene ad-layers adsorb with the conjugated
{\pi}-system of the core perpendicular to the graphene substrate. This
elucidation of the non-covalent functionalisation of graphene has major
implications on controlling its surface chemistry and opens new pathways for
adaptable functionalisation in ambient conditions and on the large scale.Comment: 27 pages (including SI), 10 figure
Probing the inter-layer exciton physics in a MoS/MoSe/MoS van der Waals heterostructure
Stacking atomic monolayers of semiconducting transition metal dichalcogenides
(TMDs) has emerged as an effective way to engineer their properties. In
principle, the staggered band alignment of TMD heterostructures should result
in the formation of inter-layer excitons with long lifetimes and robust valley
polarization. However, these features have been observed simultaneously only in
MoSe/WSe heterostructures. Here we report on the observation of long
lived inter-layer exciton emission in a MoS/MoSe/MoS trilayer van
der Waals heterostructure. The inter-layer nature of the observed transition is
confirmed by photoluminescence spectroscopy, as well as by analyzing the
temporal, excitation power and temperature dependence of the inter-layer
emission peak. The observed complex photoluminescence dynamics suggests the
presence of quasi-degenerate momentum-direct and momentum-indirect bandgaps. We
show that circularly polarized optical pumping results in long lived valley
polarization of inter-layer exciton. Intriguingly, the inter-layer exciton
photoluminescence has helicity opposite to the excitation. Our results show
that through a careful choice of the TMDs forming the van der Waals
heterostructure it is possible to control the circular polarization of the
inter-layer exciton emission.Comment: 19 pages, 3 figures. Just accepted for publication in Nano Letters
(http://pubs.acs.org/doi/10.1021/acs.nanolett.7b03184
Crystal growth furnace safety system validation
The findings are reported regarding the safe operation of the NASA crystal growth furnace (CGF) and potential methods for detecting containment failures of the furnace. The main conclusions are summarized by ampoule leak detection, cartridge leak detection, and detection of hazardous species in the experiment apparatus container (EAC)
Coherently tunable third-order nonlinearity in a nanojunction
A possibility of tuning the phase of the third-order Kerr-type nonlinear
susceptibility in a system consisting of two interacting metal nanospheres and
a nonlinearly polarizable molecule is investigated theoretically and
numerically. It is shown that by varying the relative inter-sphere separation,
it is possible to tune the phase of the effective nonlinear susceptibility
\chi^{(3)}(\omega;\omega,\omega,-\omega)2\pi$.Comment: 10 pages 5 figure
- …