140 research outputs found
Build n burn: using fire as a tool to evoke, educate and entertain
The visceral nature of fire was exploited in the Neolithic and Bronze Age periods in Britain by the burning down of timber buildings and monuments, as well as the cremation of the dead. These big fires would have created memories, perhaps even âflashbulb memoriesâ, and this powerful mnemonic aspect of fire was likely of significance to the social and religious lives of individuals, families and communities. This article introduces the Build N Burn concept, where fires are recreated and deployed alongside public talks, performances, experimental archaeology activities and demonstrations by craft specialists to create memorable and informative public events. Three public engagements to date, two on the island of Arran and one in Caithness, both Scotland, are described here. In each case, we constructed replica timber structures inspired by local prehistoric sites, and then burned these down in a free-to-attend public event at dusk, evoking the culmination of a prehistoric festival. Build N Burn has, at its core, the principle of delivering memorable experiences for the public inspired by prehistory, underpinned by research and experiment, using events which draw on cross-sectoral collaboration and working with local communities. This article offers a critical reflection on work to date, and discusses future potential for such activities, utilizing the mnemonic power and transformational potential of fire for public engagement and experimental archaeology
Mobility of antimony, arsenic and lead at a former mine, Glendinning, Scotland
Elevated concentrations of antimony (Sb), arsenic (As) and lead (Pb) in upland organic-rich soils have resulted from past Sb mining activities at Glendinning, southern Scotland. Transfer of these elements into soil porewaters was linked to the production and leaching of dissolved organic matter and to leaching of spoil material. Sb was predominantly present in truly dissolved (< 3 kDa) forms whilst As and Pb were more commonly associated with large Fe-rich/organic colloids. The distinctive porewater behaviour of Sb accounts for its loss from deeper sections of certain cores and its transport over greater distances down steeper sections of the catchment. Although Sb and As concentrations decreased with increasing distance down a steep gully from the main spoil heap, elevated concentrations (~ 6-8 and 13-20 ÎŒg Lâ 1, respectively) were detected in receiving streamwaters. Thus, only partial attenuation occurs in steeply sloping sections of mining-impacted upland organic-rich soils and so spoil-derived contamination of surface waters may continue over time periods of decades to centuries
Justice, development and the land: the social context of Scotlandâs energy transition
Scotland, like many other countries, is undergoing a transition to renewable
energy. This paper discusses the social context within which this transition
is taking place and which is conditioning the possibilities for energy
development and its effects on people. In particular, the paper explores
historically-rooted conflicts relating to land rights and wild land protection,
considering these issues and their relationship to energy development in
terms of landscape justice (i.e. the principle of fairness in the ways people
relate to the landscape and to each other through the landscape). Pursuing
a more just settlement between people and landscape is often a matter of
understanding problematic pasts and working to overcome their harmful
legacies. It is argued that there is an important role for heritage practice in
helping to deliver energy development which takes the historical, social and
cultural context more fully into account and thereby helps to bring about a
more just settlement between people and the landscape
Spatial and temporal variations in potentially toxic elemental (Sb, Pb, Cu and Zn) and PAH concentrations and associations in run-off from urban and rural areas of Scotland
Since the UK industrial revolution, coal combustion, ore smelting and other industrial
activities have resulted in a marked increase in emissions of potentially toxic elements
(PTEs) such as antimony (Sb), lead (Pb), arsenic (As), copper (Cu) and zinc (Zn), along with
polycyclic aromatic hydrocarbons (PAHs), to the atmosphere. Although stricter
environmental regulation and improved technology has led to a notable decline for some
contaminant emissions in recent decades, this has not been observed for all elements, e.g. Sb,
where only a modest reduction in emissions have been recorded. Once emitted, Sb along
with Pb, As, Cu, Zn and PAHs may persist in the environment for considerable periods of
time after their release; although their chemical associations may change, elements are not
broken down over time and organic contaminants may break down slowly. Above all, PTEs
and PAHs are detrimental to human and environmental health, with chemical forms of Sb,
Pb, As and PAHs categorised as carcinogenic. Understanding their behaviour and fate in the
environment is therefore an important step towards evaluating their likely impact on both
ecosystem and human health. Consequently, this study focuses on the release, behaviour and
fate of contaminants from current and past anthropogenic sources in the urban and rural
environment, with a specific interest in Sb and PAHs, where emissions originate from
similar anthropogenic sources, with Pb, As, Cu and Zn also included for comparison
purposes.
Current and past industrial activity was identified as the dominant source of PTEs and PAHs
to the urban environment, with emissions from vehicle, coal combustion and metal smelting
identified as main contributors to total contaminant concentrations. Using road dust collected
from Edinburgh at five high- and low-traffic roads at a distance of 10 and 50 m from the
closest road junction, concentrations of Sb, Pb, Cu, Zn, PAHs and Pb isotope ratios were
determined, with road dust undergoing further characterisation using chemical (sequential
extraction) and spectroscopic (X-ray diffraction, SEM-EDX) techniques. No consistent trend
for the element concentrations released from vehicles braking at 10 and 50 m from the
closest road junction was observed. Mean concentrations for Sb, Cu and Zn were 5.3 ± 2.8
mg kg-1, 91.4 ± 48 mg kg-1 and 237 ± 144 mg kg-1, respectively, and were similar to road
dust sampled from five high- and five low-traffic locations in Glasgow (Sb 4.5 ± 2.1 mg kg-1;
Cu 117 ± 71.9 mg kg-1; Zn: 283 ± 146 mg kg-1). This was in contrast to mean concentrations
for Pb and Σ16PAHs obtained from Glasgow (Pb 250 ± 283 mg kg-1, Σ16PAH 7.7 ± 4.3
mg kg-1) where values were approximately double and two-thirds greater than those found in
Edinburgh (Pb 135 ± 129 mg kg-1, Σ16PAH 4.7 ± 2.9 mg kg-1), respectively. Lead isotopic
analysis of Glasgow road dust (206Pb/207Pb range of 1.140-1.174) showed a strong influence
of past emissions from coal combustion and metal smelting, and was in agreement with
Glasgow's industrial history. For Edinburgh, the isotopic signature was considerably lower
(206Pb/207Pb range of 1.116-1.151), and was influenced moreso by emissions of Australian
sourced Pb in leaded fuel. Isotopic signatures in Edinburgh were lowest at easterly locations
within 5 km of Edinburgh airport (206Pb/207Pb ~ 1.12), and corresponded with past vehicle
emissions from leaded petrol use, and to a lesser degree, emissions from avgas, which was
consistent with the mean annual wind direction for Edinburgh. The mobility of elements
from the road dust to the aqueous phase were assessed by sequential extraction, and by using
road surface water samples which showed mobility decreased in the order of Zn>Cu>Pb>Sb.
Road dust characterised by XRD and SEM-EDX had a high proportion of quartz present
(~55%), whilst the presence of less abundant minerals such as calcite were found to increase
Pb mobility through ease of dissolution into the aqueous phase.
For the rural environment, the behaviour and fate of elemental pollution originating from
two former mining sites, an Sb mine at Glendinning, SW Scotland, and a Pb mine at
Tyndrum in central Scotland was examined. Under specific environmental conditions, Sb
was found to be both mobile and immobile in the environment. The chemical weathering of
stibnite found in spoil heaps at Glendinning Sb mine demonstrated that ~3% of total Sb can
be mobilised during the chemical weathering process, while hydrous Fe oxides and organic
matter in the surrounding soil favoured its retention. The retention of Sb, along with Pb, was
similarly observed in Loch Tay sediment downstream of Tyndrum Pb mine, where upon
deposition, Sb and Pb remained immobile in sediment and allowed the construction of
deposition chronologies for two sediment cores to be established. Excellent agreement
between the sediment core deposition chronologies was observed, with both chronologies
identifying atmospheric deposition as the primary source of Sb to Loch Tay sediment, whilst
the dominant source of Pb was from Tyndrum Pb mine ~25 km upstream of Loch Tay.
Relative to Sb and Pb, As had the greatest mobility, with its geochemical behaviour and
partial retention by the solid phase influenced by the presence of Fe. This was evident in the
surrounding soil at Glendinning Sb mine, where As was associated with hydrous Fe oxides
present in the solid phase, while at Loch Tay, the redox cycling of Fe resulted in the post-depositional
mobility of As in sediment.
The use of ombrotrophic peat bogs for this study provided an effective means to assess
atmospheric deposition of contaminants over past centuries; they continually accumulate and
receive all their nutrients and contaminants exclusively by deposition from the atmosphere.
The deposition archives of Sb and Pb from two Scottish peat cores sampled from Great
Moss, Cairngorms Mountains, and, Auchencorth Moss, Midlothian, were used to construct
chronologies for historic and contemporary emissions, particularly in relation to current and
historic anthropogenic activities observed in urban and rural environments. At Great Moss,
the deposition of Sb and Pb during the 19th century increased by a factor of 10 and 4,
respectively, as a result of the industrial revolution and emissions from the combustion of
coal and metal smelting. The trend continued into the 20th century where Sb and Pb
deposition peaked ~1950, followed by a decline towards the early 21st century by a factor of
5 and 11, respectively. Over this period of time, the contribution from coal combustion and
metal smelting towards total anthropogenic emissions was on the decline, while emissions
from the combustion of leaded fuel increased until the ~1980s. Although deposition
chronologies before 1970 for Sb and Pb at Auchencorth Moss were generally in agreement
with those from Great Moss, several differences were observed after 1970, or more
specifically, in the top ~10 cm of the peat core. This was a result of sub-surface perturbations
for Ti, Sb, Pb and 210Pb concentrations, and indicated once deposited, elements were
susceptible to post-depositional mobility brought about from a change in environmental
conditions. The thicker acrotelm layer present at Auchencorth Moss, and the vertical
movement of the peat water-table within this layer, resulted in a change in redox conditions
and led to the redox cycling of Mn and Fe, which in turn, influenced vertical concentrations
of Ti, Sb, Pb and 210Pb. While Sb and Pb are usually found immobile in peat systems, the
post-deposition mobility of Sb and Pb at Auchencorth Moss was comparable to a peat core
sampled from Flanders Moss, and indicated that under specific environmental conditions,
both elements can become mobile in ombrotrophic peat bogs. It is worth bearing in mind
however, that these results are the exception, and in all other cases ombrotrophic peat bogs
remain a reliable archival material to use
Relation of Trauma, Disease, and Law - Panel Discussion
A symposium on Relation of Trama, Disease, and Law. The symposium took place under the auspices of the Amerian Board of Legal Medicine Inc., in conjucntion with the sesquicentennial meeting of the Medical Society of the State of New York
Relation of Trauma, Disease, and Law - Panel Discussion
A symposium on Relation of Trama, Disease, and Law. The symposium took place under the auspices of the Amerian Board of Legal Medicine Inc., in conjucntion with the sesquicentennial meeting of the Medical Society of the State of New York
Impulse-breakdown characteristics of polymers immersed in insulating oil
Surface discharges along oil-immersed solids used as insulators and supports in high-voltage pulsed-power equipment can lead to catastrophic system failures. To achieve reliable compact pulsed-power systems, it is important to quantify the electrical fields at which surface flashover, or other types of breakdown event, will occur for different dielectric materials. This paper reports the observed behavior of samples of polypropylene, low-density polyethylene, ultrahigh-molecular-weight polyethylene, Rexolite, and Torlon, which were subjected to impulse voltages of peak amplitude of 350 kV and a rise time of 1 . The cylindrical samples were located between pairs of electrodes immersed in insulating oil. Breakdown events were studied under both nonuniform- and uniform-field conditions, with sample lengths being chosen so that the breakdown events occurred on the rising edge of the impulse. Ultrahigh-molecular-weight polyethylene showed the highest average breakdown field, which is 645 kV/cm, in uniform fields, and the corresponding breakdown field was reduced to 400 kV/cm in the nonuniform fields. Weibull plots of the various sets of results are presented, providing comparative data for system designers for the appropriate choice of dielectric materials to act as insulators for high-voltage pulsed-power machines
A Randomized Controlled Trial of the Effect of Allopurinol on Left Ventricular Mass Index in Hemodialysis Patients
Introduction:
Increased left ventricular mass index (LVMI) is associated with mortality in end-stage renal disease. LVMI regression may improve outcomes. Allopurinol has reduced LVMI in randomized controlled trials in chronic kidney disease, diabetes, and ischemic heart disease. This study investigated whether allopurinol would regress LVMI in hemodialysis patients.
Methods:
This was a randomized placebo-controlled double-blind multicenter trial. A total of 80 patients undergoing regular maintenance hemodialysis were recruited from NHS Tayside, NHS Greater Glasgow and Clyde and NHS Ayrshire and Arran in Scotland, UK. Participants were randomly assigned on a 1:1 ratio to 12 months of therapy with allopurinol 300 mg or placebo after each dialysis session. The primary outcome was change in LVMI, as assessed by cardiac magnetic resonance imaging (MRI) at baseline and 12 months. Secondary outcomes were change in BP, flow-mediated dilation (FMD), augmentation indices (AIx), and pulse wave velocity (PWV).
Results:
A total of 53 patients, with a mean age of 58 years, completed the study and had MRI follow-up data for analysis. Allopurinol did not regress LVMI (change in LVMI: placebo +3.6 ± 10.4 g/m2; allopurinol: +1.6 ± 11 g/m2; P = 0.49). Allopurinol had no demonstrable effect on BP, FMD, AIx, or PWV.
Conclusion:
Compared with placebo, treatment with allopurinol did not regress LVMI in this trial
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