Charge and momentum transfer in supercooled melts: Why should their relaxation times differ?

The steady state values of the viscosity and the intrinsic ionic-conductivity of quenched melts are computed, in terms of independently measurable quantities. The frequency dependence of the ac dielectric response is estimated. The discrepancy between the corresponding characteristic relaxation times is only apparent; it does not imply distinct mechanisms, but stems from the intrinsic barrier distribution for $\alpha$-relaxation in supercooled fluids and glasses. This type of intrinsic ``decoupling'' is argued not to exceed four orders in magnitude, for known glassformers. We explain the origin of the discrepancy between the stretching exponent $\beta$, as extracted from $\epsilon(\omega)$ and the dielectric modulus data. The actual width of the barrier distribution always grows with lowering the temperature. The contrary is an artifact of the large contribution of the dc-conductivity component to the modulus data. The methodology allows one to single out other contributions to the conductivity, as in ``superionic'' liquids or when charge carriers are delocalized, implying that in those systems, charge transfer does not require structural reconfiguration.Comment: submitted to J Chem Phy

Electric and magnetic fields effects on the excitonic properties of elliptic core-multishell quantum wires

The effect of eccentricity distortions of core-multishell quantum wires on their electron, hole and exciton states is theoretically investigated. Within the effective mass approximation, the Schrodinger equation is numerically solved for electrons and holes in systems with single and double radial heterostructures, and the exciton binding energy is calculated by means of a variational approach. We show that the energy spectrum of a core-multishell heterostructure with eccentricity distortions, as well as its magnetic field dependence, are very sensitive to the direction of an externally applied electric field, an effect that can be used to identify the eccentricity of the system. For a double heterostructure, the eccentricities of the inner and outer shells play an important role on the excitonic binding energy, specially in the presence of external magnetic fields, and lead to drastic modifications in the oscillator strength.Comment: 17 pages, 10 figure

Isotretinoin and inflammatory bowel disease

[Excerpt] We read with great interest the recent review published in your Journal by Reddy et al., which suggests a possible association between isotretinoin use and inflammatory bowel disease (IBD) (1). Although IBD is described as a possible adverse drug reaction in the product information, little attention has been given in the literature to this association.[...

Micropedologia de um Argissolo amarelo com horizontes antrópicos (Terra Preta de Índio) na Amazônia Central.

Estudos micropedológicos foram carreados em Terra Preta de Índio (TPI) com o objetivo de elucidar os processos envolvidos em sua gênese, bem como suas formas de utilização pré-colombiana. Blocos indeformados de solo foram coletados por horizonte e em suas respectivas transições em um perfil de Argissolo Amarelo A Antrópico (TPI) localizado no município de Iranduba, AM. As lâminas delgadas confeccionadas a partir dos blocos foram descritas por meio de microscopia óptica. Os resultados mostraram que os processos envolvidos na gênese desse solo envolveram: i) condições pedoambientais diferentes das atuais (pedorrelíquias - nódulos ferruginosos); ii) argiluviação, indicada por revestimentos de ferri-argilãs orientados na parede de poros entre agregados e canais; iii) migração de ferro impregnando o fundo matricial (cutãs de difusão); iv) bioturbação, atestada por preenchimento de poros por pelotas fecais e microagregação zoogenética e v) antropismo, que contribuiu com a queima de resíduos (partículas de carvões) e descarte de artefatos cerâmicos. A análise dos fragmentos cerâmicos corroborou a utilização de cauixi (Tubella reticulata e Parnula betesil) e cariapé (Bignoniacea) como antiplástico para o seu fabrico

Caracterização de dois perfis com horizonte antrópico (Terra Preta de Índio) no Lago do Limão - AM.

O trabalho teve por objetivo caracterizar dois perfis com horizonte antrópico no Lago do Limão, município de Iranduba