Ortega Y Gasset's Idea of the University

The problems of education that concerned Ortega in 1930 are essentially those which contemporary thinkers are trying to resolve. Ortega proposed separation of teaching and research, curtailment of the curriculum, demands for a high level of mastery, and a compulsory core of essential subjects. Because of the role of culture in life, the university must be remodelled if science and rationality are to endure. This solution faces great obstacles, but there may be no alternative

Structure and reactivity of a mononuclear gold(II) complex

Mononuclear gold(II) complexes are very rare labile species. Transient gold(II) species have been suggested in homogeneous catalysis and in medical applications, but their geometric and electronic structures have remained essentially unexplored: even fundamental data, such as the ionic radius of gold(II), are unknown. Now, an unprecedentedly stable neutral gold(II) complex of a porphyrin derivative has been isolated, and its structural and spectroscopic features determined. The gold atom adopts a 2+2 coordination mode in between those of gold(III) (four-coordinate square planar) and gold(I) (two-coordinate linear), owing to a second-order Jahn–Teller distortion enabled by the relativistically lowered 6s orbital of gold. The reactivity of this gold(II) complex towards dioxygen, nitrosobenzene and acids is discussed. This study provides insight on the ionic radius of gold(II), and allows it to be placed within the homologous series of nd9 Cu/Ag/Au divalent ions and the 5d8/9/10 Pt/Au/Hg ‘relativistic’ triad in the periodic table