End-On Orientation of Semiconducting Polymers in Thin Films Induced by Surface Segregation of Fluoroalkyl Chains

Controlling the orientation of highly anisotropic structures of polymers is important because the majority of their mechanical, electronic, and optical properties depend on the orientation of the polymer backbone. In thin films, the polymer chains tend to adopt an orientation parallel to the substrate; therefore, forcing the chains to stand perpendicular to the substrate is challenging. We have developed a simple way to achieve this end-on orientation. We functionalized one end of a poly­(3-butylthiophene) (P3BT) chain with a 1<i>H</i>,1<i>H</i>,2<i>H</i>,2<i>H</i>,3<i>H</i>,3<i>H</i>-perfluoroundecyl group, which caused spontaneous self-segregation of the polymer (P3BT-F₁₇) to the surface of the polymer film. In P3BT-F₁₇/polystyrene (PS) blend films, a highly ordered end-on orientation of the conjugated backbone was observed in the surface-segregated layer of the crystalline P3BT-F₁₇. Furthermore, when the film was spin-coated from a mixture of P3BT-F₁₇ and P3BT, the chain orientation of P3BT-F₁₇ at the surface forced the P3BT in the bulk of the film to adopt the end-on orientation because of the high crystallinity of P3BT. The electronic conductivity measured perpendicular to the film surface also reflected the end-on orientation in the bulk, resulting in a more than 30-fold enhancement of the hole mobility

Joining mechanism of connection between Ag-plated Kovar interconnector and stranded Ag-plated Cu wire produced via parallel gap resistance welding

A space solar array includes GaAs solar cell, interconnector, and stranded Cu wire. Due to the preferential high working efficiency, the assembly of solar array is mostly performed using parallel gap resistance welding (PGRW). Since strengthening of the PGRW joints is the key to further extend service life of solar array, it is necessary to elucidate joining mechanism of each connection. In the present research, to clarify the controversy over PGRW joining mechanism between Ag-plated Kovar interconnector and stranded Ag-plated Cu wire, various advanced material characterization methods are conducted to joining interfaces. Experimental results confirm that, in addition to the known Ag/Cu eutectic interface, solid evidence of metallurgy bonding is also found in Cu/Cu interface. Such finding has significant implication for further enlarge the PGRW process window and produce stronger joints

A comprehensive study of parallel gap resistance welding joint between Ag foil and front electrode of GaAs solar cell

When space solar cell array is subjected to harsh temperature cycle, such as planet orbit, thermal fatigue cracks in bonding area are easily induced. With the aim of improving bonding quality and elucidating failure mechanism of parallel gap resistance welding (PGRW) joints in temperature cycling environment, the present research investigates the effect of current density on bonding quality and thermal fatigue behavior of PGRW joint between Ag interconnector and front electrode of GaAs solar cell. When current density is set at 417 A/mm2, a solid diffusion bonding is achieved at the Ag/Au interface, which also possesses adequate joint strength as ensured by both pressure and input energy of PGRW. Crack initiation by thermal fatigue is found at joint edge, which subsequently propagates along the interface as the environment temperature cycling continues. Further investigation reveals that the conducted temperature cycling generates serious tensile and compressive stress in the multi-layered joint structure. Since such reciprocating forces directly induce micro-plastic deformation and strain accumulation at joint interface, failure by crack is finally generated at the joining interface

Effects of Electron Irradiation and Temperature on Mechanical Properties of Polyimide Film

Polyimide (PI) is widely deployed in space missions due to its good radiation resistance and durability. The influences from radiation and harsh temperatures should be carefully evaluated during the long-term service life. In the current work, the coupled thermal and radiation effects on the mechanical properties of PI samples were quantitatively investigated via experiments. At first, various PI specimens were prepared, and electron irradiation tests were conducted with different fluences. Then, both uniaxial tensile tests at room temperature and the dynamic mechanical analysis at varied temperatures of PI specimens with and without electron irradiation were performed. After that, uniaxial tensile tests at low and high temperatures were performed. The fracture surface of the PI film was observed using a scanning electron microscope, and its surface topography was measured using atomic force microscopy. In the meantime, the Fourier-transform infrared spectrum tests were conducted to check for chemical changes. In conclusion, the tensile tests showed that electron irradiation has a negligible effect during the linear stretching period but significantly impacts the hardening stage and elongation at break. Moreover, electron irradiation slightly influences the thermal properties of PI according to the differential scanning calorimetry results. However, both high and low temperatures dramatically affect the elastic modulus and elongation at break of PI

Microstructure evolution and formation mechanism of interfaces in parallel gap resistance welding of stranded Ag-plated Cu conductor to Ag interconnector

In space flexible solar arrays, stranded Ag-plated Cu conductors and Ag interconnectors are preferred materials for energy transmission. Parallel gap resistance welding is a solderless micro-joining process that favors the reliability of joints between stranded Ag-plated Cu conductors and Ag interconnectors. It was found the interfacial microstructure presented diversity and complexity while mechanical and electrical properties showed unusual nonlinear variations with welding voltage. This study aims to clarify the interfacial microstructure evolution and its effects on the joint properties while elucidating the microstructure formation mechanisms. A shift in the bonding mechanism at interfaces from solid-state diffusion to brazing was found as welding voltage reached a critical value (1.5 V). It eliminated micro gaps and built nano-scale interlocking structures, resulting in substantial improvement in mechanical properties. Increasing the welding voltage from 1.2 V to 1.4 V improved electrical conductivity due to the enlarged bonding area at interfaces. However, high welding voltage (1.6 V) led to degradation in the electrical conductivity of joints due to excessive Ag-Cu solid solution formed at interfaces. The key to fabricating high-strength and high-conductivity joints lies in achieving appropriate interfacial melting while reducing alloying by controlling peak temperature and shortening the duration above the Ag-Cu eutectic point

Applications and Potentials of Intelligent Swarms for magnetospheric studies

Earth's magnetosphere is vital for today's technologically dependent society. To date, numerous design studies have been conducted and over a dozen science missions have flown to study the magnetosphere. However, a majority of these solutions relied on large monolithic satellites, which limited the spatial resolution of these investigations, as did the technological limitations of the past. To counter these limitations, we propose the use of a satellite swarm carrying numerous and distributed payloads for magnetospheric measurements. Our mission is named APIS — Applications and Potentials of Intelligent Swarms. The APIS mission aims to characterize fundamental plasma processes in the Earth's magnetosphere and measure the effect of the solar wind on our magnetosphere. We propose a swarm of 40 CubeSats in two highly-elliptical orbits around the Earth, which perform radio tomography in the magnetotail at 8–12 Earth Radii (RE) downstream, and the subsolar magnetosphere at 8–12 RE upstream. These maps will be made at both low-resolutions (at 0.5 RE, 5 s cadence) and high-resolutions (at 0.025 RE, 2 s cadence). In addition, in-situ measurements of the magnetic and electric fields, plasma density will be performed by on-board instruments. In this article, we present an outline of previous missions and designs for magnetospheric studies, along with the science drivers and motivation for the APIS mission. Furthermore, preliminary design results are included to show the feasibility of such a mission. The science requirements drive the APIS mission design, the mission operation and the system requirements. In addition to the various science payloads, critical subsystems of the satellites are investigated e.g., navigation, communication, processing and power systems. Our preliminary investigation on the mass, power and link budgets indicate that the mission could be realized using Commercial Off-the-Shelf (COTS) technologies and with homogeneous CubeSats, each with a 12U form factor. We summarize our findings, along with the potential next steps to strengthen our design study.</p

APIS : Applications and potentials of intelligent swarms for magnetospheric studies

Earth's magnetosphere is vital for today's technologically dependent society. The energy transferred from the solar wind to the magnetosphere triggers electromagnetic storms on Earth, knocking out power grids and infrastructure - e.g., communication and navigation systems. Despite occurring on our astrophysical doorstep, numerous physical processes connecting the solar wind and our magnetosphere remain poorly understood. To date, over a dozen science missions have flown to study the magnetosphere, and many more design studies have been conducted. However, the majority of these solutions relied on large monolithic satellites, which limited the spatial resolution of these investigations, in addition to the technological limitations of the past. To counter these limitations, we propose the use of a satellite swarm, carrying numerous payloads for magnetospheric measurements. Our mission is named APIS - Applications and Potentials of Intelligent Swarms. The APIS mission aims to characterize fundamental plasma processes in the magnetosphere and measure the effect of the solar wind on our magnetosphere. We propose a swarm of 40 CubeSats in two highly-elliptical orbits around the Earth, which perform radio tomography in the magnetotail at 8-12 Earth Radii (RE) downstream, and the subsolar magnetosphere at 8-12 RE upstream. These maps will be made at both low-resolutions (at 0.5 RE, 5 seconds cadence) and high-resolutions (at 0.025 RE, 2 seconds cadence). In addition, in-situ measurements of the magnetic and electric fields, and plasma density will be performed by on-board instruments. In this publication, we present a design study of the APIS mission, which includes the mission design, navigation, communication, processing, power systems, propulsion and other critical satellite subsystems. The science requirements of the APIS mission levy stringent system requirements, which are addressed using Commercial Off-the-Shelf (COTS) technologies. We show the feasibility of the APIS mission using COTS technologies using preliminary link, power, and mass budgets. In addition to the technological study, we also investigated the legal considerations of the APIS mission. The APIS mission design study was part of the International Space University Space Studies Program in 2019 (ISU-SSP19) Next Generation Space Systems: Swarms Team Project. The authors of this publication are the participants of this 9-week project, in addition to the Chairs and Support staff.</p