A study of nano-particle based silane consolidants for Globigerina limestone

This STEPS funded study focuses on the application of hybrid and nanoparticle loaded hybrid silane consolidants for the treatment of 'Franka' type Globigerina Limestone. Consolidants act by gluing the deteriorated stone material to the underlying healthy stone (Dukes, 1972; Gutt, 1973; Alessandrini et al., 1975; Garrod, 2001). The consolidants evaluated in this work were a laboratory prepared hybrid silane based on a mixture of tetraethylorthosilicate (TEOS) and 3-(glycidoxypropyl) trimethoxysilane (GPTMS), the same hybrid consolidant loaded with silica nanoparticles and GPTMS-modified silica nanoparticles. In addition, a consolidant based on the hydrolysis product of TEOS was also tested. Prepared consolidants were applied to Globigerina Limestone test blocks by complete immersion. Untreated stone block were used as benchmarks. Following application of the consolidants, half of the treated limestone blocks were subjected to accelerated weathering. Non-weathered and weathered limestone blocks were then characterised by optical and electron microscopy and the stone colour before and after treatment with consolidants was assessed by a colorimetric technique. The pore size distribution before and after application of the different consolidant treatments was assessed by Mercury Intrusion Porosimetry. A water absorption by capillarity technique was also carried out to assess how the water uptake rate into the limestone alters with the different treatments. The mechanical properties of the consolidated limestone blocks were assessed by resistance to sodium sulfate crystallisation. Microscopy observations showed that the consolidants penetrated the stone to different extents depending on the consolidant and the method of application. The hybrid consolidant on its own led to yellowing of the limestone but the addition of nanoparticles to the hybrid (modified or not) appeared to help restore the original colour of the stone. The porosity of the limestone was only marginally affected by the different treatments but the somewhat hydrophobic nature of the consolidants led to a disruption in the capillary flow of water into the limestone.peer-reviewe

Nonlinear electrodynamics and the gravitational redshift of highly magnetised neutron stars

The idea that the nonlinear electromagnetic interaction, i. e., light propagation in vacuum, can be geometrized was developed by Novello et al. (2000) and Novello & Salim (2001). Since then a number of physical consequences for the dynamics of a variety of systems have been explored. In a recent paper Mosquera Cuesta & Salim (2003) presented the first astrophysical study where such nonlinear electrodynamics (NLEDs) effects were accounted for in the case of a highly magnetized neutron star or pulsar. In that paper the NLEDs was invoked {\it a l\`a} Euler-Heisenberg, which is an infinite series expansion of which only the first term was used for the analisys. The immediate consequence of that study was an overall modification of the space-time geometry around the pulsar, which is ``perceived'', in principle, only by light propagating out of the star. This translates into an significant change in the surface redshift, as inferred from absorption (emission) lines observed from a super magnetized pulsar. The result proves to be even more dramatic for the so-called magnetars, pulsars endowed with magnetic ($B$) fields higher then the Schafroth quantum electrodynamics critical $B$-field. Here we demonstrate that the same effect still appears if one calls for the NLEDs in the form of the one rigorously derived by Born & Infeld (1934) based on the special relativistic limit for the velocity of approaching of an elementary particle to a pointlike electron [From the mathematical point of view, the Born & Infeld (1934) NLEDs is described by an exact Lagrangean, whose dynamics has been successfully studied in a wide set of physical systems.].Comment: Accepted for publication in Month. Not. Roy. Ast. Soc. latex file, mn-1.4.sty, 5 pages, 2 figure

A new approach to measure reduction intensity on cores and tools on cobbles: the Volumetric Reconstruction Method

Knowing to what extent lithic cores have been reduced through knapping is an important step toward understanding the technological variability of lithic assemblages and disentangling the formation processes of archaeological assemblages. In addition, it is a good complement to more developed studies of reduction intensity in retouched tools, and can provide information on raw material management or site occupation dynamics. This paper presents a new methodology for estimating the intensity of reduction in cores and tools on cobbles, the Volumetric Reconstruction Method (VRM). This method is based on a correction of the dimensions (length, width, and thickness) of each core from an assemblage. The mean values of thickness and platform thickness of the assemblage’s flakes are used as corrections for the cores’ original dimensions, after its diacritic analysis. Then, based on these new dimensions, the volume or mass of the original blank are reconstructed using the ellipsoid volume formula. The accuracy of this method was experimentally tested, reproducing a variety of possible archaeological scenarios. The experimental results demonstrate a high inferential potential of the VRM, both in estimating the original volume or mass of the original blanks, and in inferring the individual percentage of reduction for each core. The results of random resampling demonstrate the applicability of VRM to non size-biased archaeological contexts.Introduction Methods - The Volumetric Reconstruction Method - Experimental design - Statistical procedures - Resamples Results - Geometric formulas - Reduction strategy and size - Resampling (randomly biased record) - Resampling (size bias) - Measuring the effect of number of generations Discussion and conclusion