Polyelectrolyte-colloid complexes: polarizability and effective interaction

We theoretically study the polarizability and the interactions of neutral complexes consisting of a semi-flexible polyelectrolyte adsorbed onto an oppositely charged spherical colloid. In the systems we studied, the bending energy of the chain is small compared to the Coulomb energy and the chains are always adsorbed on the colloid. We observe that the polarizability is large for short chains and small electrical fields and shows a non-monotonic behavior with the chain length at fixed charge density. The polarizability has a maximum for a chain length equal to half of the circumference of the colloid. For long chains we recover the polarizability of a classical conducting sphere. For short chains, the existence of a permanent dipole moment of the complexes leads to a van der Waal's-type long-range attraction between them. This attractive interaction vanishes for long chains (i.e., larger than the colloidal size), where the permanent dipole moment is negligible. For short distances the complexes interact with a deep short-ranged attraction which is due to energetic bridging for short chains and entropic bridging for long chains. Exceeding a critical chain length eventually leads to a pure repulsion. This shows that the stabilization of colloidal suspensions by polyelectrolyte adsorption is strongly dependent on the chain size relative to the colloidal size: for long chains the suspensions are always stable (only repulsive forces between the particles), while for mid-sized and short chains there is attraction between the complexes and a salting-out can occur.Comment: 13 pages, 14 figure

Effects of rotation on the evolution and asteroseismic properties of red giants

The influence of rotation on the properties of red giants is studied in the context of the asteroseismic modelling of these stars. While red giants exhibit low surface rotational velocities, we find that the rotational history of the star has a large impact on its properties during the red giant phase. In particular, for stars massive enough to ignite He burning in non-degenerate conditions, rotational mixing induces a significant increase of the stellar luminosity and shifts the location of the core helium burning phase to a higher luminosity in the HR diagram. This of course results in a change of the seismic properties of red giants at the same evolutionary state. As a consequence the inclusion of rotation significantly changes the fundamental parameters of a red giant star as determined by performing an asteroseismic calibration. In particular rotation decreases the derived stellar mass and increases the age. Depending on the rotation law assumed in the convective envelope and on the initial velocity of the star, non-negligible values of rotational splitting can be reached, which may complicate the observation and identification of non-radial oscillation modes for red giants exhibiting moderate surface rotational velocities. By comparing the effects of rotation and overshooting, we find that the main-sequence widening and the increase of the H-burning lifetime induced by rotation (Vini=150 km/s) are well reproduced by non-rotating models with an overshooting parameter of 0.1, while the increase of luminosity during the post-main sequence evolution is better reproduced by non-rotating models with overshooting parameters twice as large. This is due to the fact that rotation not only increases the size of the convective core but also changes the chemical composition of the radiative zone.Comment: 9 pages, 13 figures, accepted for publication in A&

Early Aspects at ICSE 2007: Workshop on Aspect-Oriented Requirements Engineering and Architecture Design

The “Early Aspects @ ICSE’07” is the 11th workshop in the series of Early Aspects workshops [1] which focuses on aspect identification during the requirements engineering and architecture derivation activities. The specific aim of the present workshop is twofold: (a) to initiate creation of an Early Aspects application demonstration and comparisons benchmark; and (b) to solicit submission of new research

Extratores e disponibilidade de micronutrientes em solos antrópicos da Amazônia.

Editado por: Patrícia M. Santos, Edison B. pott, Alberto C. de Campos Bernardi, Ana Rita de A. Nogueira, Luciana C. de A. Regitano e Márcia Cristina de S. Oliveira