1,139 research outputs found
Electrochemical Behavior and Determination of Fluconazole
The electrochemical behavior of fluconazole showed an irreversible oxidation process, with the electrochemical - chemical mechanism being highly dependent on the electrode material. Adsorption of reagent at positive applied potential was observed at Pt electrode while preferential adsorption of the oxidation products was observed at Glassy Carbon surfaces. In pH below 7.0, the anodic current process was intensively decreased. At carbon paste electrode, the fluconazole oxidation current, recorded in phosphate buffer solution (pH 8.0), changed linearly with the fluconazole concentration, Ipa = 5.7×10-5 (mA) × 0.052 [Fluconazol] (μg mL-1), in the range of 48.0 to 250.0 μg mL-1. The detection limit obtained was 6.3 μg mL-1.O comportamento eletroquímico do fluconazol demonstrou oxidação irreversível com mecanismos eletroquímicos-químicos dependentes do material eletródico. Em eletrodos de Pt observou-se adsorção do reagente sob a aplicação de potenciais positivos, enquanto adsorção preferencial dos produtos foi observada em eletrodo de carbono vítreo. Em valores de pH inferiores a 7,0, a corrente do processo anódico é intensamente diminuída. Em eletrodo de pasta de carbono e tampão fosfato, pH 8,0, a corrente de oxidação variou linearmente com a concentração de fluconazol em solução, Ipa = 5,7×10-5 (mA) × 0,052 [Fluconazol] (μg mL-1), no intervalo de 48,0 a 250,0 μg mL-1. O limite de detecção obtido foi 6,3 μg mL-1.FAPES
Potencial ecológico para o manejo da Virolasurinamensis (Rol. Ex. Rottb.) Warb. em um ambiente de várzea na resex do Rio Cajari, Amapá, Brasil.
The transition in softly broken supersymmetry
We study the effect of supersymmetric contributions to the effective quark
transition , including leading order QCD effects. We apply
the discussion to the decay . Even though one-particle
irreducible contributions could play a role, numerical cancelations make the
amplitude for the two-photon emission strongly correlated to the
amplitude which is sharply constrained by experiment. A quite general statement
follows: as long as non-standard physics effects appear only in the matching of
the Wilson coefficients of the standard effective operator basis, the
deviations from the standard model expectations of the decay rates induced by
are bound to follow closely the corresponding deviations
on . Effects of new physics are therefore bound to be small.Comment: Latex2e, RevTex, 22 pages, 8 eps figures, comments and references
adde
Ferulic acid: a key component in grass lignocellulose recalcitrance to hydrolysis
In the near future, grasses must provide most of the biomass for the production of renewable fuels. However, grass cell walls are characterized by a large quantity of hydroxycinnamic acids such as ferulic and p-coumaric acids, which are thought to reduce the biomass saccharification. Ferulic acid (FA) binds to lignin, polysaccharides and structural proteins of grass cell walls cross-linking these components. A controlled reduction of FA level or of FA cross-linkages in plants of industrial interest can improve the production of cellulosic ethanol. Here, we review the biosynthesis and roles of FA in cell wall architecture and in grass biomass recalcitrance to enzyme hydrolysis
Rainfall, not soil temperature, will limit the seed germination of dry forest species with climate change.
Drylands are predicted to become more arid and saline due to increasing global temperature and drought. Although species from the Caatinga, a Brazilian tropical dry forest, are tolerant to these conditions, the capacity for germination to withstand extreme soil temperature and water deficit associated with climate change remains to be quantified. We aimed to evaluate how germination will be affected under future climate change scenarios of limited water and increased temperature. Seeds of three species were germinated at different temperatures and osmotic potentials. Thermal time and hydrotime model parameters were established and thresholds for germination calculated. Germination performance in 2055 was predicted, by combining temperature and osmotic/salt stress thresholds, considering soil temperature and moisture following rainfall events. The most pessimistic climate scenario predicts an increase of 3.9 °C in soil temperature and 30% decrease in rainfall. Under this scenario, soil temperature is never lower than the minimum and seldomly higher than maximum temperature thresholds for germination. As long as the soil moisture (0.139 cm3 cm3) requirements are met, germination can be achieved in 1 day. According to the base water potential and soil characteristics, the minimum weekly rainfall for germination is estimated to be 17.5 mm. Currently, the required minimum rainfall occurs in 14 weeks of the year but will be reduced to 4 weeks by 2055. This may not be sufficient for seedling recruitment of some species in the natural environment. Thus, in future climate scenarios, rainfall rather than temperature will be extremely limiting for seed germination
SuperB Progress Report for Physics
SuperB is a high luminosity e{sup +}e{sup -} collider that will be able to indirectly probe new physics at energy scales far beyond the reach of any man made accelerator planned or in existence. Just as detailed understanding of the Standard Model of particle physics was developed from stringent constraints imposed by flavour changing processes between quarks, the detailed structure of any new physics is severely constrained by flavour processes. In order to elucidate this structure it is necessary to perform a number of complementary studies of a set of golden channels. With these measurements in hand, the pattern of deviations from the Standard Model behavior can be used as a test of the structure of new physics. If new physics is found at the LHC, then the many golden measurements from SuperB will help decode the subtle nature of the new physics. However if no new particles are found at the LHC, SuperB will be able to search for new physics at energy scales up to 10-100 TeV. In either scenario, flavour physics measurements that can be made at SuperB play a pivotal role in understanding the nature of physics beyond the Standard Model. Examples for using the interplay between measurements to discriminate New Physics models are discussed in this document. SuperB is a Super Flavour Factory, in addition to studying large samples of B{sub u,d,s}, D and {tau} decays, SuperB has a broad physics programme that includes spectroscopy both in terms of the Standard Model and exotica, and precision measurements of sin{sup 2} {theta}{sub W}. In addition to performing CP violation measurements at the {Upsilon}(4S) and {phi}(3770), SuperB will test CPT in these systems, and lepton universality in a number of different processes. The multitude of rare decay measurements possible at SuperB can be used to constrain scenarios of physics beyond the Standard Model. In terms of other precision tests of the Standard Model, this experiment will be able to perform precision over-constraints of the unitarity triangle through multiple measurements of all angles and sides. This report extends and updates the studies presented in both the SuperB Conceptual Design Report in 2007 and the Proceedings of SuperB Workshop VI in Valencia in 2008. Together, these three documents detail the Physics case of the SuperB Project
Scaling Solutions to 6D Gauged Chiral Supergravity
We construct explicitly time-dependent exact solutions to the field equations
of 6D gauged chiral supergravity, compactified to 4D in the presence of up to
two 3-branes situated within the extra dimensions. The solutions we find are
scaling solutions, and are plausibly attractors which represent the late-time
evolution of a broad class of initial conditions. By matching their near-brane
boundary conditions to physical brane properties we argue that these solutions
(together with the known maximally-symmetric solutions and a new class of
non-Lorentz-invariant static solutions, which we also present here) describe
the bulk geometry between a pair of 3-branes with non-trivial on-brane
equations of state.Comment: Contribution to the New Journal of Physics focus issue on Dark
Energy; 28 page
Kicking the Rugby Ball: Perturbations of 6D Gauged Chiral Supergravity
We analyze the axially-symmetric scalar perturbations of 6D chiral gauged
supergravity compactified on the general warped geometries in the presence of
two source branes. We find all of the conical geometries are marginally stable
for normalizable perturbations (in disagreement with some recent calculations)
and the nonconical for regular perturbations, even though none of them are
supersymmetric (apart from the trivial Salam-Sezgin solution, for which there
are no source branes). The marginal direction is the one whose presence is
required by the classical scaling property of the field equations, and all
other modes have positive squared mass. In the special case of the conical
solutions, including (but not restricted to) the unwarped `rugby-ball'
solutions, we find closed-form expressions for the mode functions in terms of
Legendre and Hypergeometric functions. In so doing we show how to match the
asymptotic near-brane form for the solution to the physics of the source
branes, and thereby how to physically interpret perturbations which can be
singular at the brane positions.Comment: 21 pages + appendices, references adde
Bayesian Fit of Exclusive Decays: The Standard Model Operator Basis
We perform a model-independent fit of the short-distance couplings
within the Standard Model set of and operators. Our analysis of , and decays is the first to harness the full
power of the Bayesian approach: all major sources of theory uncertainty
explicitly enter as nuisance parameters. Exploiting the latest measurements,
the fit reveals a flipped-sign solution in addition to a Standard-Model-like
solution for the couplings . Each solution contains about half of the
posterior probability, and both have nearly equal goodness of fit. The Standard
Model prediction is close to the best-fit point. No New Physics contributions
are necessary to describe the current data. Benefitting from the improved
posterior knowledge of the nuisance parameters, we predict ranges for currently
unmeasured, optimized observables in the angular distributions of .Comment: 42 pages, 8 figures; v2: Using new lattice input for f_Bs,
considering Bs-mixing effects in BR[B_s->ll]. Main results and conclusion
unchanged, matches journal versio
Thin Film Growth and Device Fabrication of Iron-Based Superconductors
Iron-based superconductors have received much attention as a new family of
high-temperature superconductors owing to their unique properties and distinct
differences from cuprates and conventional superconductors. This paper reviews
progress in thin film research on iron-based superconductors since their
discovery for each of five material systems with an emphasis on growth,
physical properties, device fabrication, and relevant bulk material properties.Comment: To appear in J. Phys. Soc. Jp
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