21,946 research outputs found
Evolution of the fine-structure constant in runaway dilaton models
We study the detailed evolution of the fine-structure constant in
the string-inspired runaway dilaton class of models of Damour, Piazza and
Veneziano. We provide constraints on this scenario using the most recent
measurements and discuss ways to distinguish it from alternative
models for varying . For model parameters which saturate bounds from
current observations, the redshift drift signal can differ considerably from
that of the canonical CDM paradigm at high redshifts. Measurements of
this signal by the forthcoming European Extremely Large Telescope (E-ELT),
together with more sensitive measurements, will thus dramatically
constrain these scenarios.Comment: 11 pages, 4 figure
Liquid mixtures involving fluorinated alcohols: The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol) Experimental and Simulation
Liquid mixtures involving fluorinated alcohols:
The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol)
Experimental and Simulation
Pedro Duartea, Djêide Rodriguesa, Marcelo Silvaa, Pedro Morgadoa,
Luís Martinsa,b and Eduardo J. M. Filipea*
aCentro de Química Estrutural, Instituto Superior Técnico, 1049-001 Lisboa, Portugal
bCentro de Química de Évora, Universidade de Évora, 7000-671 Évora, Portugal
Fluorinated alcohols are substances with unique properties and high technological value in the pharmaceutical and chemical industries. Trifluoroethanol (TFE), in particular, displays a number of unusual properties as a solvent. For example, it dissolves nylon at room temperature and is effectively used as solvent in bioengineering. The presence of the three fluorines atoms gives the alcohol a high ionization constant, strong hydrogen bonding capability and stability at high temperatures.
In the pharmaceutical industry, TFE finds use as the major raw material for the production of inhalation anesthetics. Mixtures of TFE and water (known as Fluorinols®) are used as working fluids for Rankine cycle heat engines for terrestrial and space applications, as a result of a unique combination of physical and thermodynamic properties such as high thermal efficiency and excellent turbine expansion characteristics.
Environmentally, TFE is a CFC substitute with an acceptable short lifetime and with small ozone depletion potential. Additionally, TFE is known to induce conformational changes in proteins and it is used as a co-solvent to analyze structural features of partially folded states.
The (ethanol + TFE) system displays an interesting and peculiar behaviour, combining a negative azeotrope with high positive excess volumes.
In this work, liquid mixtures of (ethanol + TFE) were investigated. The densities of the mixtures were measured as a function of composition between 278K and 338K and at pressures up to 700 bar. The corresponding excess volumes as a function of temperature and pressure, the isothermal compressibilities and thermal expansivities were calculated from the experimental results. The mixtures are highly non-ideal with excess volumes ranging from 0.8 - 1.0 cm3mol-1.
Finally, molecular dynamic simulations were performed to model and interpret the experimental results. The Trappe force field was used to simulate the (TFE + ethanol) mixtures and calculate the corresponding excess volumes. The simulation results are able to reproduce the correct sign and order of magnitude of the experimental VE without fitting to the experimental data. Furthermore, the simulations suggest the presence of a particular type of hydrogen bridge between ethanol and TFE, that can help to rationalize the experimental results
Automatic speaker segmentation using multiple features and distance measures: a comparison of three approaches
This paper addresses the problem of unsupervised speaker change detection. Three systems based on the Bayesian Information Criterion (BIC) are tested. The first system investigates the AudioSpectrumCentroid and the AudioWaveformEnvelope features, implements a dynamic thresholding followed by a fusion scheme, and finally applies BIC. The second method is a real-time one that uses a metric-based approach employing the line spectral pairs and the BIC to validate a potential speaker change point. The third method consists of three modules. In the first module, a measure based on second-order statistics is used; in the second module, the Euclidean distance and T2 Hotelling statistic are applied; and in the third module, the BIC is utilized. The experiments are carried out on a dataset created by concatenating speakers from the TIMIT database, that is referred to as the TIMIT data set. A comparison between the performance of the three systems is made based on t-statistics
Probability distribution of the order parameter in the directed percolation universality class
The probability distributions of the order parameter for two models in the
directed percolation universality class were evaluated. Monte Carlo simulations
have been performed for the one-dimensional generalized contact process and the
Domany-Kinzel cellular automaton. In both cases, the density of active sites
was chosen as the order parameter. The criticality of those models was obtained
by solely using the corresponding probability distribution function. It has
been shown that the present method, which has been successfully employed in
treating equilibrium systems, is indeed also useful in the study of
nonequilibrium phase transitions.Comment: 6 pages, 4 figure
The Structure of Conserved Charges in Open Spin Chains
We study the local conserved charges in integrable spin chains of the XYZ
type with nontrivial boundary conditions. The general structure of these
charges consists of a bulk part, whose density is identical to that of a
periodic chain, and a boundary part. In contrast with the periodic case, only
charges corresponding to interactions of even number of spins exist for the
open chain. Hence, there are half as many charges in the open case as in the
closed case. For the open spin-1/2 XY chain, we derive the explicit expressions
of all the charges. For the open spin-1/2 XXX chain, several lowest order
charges are presented and a general method of obtaining the boundary terms is
indicated. In contrast with the closed case, the XXX charges cannot be
described in terms of a Catalan tree pattern.Comment: 22 pages, harvmac.tex (minor clarifications and reference corrections
added
Vorton Formation
In this paper we present the first analytic model for vorton formation. We
start by deriving the microscopic string equations of motion in Witten's
superconducting model, and show that in the relevant chiral limit these
coincide with the ones obtained from the supersonic elastic models of Carter
and Peter. We then numerically study a number of solutions of these equations
of motion and thereby suggest criteria for deciding whether a given
superconducting loop configuration can form a vorton. Finally, using a recently
developed model for the evolution of currents in superconducting strings we
conjecture, by comparison with these criteria, that string networks formed at
the GUT phase transition should produce no vortons. On the other hand, a
network formed at the electroweak scale can produce vortons accounting for up
to 6% of the critical density. Some consequences of our results are discussed.Comment: 41 pages; color figures 3-6 not included, but available from authors.
To appear in Phys. Rev.
New results for the t-J model in ladders: Changes in the spin liquid state with applied magnetic field. Implications for the cuprates
Exact Diagonalization calculations are presented for the t-J model in the
presence of a uniform magnetic field. Results for 2xL ladders (L=8,10,12) and
4x4 square clusters with 1 and 2 holes indicate that the diamagnetic response
to a perpendicular magnetic field tends to induce a spin liquid state in the
spin background. The zero-field spin liquid state of a two-leg ladder is
reinforced by the magnetic field: a considerable increase of rung
antiferromagnetic correlations is observed for J/t up to 0.6, for 1 and 2
holes. Pair-breaking is also clearly observed in the ladders and seems to be
associated in part with changes promoted by the field in the spin correlations
around the zero-field pair. In the 4x4 cluster, the numerical results seem to
indicate that the field-induced spin liquid state competes with the zero-field
antiferromagnetic short-range-order, the spin liquid state being favored by
higher doping and smaller values of J/t. It is interesting to note that the
field-effect can also be observed in a 2x2 plaquette with 1 and 2 holes. This
opens up the possibility of gaining a qualitative understanding of the effect.Comment: 16 pages, 7 figures, latex New results adde
Recuperação de Mata Ciliar em Ouro Preto do Oeste, estado de Rondônia, Brasil.
Este trabalho foi realizado na bacia do rio Boa Vista localizada no município de Ouro Preto do Oeste, Rondônia, com o intuito de avaliar o desenvolvimento de um plantio de espécies arbóreas na área de mata ciliar. A recuperação desta bacia se deu mediante acordos firmados entre o poder público Estadual e a sociedade envolvida, a partir daí vários produtores se engajaram no projeto, visto que o rio é muito importante na região e também é fonte de captação da água que abastece a cidade. Foi observado a área de um produtor envolvido neste processo. No caso em estudo foram encontradas 13 espécies, 11 famílias e 92 indivíduos plantados e nativos, com grande chance de sobrevivência nas parcelas.Resumos do VIII Congresso Brasileiro de Agroecologia. Porto Alegre/RS - 25 a 28/11/2013. Trabalho n. 14816
Properties of magnetic nanodots with perpendicular anisotropy
Nanodots with magnetic vortices have many potential applications, such as
magnetic memories (VRAMs) and spin transfer nano-oscillators (STNOs). Adding a
perpendicular anisotropy term to the magnetic energy of the nanodot it becomes
possible to tune the vortex core properties. This can be obtained, e.g., in Co
nanodots by varying the thickness of the Co layer in a Co/Pt stack. Here we
discuss the spin configuration of circular and elliptical nanodots for
different perpendicular anisotropies; we show for nanodisks that micromagnetic
simulations and analytical results agree. Increasing the perpendicular
anisotropy, the vortex core radii increase, the phase diagrams are modified and
new configurations appear; the knowledge of these phase diagrams is relevant
for the choice of optimum nanodot dimensions for applications. MFM measurements
on Co/Pt multilayers confirm the trend of the vortex core diameters with
varying Co layer thicknesses.Comment: 7 pages, 8 figure
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